Tautomería y reactividad de 2-alquiltioisomünchnonas

Participation of tautomers in the mesoionic heterocycles properties has been demonstrated. For the first time, both the 2-alkylthioisomünchnones and their tiazolidinic tautomers have been isolated, characterized and used in organic synthesis. Results have been rationalized through DFT (B3LYP/6-31G*)...

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Detalles Bibliográficos
Autor principal: Díaz Álvarez, Jesús
Otros Autores: Babiano Caballero, Reyes (Universidad de Extremadura)
Formato: text (thesis)
Lenguaje:spa
Publicado: Universidad de Extremadura (España) 2006
Acceso en línea:https://dialnet.unirioja.es/servlet/oaites?codigo=616
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Sumario:Participation of tautomers in the mesoionic heterocycles properties has been demonstrated. For the first time, both the 2-alkylthioisomünchnones and their tiazolidinic tautomers have been isolated, characterized and used in organic synthesis. Results have been rationalized through DFT (B3LYP/6-31G*) calculations.