Silver-catalyzed remote Csp3-H functionalization of aliphatic alcohols

Aliphatic alcohols usually require pre-activation for successful functionalization of their carbon chain. Here, the authors report a silver-catalyzed δ-selective functionalization of aliphatic alcohols via Csp3-H bond cleavage under mild conditions without the need of substrate pre-activation.

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Autores principales:	Yuchao Zhu, Kaimeng Huang, Jun Pan, Xu Qiu, Xiao Luo, Qixue Qin, Jialiang Wei, Xiaojin Wen, Lizhi Zhang, Ning Jiao
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/02be461833a44d27a67c30e7211716fe
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spelling	oai:doaj.org-article:02be461833a44d27a67c30e7211716fe2021-12-02T14:40:54ZSilver-catalyzed remote Csp3-H functionalization of aliphatic alcohols10.1038/s41467-018-05014-w2041-1723https://doaj.org/article/02be461833a44d27a67c30e7211716fe2018-07-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-05014-whttps://doaj.org/toc/2041-1723Aliphatic alcohols usually require pre-activation for successful functionalization of their carbon chain. Here, the authors report a silver-catalyzed δ-selective functionalization of aliphatic alcohols via Csp3-H bond cleavage under mild conditions without the need of substrate pre-activation.Yuchao ZhuKaimeng HuangJun PanXu QiuXiao LuoQixue QinJialiang WeiXiaojin WenLizhi ZhangNing JiaoNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-7 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Yuchao Zhu Kaimeng Huang Jun Pan Xu Qiu Xiao Luo Qixue Qin Jialiang Wei Xiaojin Wen Lizhi Zhang Ning Jiao Silver-catalyzed remote Csp3-H functionalization of aliphatic alcohols
description	Aliphatic alcohols usually require pre-activation for successful functionalization of their carbon chain. Here, the authors report a silver-catalyzed δ-selective functionalization of aliphatic alcohols via Csp3-H bond cleavage under mild conditions without the need of substrate pre-activation.
format	article
author	Yuchao Zhu Kaimeng Huang Jun Pan Xu Qiu Xiao Luo Qixue Qin Jialiang Wei Xiaojin Wen Lizhi Zhang Ning Jiao
author_facet	Yuchao Zhu Kaimeng Huang Jun Pan Xu Qiu Xiao Luo Qixue Qin Jialiang Wei Xiaojin Wen Lizhi Zhang Ning Jiao
author_sort	Yuchao Zhu
title	Silver-catalyzed remote Csp3-H functionalization of aliphatic alcohols
title_short	Silver-catalyzed remote Csp3-H functionalization of aliphatic alcohols
title_full	Silver-catalyzed remote Csp3-H functionalization of aliphatic alcohols
title_fullStr	Silver-catalyzed remote Csp3-H functionalization of aliphatic alcohols
title_full_unstemmed	Silver-catalyzed remote Csp3-H functionalization of aliphatic alcohols
title_sort	silver-catalyzed remote csp3-h functionalization of aliphatic alcohols
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/02be461833a44d27a67c30e7211716fe
work_keys_str_mv	AT yuchaozhu silvercatalyzedremotecsp3hfunctionalizationofaliphaticalcohols AT kaimenghuang silvercatalyzedremotecsp3hfunctionalizationofaliphaticalcohols AT junpan silvercatalyzedremotecsp3hfunctionalizationofaliphaticalcohols AT xuqiu silvercatalyzedremotecsp3hfunctionalizationofaliphaticalcohols AT xiaoluo silvercatalyzedremotecsp3hfunctionalizationofaliphaticalcohols AT qixueqin silvercatalyzedremotecsp3hfunctionalizationofaliphaticalcohols AT jialiangwei silvercatalyzedremotecsp3hfunctionalizationofaliphaticalcohols AT xiaojinwen silvercatalyzedremotecsp3hfunctionalizationofaliphaticalcohols AT lizhizhang silvercatalyzedremotecsp3hfunctionalizationofaliphaticalcohols AT ningjiao silvercatalyzedremotecsp3hfunctionalizationofaliphaticalcohols
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Silver-catalyzed remote Csp3-H functionalization of aliphatic alcohols

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