Remarkable catalytic activity of dinitrogen-bridged dimolybdenum complexes bearing NHC-based PCP-pincer ligands toward nitrogen fixation

Remarkable catalytic activity of dinitrogen-bridged dimolybdenum complexes bearing NHC-based PCP-pincer ligands toward nitrogen fixation

Catalytic nitrogen fixation is a very active research area, given the need to develop mild routes for ammonia production. Here the authors report a PCP-pincer molybdenum complex allowing for highly efficient ammonia generation under ambient conditions.

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Autores principales: Aya Eizawa, Kazuya Arashiba, Hiromasa Tanaka, Shogo Kuriyama, Yuki Matsuo, Kazunari Nakajima, Kazunari Yoshizawa, Yoshiaki Nishibayashi
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Science
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Acceso en línea:https://doaj.org/article/00f3865dfd9c42ea88635a09ad30f98a
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