Deazaflavin reductive photocatalysis involves excited semiquinone radicals

Flavins and deazaflavins are well suited for photoredox processes but their application in photoreductions is challenging. Here, the authors provide direct evidence of the high reductive power of excited deazaflavin semiquinones and their application in catalytic photodehalogenations.

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Bibliographic Details
Main Authors: Andreas Graml, Tomáš Neveselý, Roger Jan Kutta, Radek Cibulka, Burkhard König
Format: article
Language:EN
Published: Nature Portfolio 2020
Subjects:
Q
Online Access:https://doaj.org/article/036b9a58c65b47d5b79a52544327e4f1
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