A thermodynamic assessment of precipitation, growth, and control of MnS inclusion in U75V heavy rail steel

Thermodynamic analysis of the precipitation behavior, growth kinetic, and control mechanism of MnS inclusion in U75V heavy rail steel was conducted in this study. The results showed that solute element S had a much higher segregation ratio than that of Mn, and MnS would only precipitate in the solid...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: Ren Wen-Qiang, Wang Lu, Xue Zheng-Liang, Li Cheng-Zhi, Zhu Hang-Yu, Huang Ao, Li Chang
Formato: article
Lenguaje:EN
Publicado: De Gruyter 2021
Materias:
T
Acceso en línea:https://doaj.org/article/01aac7dec8364b9bbdaeb270229df1a8
Etiquetas: Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
id oai:doaj.org-article:01aac7dec8364b9bbdaeb270229df1a8
record_format dspace
spelling oai:doaj.org-article:01aac7dec8364b9bbdaeb270229df1a82021-12-05T14:10:50ZA thermodynamic assessment of precipitation, growth, and control of MnS inclusion in U75V heavy rail steel2191-032410.1515/htmp-2021-0022https://doaj.org/article/01aac7dec8364b9bbdaeb270229df1a82021-06-01T00:00:00Zhttps://doi.org/10.1515/htmp-2021-0022https://doaj.org/toc/2191-0324Thermodynamic analysis of the precipitation behavior, growth kinetic, and control mechanism of MnS inclusion in U75V heavy rail steel was conducted in this study. The results showed that solute element S had a much higher segregation ratio than that of Mn, and MnS would only precipitate in the solid–liquid (two-phase) regions at the late stage during the solidification process at the solid fraction of 0.9518. Increasing the cooling rate had no obvious influence on the precipitation time of MnS inclusion; however, its particle size would be decreased greatly. The results also suggested that increasing the concentration of Mn would lead to an earlier precipitation time of MnS, while it had little effect on the final particle size; as to S, it was found that increasing its concentration could not only make the precipitation time earlier but also make the particle size larger. Adding a certain amount of Ti additive could improve the mechanical properties of U75V heavy rail steel due to the formation of TiOx–MnS or MnS–TiS complex inclusions. The precipitation sequences of Ti3O5 → Ti2O3 → TiO2 → TiO → MnS → TiS for Ti treatment were determined based on the thermodynamic calculation.Ren Wen-QiangWang LuXue Zheng-LiangLi Cheng-ZhiZhu Hang-YuHuang AoLi ChangDe Gruyterarticleu75v heavy rail steelmns inclusionthermodynamic calculationti treatmentTechnologyTChemical technologyTP1-1185Chemicals: Manufacture, use, etc.TP200-248ENHigh Temperature Materials and Processes, Vol 40, Iss 1, Pp 178-192 (2021)
institution DOAJ
collection DOAJ
language EN
topic u75v heavy rail steel
mns inclusion
thermodynamic calculation
ti treatment
Technology
T
Chemical technology
TP1-1185
Chemicals: Manufacture, use, etc.
TP200-248
spellingShingle u75v heavy rail steel
mns inclusion
thermodynamic calculation
ti treatment
Technology
T
Chemical technology
TP1-1185
Chemicals: Manufacture, use, etc.
TP200-248
Ren Wen-Qiang
Wang Lu
Xue Zheng-Liang
Li Cheng-Zhi
Zhu Hang-Yu
Huang Ao
Li Chang
A thermodynamic assessment of precipitation, growth, and control of MnS inclusion in U75V heavy rail steel
description Thermodynamic analysis of the precipitation behavior, growth kinetic, and control mechanism of MnS inclusion in U75V heavy rail steel was conducted in this study. The results showed that solute element S had a much higher segregation ratio than that of Mn, and MnS would only precipitate in the solid–liquid (two-phase) regions at the late stage during the solidification process at the solid fraction of 0.9518. Increasing the cooling rate had no obvious influence on the precipitation time of MnS inclusion; however, its particle size would be decreased greatly. The results also suggested that increasing the concentration of Mn would lead to an earlier precipitation time of MnS, while it had little effect on the final particle size; as to S, it was found that increasing its concentration could not only make the precipitation time earlier but also make the particle size larger. Adding a certain amount of Ti additive could improve the mechanical properties of U75V heavy rail steel due to the formation of TiOx–MnS or MnS–TiS complex inclusions. The precipitation sequences of Ti3O5 → Ti2O3 → TiO2 → TiO → MnS → TiS for Ti treatment were determined based on the thermodynamic calculation.
format article
author Ren Wen-Qiang
Wang Lu
Xue Zheng-Liang
Li Cheng-Zhi
Zhu Hang-Yu
Huang Ao
Li Chang
author_facet Ren Wen-Qiang
Wang Lu
Xue Zheng-Liang
Li Cheng-Zhi
Zhu Hang-Yu
Huang Ao
Li Chang
author_sort Ren Wen-Qiang
title A thermodynamic assessment of precipitation, growth, and control of MnS inclusion in U75V heavy rail steel
title_short A thermodynamic assessment of precipitation, growth, and control of MnS inclusion in U75V heavy rail steel
title_full A thermodynamic assessment of precipitation, growth, and control of MnS inclusion in U75V heavy rail steel
title_fullStr A thermodynamic assessment of precipitation, growth, and control of MnS inclusion in U75V heavy rail steel
title_full_unstemmed A thermodynamic assessment of precipitation, growth, and control of MnS inclusion in U75V heavy rail steel
title_sort thermodynamic assessment of precipitation, growth, and control of mns inclusion in u75v heavy rail steel
publisher De Gruyter
publishDate 2021
url https://doaj.org/article/01aac7dec8364b9bbdaeb270229df1a8
work_keys_str_mv AT renwenqiang athermodynamicassessmentofprecipitationgrowthandcontrolofmnsinclusioninu75vheavyrailsteel
AT wanglu athermodynamicassessmentofprecipitationgrowthandcontrolofmnsinclusioninu75vheavyrailsteel
AT xuezhengliang athermodynamicassessmentofprecipitationgrowthandcontrolofmnsinclusioninu75vheavyrailsteel
AT lichengzhi athermodynamicassessmentofprecipitationgrowthandcontrolofmnsinclusioninu75vheavyrailsteel
AT zhuhangyu athermodynamicassessmentofprecipitationgrowthandcontrolofmnsinclusioninu75vheavyrailsteel
AT huangao athermodynamicassessmentofprecipitationgrowthandcontrolofmnsinclusioninu75vheavyrailsteel
AT lichang athermodynamicassessmentofprecipitationgrowthandcontrolofmnsinclusioninu75vheavyrailsteel
AT renwenqiang thermodynamicassessmentofprecipitationgrowthandcontrolofmnsinclusioninu75vheavyrailsteel
AT wanglu thermodynamicassessmentofprecipitationgrowthandcontrolofmnsinclusioninu75vheavyrailsteel
AT xuezhengliang thermodynamicassessmentofprecipitationgrowthandcontrolofmnsinclusioninu75vheavyrailsteel
AT lichengzhi thermodynamicassessmentofprecipitationgrowthandcontrolofmnsinclusioninu75vheavyrailsteel
AT zhuhangyu thermodynamicassessmentofprecipitationgrowthandcontrolofmnsinclusioninu75vheavyrailsteel
AT huangao thermodynamicassessmentofprecipitationgrowthandcontrolofmnsinclusioninu75vheavyrailsteel
AT lichang thermodynamicassessmentofprecipitationgrowthandcontrolofmnsinclusioninu75vheavyrailsteel
_version_ 1718371658558865408