Selective hydrogenolysis of catechyl lignin into propenylcatechol over an atomically dispersed ruthenium catalyst

C-lignin represents an ideal feedstock for producing catechol derivatives. Here, the authors engineered an atomically dispersed Ru catalyst, which can cleave C−O bonds efficiently and circumvent C=C bonds hydrogenation selectively, thus leading to propenylcatechol in high yields with high TONs.

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Autores principales:	Shuizhong Wang, Kaili Zhang, Helong Li, Ling-Ping Xiao, Guoyong Song
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/0185380f60294d91b2775bb143d1ee9c
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spelling	oai:doaj.org-article:0185380f60294d91b2775bb143d1ee9c2021-12-02T13:51:03ZSelective hydrogenolysis of catechyl lignin into propenylcatechol over an atomically dispersed ruthenium catalyst10.1038/s41467-020-20684-12041-1723https://doaj.org/article/0185380f60294d91b2775bb143d1ee9c2021-01-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-20684-1https://doaj.org/toc/2041-1723C-lignin represents an ideal feedstock for producing catechol derivatives. Here, the authors engineered an atomically dispersed Ru catalyst, which can cleave C−O bonds efficiently and circumvent C=C bonds hydrogenation selectively, thus leading to propenylcatechol in high yields with high TONs.Shuizhong WangKaili ZhangHelong LiLing-Ping XiaoGuoyong SongNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Shuizhong Wang Kaili Zhang Helong Li Ling-Ping Xiao Guoyong Song Selective hydrogenolysis of catechyl lignin into propenylcatechol over an atomically dispersed ruthenium catalyst
description	C-lignin represents an ideal feedstock for producing catechol derivatives. Here, the authors engineered an atomically dispersed Ru catalyst, which can cleave C−O bonds efficiently and circumvent C=C bonds hydrogenation selectively, thus leading to propenylcatechol in high yields with high TONs.
format	article
author	Shuizhong Wang Kaili Zhang Helong Li Ling-Ping Xiao Guoyong Song
author_facet	Shuizhong Wang Kaili Zhang Helong Li Ling-Ping Xiao Guoyong Song
author_sort	Shuizhong Wang
title	Selective hydrogenolysis of catechyl lignin into propenylcatechol over an atomically dispersed ruthenium catalyst
title_short	Selective hydrogenolysis of catechyl lignin into propenylcatechol over an atomically dispersed ruthenium catalyst
title_full	Selective hydrogenolysis of catechyl lignin into propenylcatechol over an atomically dispersed ruthenium catalyst
title_fullStr	Selective hydrogenolysis of catechyl lignin into propenylcatechol over an atomically dispersed ruthenium catalyst
title_full_unstemmed	Selective hydrogenolysis of catechyl lignin into propenylcatechol over an atomically dispersed ruthenium catalyst
title_sort	selective hydrogenolysis of catechyl lignin into propenylcatechol over an atomically dispersed ruthenium catalyst
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/0185380f60294d91b2775bb143d1ee9c
work_keys_str_mv	AT shuizhongwang selectivehydrogenolysisofcatechylligninintopropenylcatecholoveranatomicallydispersedrutheniumcatalyst AT kailizhang selectivehydrogenolysisofcatechylligninintopropenylcatecholoveranatomicallydispersedrutheniumcatalyst AT helongli selectivehydrogenolysisofcatechylligninintopropenylcatecholoveranatomicallydispersedrutheniumcatalyst AT lingpingxiao selectivehydrogenolysisofcatechylligninintopropenylcatecholoveranatomicallydispersedrutheniumcatalyst AT guoyongsong selectivehydrogenolysisofcatechylligninintopropenylcatecholoveranatomicallydispersedrutheniumcatalyst
_version_	1718392417608007680

Selective hydrogenolysis of catechyl lignin into propenylcatechol over an atomically dispersed ruthenium catalyst

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