Anion stabilised hypercloso-hexaalane Al6H6

While polyhedral boron hydride complexes have found application in a number of diverse fields, the isolation of stable aluminium analogues remains highly challenging. Here, Jones and colleagues demonstrate that reduction of an amidinato-aluminum(III) hydride complex with magnesium(I) dimers affords...

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Autores principales: Simon J. Bonyhady, David Collis, Nicole Holzmann, Alison J. Edwards, Ross O. Piltz, Gernot Frenking, Andreas Stasch, Cameron Jones
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Publicado: Nature Portfolio 2018
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Acceso en línea:https://doaj.org/article/012ef1d7039b45faa79e5ab9dccc5d25
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spelling oai:doaj.org-article:012ef1d7039b45faa79e5ab9dccc5d252021-12-02T17:32:32ZAnion stabilised hypercloso-hexaalane Al6H610.1038/s41467-018-05504-x2041-1723https://doaj.org/article/012ef1d7039b45faa79e5ab9dccc5d252018-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-05504-xhttps://doaj.org/toc/2041-1723While polyhedral boron hydride complexes have found application in a number of diverse fields, the isolation of stable aluminium analogues remains highly challenging. Here, Jones and colleagues demonstrate that reduction of an amidinato-aluminum(III) hydride complex with magnesium(I) dimers affords stable aluminium(I) hydride compounds.Simon J. BonyhadyDavid CollisNicole HolzmannAlison J. EdwardsRoss O. PiltzGernot FrenkingAndreas StaschCameron JonesNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-6 (2018)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Simon J. Bonyhady
David Collis
Nicole Holzmann
Alison J. Edwards
Ross O. Piltz
Gernot Frenking
Andreas Stasch
Cameron Jones
Anion stabilised hypercloso-hexaalane Al6H6
description While polyhedral boron hydride complexes have found application in a number of diverse fields, the isolation of stable aluminium analogues remains highly challenging. Here, Jones and colleagues demonstrate that reduction of an amidinato-aluminum(III) hydride complex with magnesium(I) dimers affords stable aluminium(I) hydride compounds.
format article
author Simon J. Bonyhady
David Collis
Nicole Holzmann
Alison J. Edwards
Ross O. Piltz
Gernot Frenking
Andreas Stasch
Cameron Jones
author_facet Simon J. Bonyhady
David Collis
Nicole Holzmann
Alison J. Edwards
Ross O. Piltz
Gernot Frenking
Andreas Stasch
Cameron Jones
author_sort Simon J. Bonyhady
title Anion stabilised hypercloso-hexaalane Al6H6
title_short Anion stabilised hypercloso-hexaalane Al6H6
title_full Anion stabilised hypercloso-hexaalane Al6H6
title_fullStr Anion stabilised hypercloso-hexaalane Al6H6
title_full_unstemmed Anion stabilised hypercloso-hexaalane Al6H6
title_sort anion stabilised hypercloso-hexaalane al6h6
publisher Nature Portfolio
publishDate 2018
url https://doaj.org/article/012ef1d7039b45faa79e5ab9dccc5d25
work_keys_str_mv AT simonjbonyhady anionstabilisedhyperclosohexaalaneal6h6
AT davidcollis anionstabilisedhyperclosohexaalaneal6h6
AT nicoleholzmann anionstabilisedhyperclosohexaalaneal6h6
AT alisonjedwards anionstabilisedhyperclosohexaalaneal6h6
AT rossopiltz anionstabilisedhyperclosohexaalaneal6h6
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AT andreasstasch anionstabilisedhyperclosohexaalaneal6h6
AT cameronjones anionstabilisedhyperclosohexaalaneal6h6
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