Synergistic interaction of Re complex and amine functionalized multiple ligands in metal-organic frameworks for conversion of carbon dioxide

Abstract A metal-organic framework (MOF) is composed of secondary building units (SBUs) of metal ions and organic ligands to link each SBU. Moreover, the photosynthetic synthesis of a valuable CO chemical from carbon dioxide (CO2) represents an important class of appealing methods. Herein, we find t...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Un Jin Ryu, Sang Jun Kim, Hyung-Kyu Lim, Hyungjun Kim, Kyung Min Choi, Jeung Ku Kang
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2017
Materias:	Medicine R Science Q
Acceso en línea:	https://doaj.org/article/007b93e294ef4519973db7e3db7d68e7
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:007b93e294ef4519973db7e3db7d68e7
record_format	dspace
spelling	oai:doaj.org-article:007b93e294ef4519973db7e3db7d68e72021-12-02T16:07:06ZSynergistic interaction of Re complex and amine functionalized multiple ligands in metal-organic frameworks for conversion of carbon dioxide10.1038/s41598-017-00574-12045-2322https://doaj.org/article/007b93e294ef4519973db7e3db7d68e72017-04-01T00:00:00Zhttps://doi.org/10.1038/s41598-017-00574-1https://doaj.org/toc/2045-2322Abstract A metal-organic framework (MOF) is composed of secondary building units (SBUs) of metal ions and organic ligands to link each SBU. Moreover, the photosynthetic synthesis of a valuable CO chemical from carbon dioxide (CO2) represents an important class of appealing methods. Herein, we find that a molecular photocatalyst with high selectivity and activity can be designed via a fine balance in the proximity of Re complex (ReI(CO)3(BPYDC)(Cl), BPYDC = 2,2′-bipyridine-5,5′-dicarboxylate) and -NH2 functionalized multiple ligands composing a MOF photocatalyst, denoted as Re-MOF-NH2. These ligands in Re-MOF-NH2 has been confirmed by infrared, UV-visible, and 1H nuclear magnetic resonance spectra. Moreover, we show from extended X-ray absorption fine structure and in-situ infrared spectra that the bond corresponding to Re-CO upon introduction of -NH2 functional groups is divided into asymmetric bonds of 1.4 Å and 2.3 Å along with different CO2 vibrations, thus making the configuration of carbonyl groups in a Re metal complex become asymmetric in addition to aiding formation of CO2 intermediates within Re-MOF-NH2. Indeed, both of the uneven electron distribution in asymmetric carbonyl groups for Re-CO and the intermolecular stabilization of carbamate intermediates are proven to give the approximately 3-fold increase in photocatalytic activity for conversion of CO2 into CO.Un Jin RyuSang Jun KimHyung-Kyu LimHyungjun KimKyung Min ChoiJeung Ku KangNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 7, Iss 1, Pp 1-8 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Medicine R Science Q
spellingShingle	Medicine R Science Q Un Jin Ryu Sang Jun Kim Hyung-Kyu Lim Hyungjun Kim Kyung Min Choi Jeung Ku Kang Synergistic interaction of Re complex and amine functionalized multiple ligands in metal-organic frameworks for conversion of carbon dioxide
description	Abstract A metal-organic framework (MOF) is composed of secondary building units (SBUs) of metal ions and organic ligands to link each SBU. Moreover, the photosynthetic synthesis of a valuable CO chemical from carbon dioxide (CO2) represents an important class of appealing methods. Herein, we find that a molecular photocatalyst with high selectivity and activity can be designed via a fine balance in the proximity of Re complex (ReI(CO)3(BPYDC)(Cl), BPYDC = 2,2′-bipyridine-5,5′-dicarboxylate) and -NH2 functionalized multiple ligands composing a MOF photocatalyst, denoted as Re-MOF-NH2. These ligands in Re-MOF-NH2 has been confirmed by infrared, UV-visible, and 1H nuclear magnetic resonance spectra. Moreover, we show from extended X-ray absorption fine structure and in-situ infrared spectra that the bond corresponding to Re-CO upon introduction of -NH2 functional groups is divided into asymmetric bonds of 1.4 Å and 2.3 Å along with different CO2 vibrations, thus making the configuration of carbonyl groups in a Re metal complex become asymmetric in addition to aiding formation of CO2 intermediates within Re-MOF-NH2. Indeed, both of the uneven electron distribution in asymmetric carbonyl groups for Re-CO and the intermolecular stabilization of carbamate intermediates are proven to give the approximately 3-fold increase in photocatalytic activity for conversion of CO2 into CO.
format	article
author	Un Jin Ryu Sang Jun Kim Hyung-Kyu Lim Hyungjun Kim Kyung Min Choi Jeung Ku Kang
author_facet	Un Jin Ryu Sang Jun Kim Hyung-Kyu Lim Hyungjun Kim Kyung Min Choi Jeung Ku Kang
author_sort	Un Jin Ryu
title	Synergistic interaction of Re complex and amine functionalized multiple ligands in metal-organic frameworks for conversion of carbon dioxide
title_short	Synergistic interaction of Re complex and amine functionalized multiple ligands in metal-organic frameworks for conversion of carbon dioxide
title_full	Synergistic interaction of Re complex and amine functionalized multiple ligands in metal-organic frameworks for conversion of carbon dioxide
title_fullStr	Synergistic interaction of Re complex and amine functionalized multiple ligands in metal-organic frameworks for conversion of carbon dioxide
title_full_unstemmed	Synergistic interaction of Re complex and amine functionalized multiple ligands in metal-organic frameworks for conversion of carbon dioxide
title_sort	synergistic interaction of re complex and amine functionalized multiple ligands in metal-organic frameworks for conversion of carbon dioxide
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/007b93e294ef4519973db7e3db7d68e7
work_keys_str_mv	AT unjinryu synergisticinteractionofrecomplexandaminefunctionalizedmultipleligandsinmetalorganicframeworksforconversionofcarbondioxide AT sangjunkim synergisticinteractionofrecomplexandaminefunctionalizedmultipleligandsinmetalorganicframeworksforconversionofcarbondioxide AT hyungkyulim synergisticinteractionofrecomplexandaminefunctionalizedmultipleligandsinmetalorganicframeworksforconversionofcarbondioxide AT hyungjunkim synergisticinteractionofrecomplexandaminefunctionalizedmultipleligandsinmetalorganicframeworksforconversionofcarbondioxide AT kyungminchoi synergisticinteractionofrecomplexandaminefunctionalizedmultipleligandsinmetalorganicframeworksforconversionofcarbondioxide AT jeungkukang synergisticinteractionofrecomplexandaminefunctionalizedmultipleligandsinmetalorganicframeworksforconversionofcarbondioxide
_version_	1718384695811506176

Synergistic interaction of Re complex and amine functionalized multiple ligands in metal-organic frameworks for conversion of carbon dioxide

Ejemplares similares