Room-temperature adsorption behavior of cesium onto calcium silicate insulation
A calcium silicate insulator material was investigated for its interaction with non-radioactive cesium at room temperature by batch-type adsorption experiments. An industrial-grade calcium silicate was weighted and ground into powder with an average size of 15.4 ± 0.1 μm, which was then placed into...
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The Japan Society of Mechanical Engineers
2020
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oai:doaj.org-article:00e7a941f60f4883bd35685c1c03a51c2021-11-29T05:56:31ZRoom-temperature adsorption behavior of cesium onto calcium silicate insulation2187-974510.1299/mej.19-00563https://doaj.org/article/00e7a941f60f4883bd35685c1c03a51c2020-01-01T00:00:00Zhttps://www.jstage.jst.go.jp/article/mej/7/3/7_19-00563/_pdf/-char/enhttps://doaj.org/toc/2187-9745A calcium silicate insulator material was investigated for its interaction with non-radioactive cesium at room temperature by batch-type adsorption experiments. An industrial-grade calcium silicate was weighted and ground into powder with an average size of 15.4 ± 0.1 μm, which was then placed into the polypropylene (PP) tubes containing cesium chloride aqueous solution. Cesium concentrations were range between 1.3×10-6–3.5×10-3 M. Adsorption kinetics of cesium was evaluated based on pseudo-first order and pseudo-second order models, while the adsorption isotherm was modeled using the Langmuir model and modified BET model. Physicochemical properties of calcium silicate before and after the adsorption was investigated using XRD, SEM/EDS, and FT-IR. Chemisorption was found as the underlying sorption process between calcium silicate insulator material and cesium.Muhammad RIZAALTakumi SAITOKoji OKAMOTONejdet ERKANKunihisa NAKAJIMAMasahiko OSAKAThe Japan Society of Mechanical Engineersarticleroom-temperature adsorptioncalcium silicate insulationcesiumchemisorptionMechanical engineering and machineryTJ1-1570ENMechanical Engineering Journal, Vol 7, Iss 3, Pp 19-00563-19-00563 (2020) |
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DOAJ |
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room-temperature adsorption calcium silicate insulation cesium chemisorption Mechanical engineering and machinery TJ1-1570 |
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room-temperature adsorption calcium silicate insulation cesium chemisorption Mechanical engineering and machinery TJ1-1570 Muhammad RIZAAL Takumi SAITO Koji OKAMOTO Nejdet ERKAN Kunihisa NAKAJIMA Masahiko OSAKA Room-temperature adsorption behavior of cesium onto calcium silicate insulation |
description |
A calcium silicate insulator material was investigated for its interaction with non-radioactive cesium at room temperature by batch-type adsorption experiments. An industrial-grade calcium silicate was weighted and ground into powder with an average size of 15.4 ± 0.1 μm, which was then placed into the polypropylene (PP) tubes containing cesium chloride aqueous solution. Cesium concentrations were range between 1.3×10-6–3.5×10-3 M. Adsorption kinetics of cesium was evaluated based on pseudo-first order and pseudo-second order models, while the adsorption isotherm was modeled using the Langmuir model and modified BET model. Physicochemical properties of calcium silicate before and after the adsorption was investigated using XRD, SEM/EDS, and FT-IR. Chemisorption was found as the underlying sorption process between calcium silicate insulator material and cesium. |
format |
article |
author |
Muhammad RIZAAL Takumi SAITO Koji OKAMOTO Nejdet ERKAN Kunihisa NAKAJIMA Masahiko OSAKA |
author_facet |
Muhammad RIZAAL Takumi SAITO Koji OKAMOTO Nejdet ERKAN Kunihisa NAKAJIMA Masahiko OSAKA |
author_sort |
Muhammad RIZAAL |
title |
Room-temperature adsorption behavior of cesium onto calcium silicate insulation |
title_short |
Room-temperature adsorption behavior of cesium onto calcium silicate insulation |
title_full |
Room-temperature adsorption behavior of cesium onto calcium silicate insulation |
title_fullStr |
Room-temperature adsorption behavior of cesium onto calcium silicate insulation |
title_full_unstemmed |
Room-temperature adsorption behavior of cesium onto calcium silicate insulation |
title_sort |
room-temperature adsorption behavior of cesium onto calcium silicate insulation |
publisher |
The Japan Society of Mechanical Engineers |
publishDate |
2020 |
url |
https://doaj.org/article/00e7a941f60f4883bd35685c1c03a51c |
work_keys_str_mv |
AT muhammadrizaal roomtemperatureadsorptionbehaviorofcesiumontocalciumsilicateinsulation AT takumisaito roomtemperatureadsorptionbehaviorofcesiumontocalciumsilicateinsulation AT kojiokamoto roomtemperatureadsorptionbehaviorofcesiumontocalciumsilicateinsulation AT nejdeterkan roomtemperatureadsorptionbehaviorofcesiumontocalciumsilicateinsulation AT kunihisanakajima roomtemperatureadsorptionbehaviorofcesiumontocalciumsilicateinsulation AT masahikoosaka roomtemperatureadsorptionbehaviorofcesiumontocalciumsilicateinsulation |
_version_ |
1718407565280280576 |