Organocatalytic atroposelective construction of axially chiral arylquinones
Axially chiral compounds have widespread use in asymmetric catalysis. Here, the authors disclose a highly enantioselective synthesis of axially chiral o-naphthoquinones by chiral phosphoric acid catalysis and central-to-axial chirality conversion.
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Nature Portfolio
2019
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oai:doaj.org-article:03c6732f031d4be7b207e6e3dc60046e2021-12-02T17:02:16ZOrganocatalytic atroposelective construction of axially chiral arylquinones10.1038/s41467-019-12269-42041-1723https://doaj.org/article/03c6732f031d4be7b207e6e3dc60046e2019-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-12269-4https://doaj.org/toc/2041-1723Axially chiral compounds have widespread use in asymmetric catalysis. Here, the authors disclose a highly enantioselective synthesis of axially chiral o-naphthoquinones by chiral phosphoric acid catalysis and central-to-axial chirality conversion.Shuai ZhuYe-Hui ChenYong-Bin WangPeiyuan YuShao-Yu LiShao-Hua XiangJun-Qi WangJian XiaoBin TanNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-10 (2019) |
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Science Q Shuai Zhu Ye-Hui Chen Yong-Bin Wang Peiyuan Yu Shao-Yu Li Shao-Hua Xiang Jun-Qi Wang Jian Xiao Bin Tan Organocatalytic atroposelective construction of axially chiral arylquinones |
description |
Axially chiral compounds have widespread use in asymmetric catalysis. Here, the authors disclose a highly enantioselective synthesis of axially chiral o-naphthoquinones by chiral phosphoric acid catalysis and central-to-axial chirality conversion. |
format |
article |
author |
Shuai Zhu Ye-Hui Chen Yong-Bin Wang Peiyuan Yu Shao-Yu Li Shao-Hua Xiang Jun-Qi Wang Jian Xiao Bin Tan |
author_facet |
Shuai Zhu Ye-Hui Chen Yong-Bin Wang Peiyuan Yu Shao-Yu Li Shao-Hua Xiang Jun-Qi Wang Jian Xiao Bin Tan |
author_sort |
Shuai Zhu |
title |
Organocatalytic atroposelective construction of axially chiral arylquinones |
title_short |
Organocatalytic atroposelective construction of axially chiral arylquinones |
title_full |
Organocatalytic atroposelective construction of axially chiral arylquinones |
title_fullStr |
Organocatalytic atroposelective construction of axially chiral arylquinones |
title_full_unstemmed |
Organocatalytic atroposelective construction of axially chiral arylquinones |
title_sort |
organocatalytic atroposelective construction of axially chiral arylquinones |
publisher |
Nature Portfolio |
publishDate |
2019 |
url |
https://doaj.org/article/03c6732f031d4be7b207e6e3dc60046e |
work_keys_str_mv |
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1718381888801865728 |