Deazaflavin reductive photocatalysis involves excited semiquinone radicals
Flavins and deazaflavins are well suited for photoredox processes but their application in photoreductions is challenging. Here, the authors provide direct evidence of the high reductive power of excited deazaflavin semiquinones and their application in catalytic photodehalogenations.
Enregistré dans:
Auteurs principaux: | Andreas Graml, Tomáš Neveselý, Roger Jan Kutta, Radek Cibulka, Burkhard König |
---|---|
Format: | article |
Langue: | EN |
Publié: |
Nature Portfolio
2020
|
Sujets: | |
Accès en ligne: | https://doaj.org/article/036b9a58c65b47d5b79a52544327e4f1 |
Tags: |
Ajouter un tag
Pas de tags, Soyez le premier à ajouter un tag!
|
Documents similaires
-
Profile of Semiquinone Radicals, Phytohormones and Sugars in <i>Pistacia vera</i> L. cv. Kirmizi Development
par: Iwona Morkunas, et autres
Publié: (2021) -
Evidence and implications of direct charge excitation as the dominant mechanism in plasmon-mediated photocatalysis
par: Calvin Boerigter, et autres
Publié: (2016) -
The semiquinone swing in the bifurcating electron transferring flavoprotein/butyryl-CoA dehydrogenase complex from Clostridium difficile
par: Julius K. Demmer, et autres
Publié: (2017) -
Dichloromethylation of enones by carbon nitride photocatalysis
par: Stefano Mazzanti, et autres
Publié: (2020) -
Application of Spinel and Hexagonal Ferrites in Heterogeneous Photocatalysis
par: Zuzanna Bielan, et autres
Publié: (2021)