A thermodynamic assessment of precipitation, growth, and control of MnS inclusion in U75V heavy rail steel
Thermodynamic analysis of the precipitation behavior, growth kinetic, and control mechanism of MnS inclusion in U75V heavy rail steel was conducted in this study. The results showed that solute element S had a much higher segregation ratio than that of Mn, and MnS would only precipitate in the solid...
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2021
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oai:doaj.org-article:01aac7dec8364b9bbdaeb270229df1a82021-12-05T14:10:50ZA thermodynamic assessment of precipitation, growth, and control of MnS inclusion in U75V heavy rail steel2191-032410.1515/htmp-2021-0022https://doaj.org/article/01aac7dec8364b9bbdaeb270229df1a82021-06-01T00:00:00Zhttps://doi.org/10.1515/htmp-2021-0022https://doaj.org/toc/2191-0324Thermodynamic analysis of the precipitation behavior, growth kinetic, and control mechanism of MnS inclusion in U75V heavy rail steel was conducted in this study. The results showed that solute element S had a much higher segregation ratio than that of Mn, and MnS would only precipitate in the solid–liquid (two-phase) regions at the late stage during the solidification process at the solid fraction of 0.9518. Increasing the cooling rate had no obvious influence on the precipitation time of MnS inclusion; however, its particle size would be decreased greatly. The results also suggested that increasing the concentration of Mn would lead to an earlier precipitation time of MnS, while it had little effect on the final particle size; as to S, it was found that increasing its concentration could not only make the precipitation time earlier but also make the particle size larger. Adding a certain amount of Ti additive could improve the mechanical properties of U75V heavy rail steel due to the formation of TiOx–MnS or MnS–TiS complex inclusions. The precipitation sequences of Ti3O5 → Ti2O3 → TiO2 → TiO → MnS → TiS for Ti treatment were determined based on the thermodynamic calculation.Ren Wen-QiangWang LuXue Zheng-LiangLi Cheng-ZhiZhu Hang-YuHuang AoLi ChangDe Gruyterarticleu75v heavy rail steelmns inclusionthermodynamic calculationti treatmentTechnologyTChemical technologyTP1-1185Chemicals: Manufacture, use, etc.TP200-248ENHigh Temperature Materials and Processes, Vol 40, Iss 1, Pp 178-192 (2021) |
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u75v heavy rail steel mns inclusion thermodynamic calculation ti treatment Technology T Chemical technology TP1-1185 Chemicals: Manufacture, use, etc. TP200-248 |
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u75v heavy rail steel mns inclusion thermodynamic calculation ti treatment Technology T Chemical technology TP1-1185 Chemicals: Manufacture, use, etc. TP200-248 Ren Wen-Qiang Wang Lu Xue Zheng-Liang Li Cheng-Zhi Zhu Hang-Yu Huang Ao Li Chang A thermodynamic assessment of precipitation, growth, and control of MnS inclusion in U75V heavy rail steel |
description |
Thermodynamic analysis of the precipitation behavior, growth kinetic, and control mechanism of MnS inclusion in U75V heavy rail steel was conducted in this study. The results showed that solute element S had a much higher segregation ratio than that of Mn, and MnS would only precipitate in the solid–liquid (two-phase) regions at the late stage during the solidification process at the solid fraction of 0.9518. Increasing the cooling rate had no obvious influence on the precipitation time of MnS inclusion; however, its particle size would be decreased greatly. The results also suggested that increasing the concentration of Mn would lead to an earlier precipitation time of MnS, while it had little effect on the final particle size; as to S, it was found that increasing its concentration could not only make the precipitation time earlier but also make the particle size larger. Adding a certain amount of Ti additive could improve the mechanical properties of U75V heavy rail steel due to the formation of TiOx–MnS or MnS–TiS complex inclusions. The precipitation sequences of Ti3O5 → Ti2O3 → TiO2 → TiO → MnS → TiS for Ti treatment were determined based on the thermodynamic calculation. |
format |
article |
author |
Ren Wen-Qiang Wang Lu Xue Zheng-Liang Li Cheng-Zhi Zhu Hang-Yu Huang Ao Li Chang |
author_facet |
Ren Wen-Qiang Wang Lu Xue Zheng-Liang Li Cheng-Zhi Zhu Hang-Yu Huang Ao Li Chang |
author_sort |
Ren Wen-Qiang |
title |
A thermodynamic assessment of precipitation, growth, and control of MnS inclusion in U75V heavy rail steel |
title_short |
A thermodynamic assessment of precipitation, growth, and control of MnS inclusion in U75V heavy rail steel |
title_full |
A thermodynamic assessment of precipitation, growth, and control of MnS inclusion in U75V heavy rail steel |
title_fullStr |
A thermodynamic assessment of precipitation, growth, and control of MnS inclusion in U75V heavy rail steel |
title_full_unstemmed |
A thermodynamic assessment of precipitation, growth, and control of MnS inclusion in U75V heavy rail steel |
title_sort |
thermodynamic assessment of precipitation, growth, and control of mns inclusion in u75v heavy rail steel |
publisher |
De Gruyter |
publishDate |
2021 |
url |
https://doaj.org/article/01aac7dec8364b9bbdaeb270229df1a8 |
work_keys_str_mv |
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