Deazaflavin reductive photocatalysis involves excited semiquinone radicals

Flavins and deazaflavins are well suited for photoredox processes but their application in photoreductions is challenging. Here, the authors provide direct evidence of the high reductive power of excited deazaflavin semiquinones and their application in catalytic photodehalogenations.

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Autores principales:	Andreas Graml, Tomáš Neveselý, Roger Jan Kutta, Radek Cibulka, Burkhard König
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/036b9a58c65b47d5b79a52544327e4f1
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spelling	oai:doaj.org-article:036b9a58c65b47d5b79a52544327e4f12021-12-02T18:02:47ZDeazaflavin reductive photocatalysis involves excited semiquinone radicals10.1038/s41467-020-16909-y2041-1723https://doaj.org/article/036b9a58c65b47d5b79a52544327e4f12020-06-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-16909-yhttps://doaj.org/toc/2041-1723Flavins and deazaflavins are well suited for photoredox processes but their application in photoreductions is challenging. Here, the authors provide direct evidence of the high reductive power of excited deazaflavin semiquinones and their application in catalytic photodehalogenations.Andreas GramlTomáš NeveselýRoger Jan KuttaRadek CibulkaBurkhard KönigNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-11 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Andreas Graml Tomáš Neveselý Roger Jan Kutta Radek Cibulka Burkhard König Deazaflavin reductive photocatalysis involves excited semiquinone radicals
description	Flavins and deazaflavins are well suited for photoredox processes but their application in photoreductions is challenging. Here, the authors provide direct evidence of the high reductive power of excited deazaflavin semiquinones and their application in catalytic photodehalogenations.
format	article
author	Andreas Graml Tomáš Neveselý Roger Jan Kutta Radek Cibulka Burkhard König
author_facet	Andreas Graml Tomáš Neveselý Roger Jan Kutta Radek Cibulka Burkhard König
author_sort	Andreas Graml
title	Deazaflavin reductive photocatalysis involves excited semiquinone radicals
title_short	Deazaflavin reductive photocatalysis involves excited semiquinone radicals
title_full	Deazaflavin reductive photocatalysis involves excited semiquinone radicals
title_fullStr	Deazaflavin reductive photocatalysis involves excited semiquinone radicals
title_full_unstemmed	Deazaflavin reductive photocatalysis involves excited semiquinone radicals
title_sort	deazaflavin reductive photocatalysis involves excited semiquinone radicals
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/036b9a58c65b47d5b79a52544327e4f1
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Deazaflavin reductive photocatalysis involves excited semiquinone radicals

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