Solvothermal synthesis of CdIn2S4 photocatalyst for selective photosynthesis of organic aromatic compounds under visible light

Abstract Ternary chalcogenide semiconductor, cadmium indium sulfide (CdIn2S4), was prepared by a simple solvothermal method using ethylene glycol as a solvent, as well as indium chloride tetrahydrate (InCl3 .4H2O), cadmium nitrate tetrahydrate [Cd(NO3)2 .4H2O], and thiacetamide (TAA) as precursors....

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Autores principales:	Cancan Ling, Xiangju Ye, Jinghu Zhang, Jinfeng Zhang, Sujuan Zhang, Sugang Meng, Xianliang Fu, Shifu Chen
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2017
Materias:	Medicine R Science Q
Acceso en línea:	https://doaj.org/article/02b8db868a31460094fc0e51aa930b5c
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spelling	oai:doaj.org-article:02b8db868a31460094fc0e51aa930b5c2021-12-02T12:32:58ZSolvothermal synthesis of CdIn2S4 photocatalyst for selective photosynthesis of organic aromatic compounds under visible light10.1038/s41598-017-00055-52045-2322https://doaj.org/article/02b8db868a31460094fc0e51aa930b5c2017-02-01T00:00:00Zhttps://doi.org/10.1038/s41598-017-00055-5https://doaj.org/toc/2045-2322Abstract Ternary chalcogenide semiconductor, cadmium indium sulfide (CdIn2S4), was prepared by a simple solvothermal method using ethylene glycol as a solvent, as well as indium chloride tetrahydrate (InCl3 .4H2O), cadmium nitrate tetrahydrate [Cd(NO3)2 .4H2O], and thiacetamide (TAA) as precursors. The resulted sample was subject to a series of characterizations. It is the first time to use CdIn2S4 sample as a visible light-driven photocatalyst for simultaneous selective redox transformation of organic aromatic compounds. The results indicate that the as-synthesized CdIn2S4 photocatalyst not only has excellent photocatalytic performance compared with pure In2S3 and CdS for the selective oxidation of aromatic alcohols in an oxygen environment, but also shows high photocatalytic redox activities under nitrogen atmosphere. A possible mechanism for the photocatalytic redox reaction in the coupled system was proposed. It is hoped that our current work could extend the applications of CdIn2S4 photocatalyst and provide new insights for selective transformations of organic compounds.Cancan LingXiangju YeJinghu ZhangJinfeng ZhangSujuan ZhangSugang MengXianliang FuShifu ChenNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 7, Iss 1, Pp 1-16 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Medicine R Science Q
spellingShingle	Medicine R Science Q Cancan Ling Xiangju Ye Jinghu Zhang Jinfeng Zhang Sujuan Zhang Sugang Meng Xianliang Fu Shifu Chen Solvothermal synthesis of CdIn2S4 photocatalyst for selective photosynthesis of organic aromatic compounds under visible light
description	Abstract Ternary chalcogenide semiconductor, cadmium indium sulfide (CdIn2S4), was prepared by a simple solvothermal method using ethylene glycol as a solvent, as well as indium chloride tetrahydrate (InCl3 .4H2O), cadmium nitrate tetrahydrate [Cd(NO3)2 .4H2O], and thiacetamide (TAA) as precursors. The resulted sample was subject to a series of characterizations. It is the first time to use CdIn2S4 sample as a visible light-driven photocatalyst for simultaneous selective redox transformation of organic aromatic compounds. The results indicate that the as-synthesized CdIn2S4 photocatalyst not only has excellent photocatalytic performance compared with pure In2S3 and CdS for the selective oxidation of aromatic alcohols in an oxygen environment, but also shows high photocatalytic redox activities under nitrogen atmosphere. A possible mechanism for the photocatalytic redox reaction in the coupled system was proposed. It is hoped that our current work could extend the applications of CdIn2S4 photocatalyst and provide new insights for selective transformations of organic compounds.
format	article
author	Cancan Ling Xiangju Ye Jinghu Zhang Jinfeng Zhang Sujuan Zhang Sugang Meng Xianliang Fu Shifu Chen
author_facet	Cancan Ling Xiangju Ye Jinghu Zhang Jinfeng Zhang Sujuan Zhang Sugang Meng Xianliang Fu Shifu Chen
author_sort	Cancan Ling
title	Solvothermal synthesis of CdIn2S4 photocatalyst for selective photosynthesis of organic aromatic compounds under visible light
title_short	Solvothermal synthesis of CdIn2S4 photocatalyst for selective photosynthesis of organic aromatic compounds under visible light
title_full	Solvothermal synthesis of CdIn2S4 photocatalyst for selective photosynthesis of organic aromatic compounds under visible light
title_fullStr	Solvothermal synthesis of CdIn2S4 photocatalyst for selective photosynthesis of organic aromatic compounds under visible light
title_full_unstemmed	Solvothermal synthesis of CdIn2S4 photocatalyst for selective photosynthesis of organic aromatic compounds under visible light
title_sort	solvothermal synthesis of cdin2s4 photocatalyst for selective photosynthesis of organic aromatic compounds under visible light
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/02b8db868a31460094fc0e51aa930b5c
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Solvothermal synthesis of CdIn2S4 photocatalyst for selective photosynthesis of organic aromatic compounds under visible light

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