Micro-raman spectra of Ge–As–Se chalcogenide amorphous powders
Analysis of the Micro-Raman spectra of GexAsxSe1–2x (x = 0.05–0.30) amorphous chalcogenide glasses are reported. The Micro-Raman spectra exhibit three main peaks located at about V= 193, 213, and 255 cm–1. The peaks at around V = 193 and 213 cm–1 can be attributed to the vibrations of GeSe bonds. Th...
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D.Ghitu Institute of Electronic Engineering and Nanotechnologies
2018
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oai:doaj.org-article:0321fcd57b1d4b9b8cdbb517166c0bed2021-11-21T11:56:10ZMicro-raman spectra of Ge–As–Se chalcogenide amorphous powders538.9+539.22537-63651810-648Xhttps://doaj.org/article/0321fcd57b1d4b9b8cdbb517166c0bed2018-12-01T00:00:00Zhttps://mjps.nanotech.md/archive/2018/article/71375https://doaj.org/toc/1810-648Xhttps://doaj.org/toc/2537-6365Analysis of the Micro-Raman spectra of GexAsxSe1–2x (x = 0.05–0.30) amorphous chalcogenide glasses are reported. The Micro-Raman spectra exhibit three main peaks located at about V= 193, 213, and 255 cm–1. The peaks at around V = 193 and 213 cm–1 can be attributed to the vibrations of GeSe bonds. The presence of the Raman peak at about V = 255 cm–1 is attributed to the bond-stretching vibrations of the disordered Se chains and rings. With an increase in the Ge concentration, this peak is shifted to a higher wavenumber due to the shortening of the Se chains. The peak at about V = 300 cm–1 is characteristic of the Ge–Ge vibration mode. It is found that the different Ge concentrations slightly change the shape of the Micro-Raman spectra, mainly the intensity ratio.Iaseniuc, OxanaIovu, MihailGhiulnare, A.Mesterca, RalucaJderu, Alin AlexandruEnăchescu, MariusD.Ghitu Institute of Electronic Engineering and NanotechnologiesarticlePhysicsQC1-999ElectronicsTK7800-8360ENMoldavian Journal of the Physical Sciences, Vol 17, Iss 3-4, Pp 161-166 (2018) |
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Physics QC1-999 Electronics TK7800-8360 Iaseniuc, Oxana Iovu, Mihail Ghiulnare, A. Mesterca, Raluca Jderu, Alin Alexandru Enăchescu, Marius Micro-raman spectra of Ge–As–Se chalcogenide amorphous powders |
description |
Analysis of the Micro-Raman spectra of GexAsxSe1–2x (x = 0.05–0.30) amorphous chalcogenide glasses are reported. The Micro-Raman spectra exhibit three main peaks located at about V= 193, 213, and 255 cm–1. The peaks at around V = 193 and 213 cm–1 can be attributed to the vibrations of GeSe bonds. The presence of the Raman peak at about V = 255 cm–1 is attributed to the bond-stretching vibrations of the disordered Se chains and rings. With an increase in the Ge concentration, this peak is shifted to a higher wavenumber due to the shortening of the Se chains. The peak at about V = 300 cm–1 is characteristic of the Ge–Ge vibration mode. It is found that the different Ge concentrations slightly change the shape of the Micro-Raman spectra, mainly the intensity ratio. |
format |
article |
author |
Iaseniuc, Oxana Iovu, Mihail Ghiulnare, A. Mesterca, Raluca Jderu, Alin Alexandru Enăchescu, Marius |
author_facet |
Iaseniuc, Oxana Iovu, Mihail Ghiulnare, A. Mesterca, Raluca Jderu, Alin Alexandru Enăchescu, Marius |
author_sort |
Iaseniuc, Oxana |
title |
Micro-raman spectra of Ge–As–Se chalcogenide amorphous powders |
title_short |
Micro-raman spectra of Ge–As–Se chalcogenide amorphous powders |
title_full |
Micro-raman spectra of Ge–As–Se chalcogenide amorphous powders |
title_fullStr |
Micro-raman spectra of Ge–As–Se chalcogenide amorphous powders |
title_full_unstemmed |
Micro-raman spectra of Ge–As–Se chalcogenide amorphous powders |
title_sort |
micro-raman spectra of ge–as–se chalcogenide amorphous powders |
publisher |
D.Ghitu Institute of Electronic Engineering and Nanotechnologies |
publishDate |
2018 |
url |
https://doaj.org/article/0321fcd57b1d4b9b8cdbb517166c0bed |
work_keys_str_mv |
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1718419343056830464 |