Deazaflavin reductive photocatalysis involves excited semiquinone radicals

Deazaflavin reductive photocatalysis involves excited semiquinone radicals

Flavins and deazaflavins are well suited for photoredox processes but their application in photoreductions is challenging. Here, the authors provide direct evidence of the high reductive power of excited deazaflavin semiquinones and their application in catalytic photodehalogenations.

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Auteurs principaux: Andreas Graml, Tomáš Neveselý, Roger Jan Kutta, Radek Cibulka, Burkhard König
Format: article
Langue:EN
Publié: Nature Portfolio 2020
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Science
Q
Accès en ligne:https://doaj.org/article/036b9a58c65b47d5b79a52544327e4f1
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spelling oai:doaj.org-article:036b9a58c65b47d5b79a52544327e4f12021-12-02T18:02:47ZDeazaflavin reductive photocatalysis involves excited semiquinone radicals10.1038/s41467-020-16909-y2041-1723https://doaj.org/article/036b9a58c65b47d5b79a52544327e4f12020-06-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-16909-yhttps://doaj.org/toc/2041-1723Flavins and deazaflavins are well suited for photoredox processes but their application in photoreductions is challenging. Here, the authors provide direct evidence of the high reductive power of excited deazaflavin semiquinones and their application in catalytic photodehalogenations.Andreas GramlTomáš NeveselýRoger Jan KuttaRadek CibulkaBurkhard KönigNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-11 (2020)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Andreas Graml
Tomáš Neveselý
Roger Jan Kutta
Radek Cibulka
Burkhard König
Deazaflavin reductive photocatalysis involves excited semiquinone radicals
description Flavins and deazaflavins are well suited for photoredox processes but their application in photoreductions is challenging. Here, the authors provide direct evidence of the high reductive power of excited deazaflavin semiquinones and their application in catalytic photodehalogenations.
format article
author Andreas Graml
Tomáš Neveselý
Roger Jan Kutta
Radek Cibulka
Burkhard König
author_facet Andreas Graml
Tomáš Neveselý
Roger Jan Kutta
Radek Cibulka
Burkhard König
author_sort Andreas Graml
title Deazaflavin reductive photocatalysis involves excited semiquinone radicals
title_short Deazaflavin reductive photocatalysis involves excited semiquinone radicals
title_full Deazaflavin reductive photocatalysis involves excited semiquinone radicals
title_fullStr Deazaflavin reductive photocatalysis involves excited semiquinone radicals
title_full_unstemmed Deazaflavin reductive photocatalysis involves excited semiquinone radicals
title_sort deazaflavin reductive photocatalysis involves excited semiquinone radicals
publisher Nature Portfolio
publishDate 2020
url https://doaj.org/article/036b9a58c65b47d5b79a52544327e4f1
work_keys_str_mv AT andreasgraml deazaflavinreductivephotocatalysisinvolvesexcitedsemiquinoneradicals
AT tomasnevesely deazaflavinreductivephotocatalysisinvolvesexcitedsemiquinoneradicals
AT rogerjankutta deazaflavinreductivephotocatalysisinvolvesexcitedsemiquinoneradicals
AT radekcibulka deazaflavinreductivephotocatalysisinvolvesexcitedsemiquinoneradicals
AT burkhardkonig deazaflavinreductivephotocatalysisinvolvesexcitedsemiquinoneradicals
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