trans-Bis[8-(benzylsulfanyl)quinoline-κ2N,S]dichloridocobalt(II)

The title dichlorocobalt(II) complex, trans-[CoCl2(1)2] [1 = 8-(benzylsulfanyl)quinoline, C16H13NS], has a central CoII atom (site symmetry \overline1) that exhibits a distorted octahedral coordination geometry and is coordinated by two N and two S atoms from the bidentate N,S-ligand (1) situated in...

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Autores principales:	Shintaro Kodama, Kazuki Bunno, Akihiro Nomoto, Akiya Ogawa
Formato:	article
Lenguaje:	EN
Publicado:	International Union of Crystallography 2021
Materias:	crystal structure cobalt(ii) complex bidentate n,s-ligand Crystallography QD901-999
Acceso en línea:	https://doaj.org/article/03b4b88c6cd14aa9b822ccda0670d853
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id	oai:doaj.org-article:03b4b88c6cd14aa9b822ccda0670d853
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spelling	oai:doaj.org-article:03b4b88c6cd14aa9b822ccda0670d8532021-11-12T12:26:16Ztrans-Bis[8-(benzylsulfanyl)quinoline-κ2N,S]dichloridocobalt(II)2414-314610.1107/S2414314621009925https://doaj.org/article/03b4b88c6cd14aa9b822ccda0670d8532021-10-01T00:00:00Zhttp://scripts.iucr.org/cgi-bin/paper?S2414314621009925https://doaj.org/toc/2414-3146The title dichlorocobalt(II) complex, trans-[CoCl2(1)2] [1 = 8-(benzylsulfanyl)quinoline, C16H13NS], has a central CoII atom (site symmetry \overline1) that exhibits a distorted octahedral coordination geometry and is coordinated by two N and two S atoms from the bidentate N,S-ligand (1) situated in an equatorial plane and two Cl atoms in the axial positions. Complexes are linked by weak intermolecular C—H...π interactions between the 8-(benzylsulfanyl)quinoline ligands, forming a chain extending along the a-axis direction.Shintaro KodamaKazuki BunnoAkihiro NomotoAkiya OgawaInternational Union of Crystallographyarticlecrystal structurecobalt(ii) complexbidentate n,s-ligandCrystallographyQD901-999ENIUCrData, Vol 6, Iss 10, p x210992 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	crystal structure cobalt(ii) complex bidentate n,s-ligand Crystallography QD901-999
spellingShingle	crystal structure cobalt(ii) complex bidentate n,s-ligand Crystallography QD901-999 Shintaro Kodama Kazuki Bunno Akihiro Nomoto Akiya Ogawa trans-Bis[8-(benzylsulfanyl)quinoline-κ2N,S]dichloridocobalt(II)
description	The title dichlorocobalt(II) complex, trans-[CoCl2(1)2] [1 = 8-(benzylsulfanyl)quinoline, C16H13NS], has a central CoII atom (site symmetry \overline1) that exhibits a distorted octahedral coordination geometry and is coordinated by two N and two S atoms from the bidentate N,S-ligand (1) situated in an equatorial plane and two Cl atoms in the axial positions. Complexes are linked by weak intermolecular C—H...π interactions between the 8-(benzylsulfanyl)quinoline ligands, forming a chain extending along the a-axis direction.
format	article
author	Shintaro Kodama Kazuki Bunno Akihiro Nomoto Akiya Ogawa
author_facet	Shintaro Kodama Kazuki Bunno Akihiro Nomoto Akiya Ogawa
author_sort	Shintaro Kodama
title	trans-Bis[8-(benzylsulfanyl)quinoline-κ2N,S]dichloridocobalt(II)
title_short	trans-Bis[8-(benzylsulfanyl)quinoline-κ2N,S]dichloridocobalt(II)
title_full	trans-Bis[8-(benzylsulfanyl)quinoline-κ2N,S]dichloridocobalt(II)
title_fullStr	trans-Bis[8-(benzylsulfanyl)quinoline-κ2N,S]dichloridocobalt(II)
title_full_unstemmed	trans-Bis[8-(benzylsulfanyl)quinoline-κ2N,S]dichloridocobalt(II)
title_sort	trans-bis[8-(benzylsulfanyl)quinoline-κ2n,s]dichloridocobalt(ii)
publisher	International Union of Crystallography
publishDate	2021
url	https://doaj.org/article/03b4b88c6cd14aa9b822ccda0670d853
work_keys_str_mv	AT shintarokodama transbis8benzylsulfanylquinolinek2nsdichloridocobaltii AT kazukibunno transbis8benzylsulfanylquinolinek2nsdichloridocobaltii AT akihironomoto transbis8benzylsulfanylquinolinek2nsdichloridocobaltii AT akiyaogawa transbis8benzylsulfanylquinolinek2nsdichloridocobaltii
_version_	1718430475287003136

trans-Bis[8-(benzylsulfanyl)quinoline-κ2N,S]dichloridocobalt(II)

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