Study of the Electrochemical Behavior of Merocyanine and Merocarbocyanine Salts and Their Transformation into Π-Electron Donor Molecules, Namely Tetrathiatetraazafulvalenes

An electrochemical study using the cyclic voltammetry method was carried out on some previously prepared merocyanines salts, namely thiazolideniumsulfonate salts 5a-b, and thiazolidenium chloride salts 6a-b, and merocarbocyanines salts, namely alkylidenthiazolidenium sulfonate salt 5c, and alkyliden...

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Autores principales:	Manel Khiat, Fatima-Zohra Zradni, Souad Kasmi-Mir, Alejandro Baeza
Formato:	article
Lenguaje:	EN
Publicado:	Department of Chemistry, Universitas Gadjah Mada 2021
Materias:	rhodanines thiazolium salts merocyanines tetrathiafulvalenes dithiadiazafulvalenes cyclic voltammetry Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/0021726783d74ba7b63d0ac09ca4a472
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spelling	oai:doaj.org-article:0021726783d74ba7b63d0ac09ca4a4722021-12-02T15:58:52ZStudy of the Electrochemical Behavior of Merocyanine and Merocarbocyanine Salts and Their Transformation into Π-Electron Donor Molecules, Namely Tetrathiatetraazafulvalenes1411-94202460-157810.22146/ijc.58132https://doaj.org/article/0021726783d74ba7b63d0ac09ca4a4722021-03-01T00:00:00Zhttps://jurnal.ugm.ac.id/ijc/article/view/58132https://doaj.org/toc/1411-9420https://doaj.org/toc/2460-1578An electrochemical study using the cyclic voltammetry method was carried out on some previously prepared merocyanines salts, namely thiazolideniumsulfonate salts 5a-b, and thiazolidenium chloride salts 6a-b, and merocarbocyanines salts, namely alkylidenthiazolidenium sulfonate salt 5c, and alkylidenthiazolidenium chloride salt 6c. These salts are transformed by dimerization in situ in a voltammetric cell into tetrathiatetraazafulvalenes (TTTAFs) 7a-b, 7’a-b, 8c, and 8'c supposed to be π-electron donor molecules due to the existing conjugation in their structure. The structure of all new chemically synthesized molecules was confirmed by IR, 1H-NMR, 13C-NMR, and MS. The transformation of salts into TTTAF was confirmed by a reversible voltammogram curve and the variation of observed potentials.Manel KhiatFatima-Zohra ZradniSouad Kasmi-MirAlejandro BaezaDepartment of Chemistry, Universitas Gadjah Madaarticlerhodaninesthiazolium saltsmerocyaninestetrathiafulvalenesdithiadiazafulvalenescyclic voltammetryChemistryQD1-999ENIndonesian Journal of Chemistry, Vol 21, Iss 2, Pp 462-477 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	rhodanines thiazolium salts merocyanines tetrathiafulvalenes dithiadiazafulvalenes cyclic voltammetry Chemistry QD1-999
spellingShingle	rhodanines thiazolium salts merocyanines tetrathiafulvalenes dithiadiazafulvalenes cyclic voltammetry Chemistry QD1-999 Manel Khiat Fatima-Zohra Zradni Souad Kasmi-Mir Alejandro Baeza Study of the Electrochemical Behavior of Merocyanine and Merocarbocyanine Salts and Their Transformation into Π-Electron Donor Molecules, Namely Tetrathiatetraazafulvalenes
description	An electrochemical study using the cyclic voltammetry method was carried out on some previously prepared merocyanines salts, namely thiazolideniumsulfonate salts 5a-b, and thiazolidenium chloride salts 6a-b, and merocarbocyanines salts, namely alkylidenthiazolidenium sulfonate salt 5c, and alkylidenthiazolidenium chloride salt 6c. These salts are transformed by dimerization in situ in a voltammetric cell into tetrathiatetraazafulvalenes (TTTAFs) 7a-b, 7’a-b, 8c, and 8'c supposed to be π-electron donor molecules due to the existing conjugation in their structure. The structure of all new chemically synthesized molecules was confirmed by IR, 1H-NMR, 13C-NMR, and MS. The transformation of salts into TTTAF was confirmed by a reversible voltammogram curve and the variation of observed potentials.
format	article
author	Manel Khiat Fatima-Zohra Zradni Souad Kasmi-Mir Alejandro Baeza
author_facet	Manel Khiat Fatima-Zohra Zradni Souad Kasmi-Mir Alejandro Baeza
author_sort	Manel Khiat
title	Study of the Electrochemical Behavior of Merocyanine and Merocarbocyanine Salts and Their Transformation into Π-Electron Donor Molecules, Namely Tetrathiatetraazafulvalenes
title_short	Study of the Electrochemical Behavior of Merocyanine and Merocarbocyanine Salts and Their Transformation into Π-Electron Donor Molecules, Namely Tetrathiatetraazafulvalenes
title_full	Study of the Electrochemical Behavior of Merocyanine and Merocarbocyanine Salts and Their Transformation into Π-Electron Donor Molecules, Namely Tetrathiatetraazafulvalenes
title_fullStr	Study of the Electrochemical Behavior of Merocyanine and Merocarbocyanine Salts and Their Transformation into Π-Electron Donor Molecules, Namely Tetrathiatetraazafulvalenes
title_full_unstemmed	Study of the Electrochemical Behavior of Merocyanine and Merocarbocyanine Salts and Their Transformation into Π-Electron Donor Molecules, Namely Tetrathiatetraazafulvalenes
title_sort	study of the electrochemical behavior of merocyanine and merocarbocyanine salts and their transformation into π-electron donor molecules, namely tetrathiatetraazafulvalenes
publisher	Department of Chemistry, Universitas Gadjah Mada
publishDate	2021
url	https://doaj.org/article/0021726783d74ba7b63d0ac09ca4a472
work_keys_str_mv	AT manelkhiat studyoftheelectrochemicalbehaviorofmerocyanineandmerocarbocyaninesaltsandtheirtransformationintopelectrondonormoleculesnamelytetrathiatetraazafulvalenes AT fatimazohrazradni studyoftheelectrochemicalbehaviorofmerocyanineandmerocarbocyaninesaltsandtheirtransformationintopelectrondonormoleculesnamelytetrathiatetraazafulvalenes AT souadkasmimir studyoftheelectrochemicalbehaviorofmerocyanineandmerocarbocyaninesaltsandtheirtransformationintopelectrondonormoleculesnamelytetrathiatetraazafulvalenes AT alejandrobaeza studyoftheelectrochemicalbehaviorofmerocyanineandmerocarbocyaninesaltsandtheirtransformationintopelectrondonormoleculesnamelytetrathiatetraazafulvalenes
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Study of the Electrochemical Behavior of Merocyanine and Merocarbocyanine Salts and Their Transformation into Π-Electron Donor Molecules, Namely Tetrathiatetraazafulvalenes

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