Anion stabilised hypercloso-hexaalane Al6H6
While polyhedral boron hydride complexes have found application in a number of diverse fields, the isolation of stable aluminium analogues remains highly challenging. Here, Jones and colleagues demonstrate that reduction of an amidinato-aluminum(III) hydride complex with magnesium(I) dimers affords...
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Nature Portfolio
2018
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oai:doaj.org-article:012ef1d7039b45faa79e5ab9dccc5d252021-12-02T17:32:32ZAnion stabilised hypercloso-hexaalane Al6H610.1038/s41467-018-05504-x2041-1723https://doaj.org/article/012ef1d7039b45faa79e5ab9dccc5d252018-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-05504-xhttps://doaj.org/toc/2041-1723While polyhedral boron hydride complexes have found application in a number of diverse fields, the isolation of stable aluminium analogues remains highly challenging. Here, Jones and colleagues demonstrate that reduction of an amidinato-aluminum(III) hydride complex with magnesium(I) dimers affords stable aluminium(I) hydride compounds.Simon J. BonyhadyDavid CollisNicole HolzmannAlison J. EdwardsRoss O. PiltzGernot FrenkingAndreas StaschCameron JonesNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-6 (2018) |
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Science Q Simon J. Bonyhady David Collis Nicole Holzmann Alison J. Edwards Ross O. Piltz Gernot Frenking Andreas Stasch Cameron Jones Anion stabilised hypercloso-hexaalane Al6H6 |
description |
While polyhedral boron hydride complexes have found application in a number of diverse fields, the isolation of stable aluminium analogues remains highly challenging. Here, Jones and colleagues demonstrate that reduction of an amidinato-aluminum(III) hydride complex with magnesium(I) dimers affords stable aluminium(I) hydride compounds. |
format |
article |
author |
Simon J. Bonyhady David Collis Nicole Holzmann Alison J. Edwards Ross O. Piltz Gernot Frenking Andreas Stasch Cameron Jones |
author_facet |
Simon J. Bonyhady David Collis Nicole Holzmann Alison J. Edwards Ross O. Piltz Gernot Frenking Andreas Stasch Cameron Jones |
author_sort |
Simon J. Bonyhady |
title |
Anion stabilised hypercloso-hexaalane Al6H6 |
title_short |
Anion stabilised hypercloso-hexaalane Al6H6 |
title_full |
Anion stabilised hypercloso-hexaalane Al6H6 |
title_fullStr |
Anion stabilised hypercloso-hexaalane Al6H6 |
title_full_unstemmed |
Anion stabilised hypercloso-hexaalane Al6H6 |
title_sort |
anion stabilised hypercloso-hexaalane al6h6 |
publisher |
Nature Portfolio |
publishDate |
2018 |
url |
https://doaj.org/article/012ef1d7039b45faa79e5ab9dccc5d25 |
work_keys_str_mv |
AT simonjbonyhady anionstabilisedhyperclosohexaalaneal6h6 AT davidcollis anionstabilisedhyperclosohexaalaneal6h6 AT nicoleholzmann anionstabilisedhyperclosohexaalaneal6h6 AT alisonjedwards anionstabilisedhyperclosohexaalaneal6h6 AT rossopiltz anionstabilisedhyperclosohexaalaneal6h6 AT gernotfrenking anionstabilisedhyperclosohexaalaneal6h6 AT andreasstasch anionstabilisedhyperclosohexaalaneal6h6 AT cameronjones anionstabilisedhyperclosohexaalaneal6h6 |
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1718380223973556224 |