Immediate hydroxylation of arenes to phenols via V-containing all-silica ZSM-22 zeolite triggered non-radical mechanism
Hydroxylation of arenes via activation of aromatic Csp2–H bond remains a challenge. Here, the authors have managed to get various arenes hydroxylated to corresponding phenols using stoichiometric hydrogen peroxide and a series of robust V–Si–ZSM-22 catalysts synthesized via an ionic liquid involved...
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Nature Portfolio
2018
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oai:doaj.org-article:032d3ab2f1ab440a865646757387ad702021-12-02T15:34:26ZImmediate hydroxylation of arenes to phenols via V-containing all-silica ZSM-22 zeolite triggered non-radical mechanism10.1038/s41467-018-05351-w2041-1723https://doaj.org/article/032d3ab2f1ab440a865646757387ad702018-07-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-05351-whttps://doaj.org/toc/2041-1723Hydroxylation of arenes via activation of aromatic Csp2–H bond remains a challenge. Here, the authors have managed to get various arenes hydroxylated to corresponding phenols using stoichiometric hydrogen peroxide and a series of robust V–Si–ZSM-22 catalysts synthesized via an ionic liquid involved dry-gel-conversion route.Yu ZhouZhipan MaJunjie TangNing YanYonghua DuShibo XiKai WangWei ZhangHaimeng WenJun WangNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-10 (2018) |
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Science Q Yu Zhou Zhipan Ma Junjie Tang Ning Yan Yonghua Du Shibo Xi Kai Wang Wei Zhang Haimeng Wen Jun Wang Immediate hydroxylation of arenes to phenols via V-containing all-silica ZSM-22 zeolite triggered non-radical mechanism |
description |
Hydroxylation of arenes via activation of aromatic Csp2–H bond remains a challenge. Here, the authors have managed to get various arenes hydroxylated to corresponding phenols using stoichiometric hydrogen peroxide and a series of robust V–Si–ZSM-22 catalysts synthesized via an ionic liquid involved dry-gel-conversion route. |
format |
article |
author |
Yu Zhou Zhipan Ma Junjie Tang Ning Yan Yonghua Du Shibo Xi Kai Wang Wei Zhang Haimeng Wen Jun Wang |
author_facet |
Yu Zhou Zhipan Ma Junjie Tang Ning Yan Yonghua Du Shibo Xi Kai Wang Wei Zhang Haimeng Wen Jun Wang |
author_sort |
Yu Zhou |
title |
Immediate hydroxylation of arenes to phenols via V-containing all-silica ZSM-22 zeolite triggered non-radical mechanism |
title_short |
Immediate hydroxylation of arenes to phenols via V-containing all-silica ZSM-22 zeolite triggered non-radical mechanism |
title_full |
Immediate hydroxylation of arenes to phenols via V-containing all-silica ZSM-22 zeolite triggered non-radical mechanism |
title_fullStr |
Immediate hydroxylation of arenes to phenols via V-containing all-silica ZSM-22 zeolite triggered non-radical mechanism |
title_full_unstemmed |
Immediate hydroxylation of arenes to phenols via V-containing all-silica ZSM-22 zeolite triggered non-radical mechanism |
title_sort |
immediate hydroxylation of arenes to phenols via v-containing all-silica zsm-22 zeolite triggered non-radical mechanism |
publisher |
Nature Portfolio |
publishDate |
2018 |
url |
https://doaj.org/article/032d3ab2f1ab440a865646757387ad70 |
work_keys_str_mv |
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_version_ |
1718386819872063488 |