Electrochemical oxidation of ferricyanide

Electrochemical oxidation of ferricyanide

Abstract We report the electrochemical oxidation of ferricyanide, [FeIII(CN)6]3− and characterised the oxidation product by in-situ FTIR and XAS spectroelectrochemistry methods. Oxidation of [FeIII(CN)6]3− is proposed to proceed via a tentative Fe(IV) intermediate that undergoes reduction eliminatio...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: Mun Hon Cheah, Petko Chernev
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
Materias:
Medicine
R
Science
Q
Acceso en línea:https://doaj.org/article/030c16cc045642759be4b5869ca5928c
Etiquetas: Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
id oai:doaj.org-article:030c16cc045642759be4b5869ca5928c
record_format dspace
spelling oai:doaj.org-article:030c16cc045642759be4b5869ca5928c2021-12-05T12:16:10ZElectrochemical oxidation of ferricyanide10.1038/s41598-021-02355-32045-2322https://doaj.org/article/030c16cc045642759be4b5869ca5928c2021-11-01T00:00:00Zhttps://doi.org/10.1038/s41598-021-02355-3https://doaj.org/toc/2045-2322Abstract We report the electrochemical oxidation of ferricyanide, [FeIII(CN)6]3− and characterised the oxidation product by in-situ FTIR and XAS spectroelectrochemistry methods. Oxidation of [FeIII(CN)6]3− is proposed to proceed via a tentative Fe(IV) intermediate that undergoes reduction elimination to give cis-[FeIII(CN)4(CH3CN)2]1− as stable product in acetonitrile. Speciation of the oxidation product by DFT calculations is underpinned by good agreement to experimental data.Mun Hon CheahPetko ChernevNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 11, Iss 1, Pp 1-7 (2021)
institution DOAJ
collection DOAJ
language EN
topic Medicine
R
Science
Q
spellingShingle Medicine
R
Science
Q
Mun Hon Cheah
Petko Chernev
Electrochemical oxidation of ferricyanide
description Abstract We report the electrochemical oxidation of ferricyanide, [FeIII(CN)6]3− and characterised the oxidation product by in-situ FTIR and XAS spectroelectrochemistry methods. Oxidation of [FeIII(CN)6]3− is proposed to proceed via a tentative Fe(IV) intermediate that undergoes reduction elimination to give cis-[FeIII(CN)4(CH3CN)2]1− as stable product in acetonitrile. Speciation of the oxidation product by DFT calculations is underpinned by good agreement to experimental data.
format article
author Mun Hon Cheah
Petko Chernev
author_facet Mun Hon Cheah
Petko Chernev
author_sort Mun Hon Cheah
title Electrochemical oxidation of ferricyanide
title_short Electrochemical oxidation of ferricyanide
title_full Electrochemical oxidation of ferricyanide
title_fullStr Electrochemical oxidation of ferricyanide
title_full_unstemmed Electrochemical oxidation of ferricyanide
title_sort electrochemical oxidation of ferricyanide
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/030c16cc045642759be4b5869ca5928c
work_keys_str_mv AT munhoncheah electrochemicaloxidationofferricyanide
AT petkochernev electrochemicaloxidationofferricyanide
_version_ 1718372055639916544

Ejemplares similares