Remarkable catalytic activity of dinitrogen-bridged dimolybdenum complexes bearing NHC-based PCP-pincer ligands toward nitrogen fixation

Catalytic nitrogen fixation is a very active research area, given the need to develop mild routes for ammonia production. Here the authors report a PCP-pincer molybdenum complex allowing for highly efficient ammonia generation under ambient conditions.

Guardado en:

Detalles Bibliográficos
Autores principales:	Aya Eizawa, Kazuya Arashiba, Hiromasa Tanaka, Shogo Kuriyama, Yuki Matsuo, Kazunari Nakajima, Kazunari Yoshizawa, Yoshiaki Nishibayashi
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2017
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/00f3865dfd9c42ea88635a09ad30f98a
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:00f3865dfd9c42ea88635a09ad30f98a
record_format	dspace
spelling	oai:doaj.org-article:00f3865dfd9c42ea88635a09ad30f98a2021-12-02T17:06:26ZRemarkable catalytic activity of dinitrogen-bridged dimolybdenum complexes bearing NHC-based PCP-pincer ligands toward nitrogen fixation10.1038/ncomms148742041-1723https://doaj.org/article/00f3865dfd9c42ea88635a09ad30f98a2017-04-01T00:00:00Zhttps://doi.org/10.1038/ncomms14874https://doaj.org/toc/2041-1723Catalytic nitrogen fixation is a very active research area, given the need to develop mild routes for ammonia production. Here the authors report a PCP-pincer molybdenum complex allowing for highly efficient ammonia generation under ambient conditions.Aya EizawaKazuya ArashibaHiromasa TanakaShogo KuriyamaYuki MatsuoKazunari NakajimaKazunari YoshizawaYoshiaki NishibayashiNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-12 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Aya Eizawa Kazuya Arashiba Hiromasa Tanaka Shogo Kuriyama Yuki Matsuo Kazunari Nakajima Kazunari Yoshizawa Yoshiaki Nishibayashi Remarkable catalytic activity of dinitrogen-bridged dimolybdenum complexes bearing NHC-based PCP-pincer ligands toward nitrogen fixation
description	Catalytic nitrogen fixation is a very active research area, given the need to develop mild routes for ammonia production. Here the authors report a PCP-pincer molybdenum complex allowing for highly efficient ammonia generation under ambient conditions.
format	article
author	Aya Eizawa Kazuya Arashiba Hiromasa Tanaka Shogo Kuriyama Yuki Matsuo Kazunari Nakajima Kazunari Yoshizawa Yoshiaki Nishibayashi
author_facet	Aya Eizawa Kazuya Arashiba Hiromasa Tanaka Shogo Kuriyama Yuki Matsuo Kazunari Nakajima Kazunari Yoshizawa Yoshiaki Nishibayashi
author_sort	Aya Eizawa
title	Remarkable catalytic activity of dinitrogen-bridged dimolybdenum complexes bearing NHC-based PCP-pincer ligands toward nitrogen fixation
title_short	Remarkable catalytic activity of dinitrogen-bridged dimolybdenum complexes bearing NHC-based PCP-pincer ligands toward nitrogen fixation
title_full	Remarkable catalytic activity of dinitrogen-bridged dimolybdenum complexes bearing NHC-based PCP-pincer ligands toward nitrogen fixation
title_fullStr	Remarkable catalytic activity of dinitrogen-bridged dimolybdenum complexes bearing NHC-based PCP-pincer ligands toward nitrogen fixation
title_full_unstemmed	Remarkable catalytic activity of dinitrogen-bridged dimolybdenum complexes bearing NHC-based PCP-pincer ligands toward nitrogen fixation
title_sort	remarkable catalytic activity of dinitrogen-bridged dimolybdenum complexes bearing nhc-based pcp-pincer ligands toward nitrogen fixation
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/00f3865dfd9c42ea88635a09ad30f98a
work_keys_str_mv	AT ayaeizawa remarkablecatalyticactivityofdinitrogenbridgeddimolybdenumcomplexesbearingnhcbasedpcppincerligandstowardnitrogenfixation AT kazuyaarashiba remarkablecatalyticactivityofdinitrogenbridgeddimolybdenumcomplexesbearingnhcbasedpcppincerligandstowardnitrogenfixation AT hiromasatanaka remarkablecatalyticactivityofdinitrogenbridgeddimolybdenumcomplexesbearingnhcbasedpcppincerligandstowardnitrogenfixation AT shogokuriyama remarkablecatalyticactivityofdinitrogenbridgeddimolybdenumcomplexesbearingnhcbasedpcppincerligandstowardnitrogenfixation AT yukimatsuo remarkablecatalyticactivityofdinitrogenbridgeddimolybdenumcomplexesbearingnhcbasedpcppincerligandstowardnitrogenfixation AT kazunarinakajima remarkablecatalyticactivityofdinitrogenbridgeddimolybdenumcomplexesbearingnhcbasedpcppincerligandstowardnitrogenfixation AT kazunariyoshizawa remarkablecatalyticactivityofdinitrogenbridgeddimolybdenumcomplexesbearingnhcbasedpcppincerligandstowardnitrogenfixation AT yoshiakinishibayashi remarkablecatalyticactivityofdinitrogenbridgeddimolybdenumcomplexesbearingnhcbasedpcppincerligandstowardnitrogenfixation
_version_	1718381594816806912

Remarkable catalytic activity of dinitrogen-bridged dimolybdenum complexes bearing NHC-based PCP-pincer ligands toward nitrogen fixation

Ejemplares similares