Organocatalytic atroposelective construction of axially chiral arylquinones

Axially chiral compounds have widespread use in asymmetric catalysis. Here, the authors disclose a highly enantioselective synthesis of axially chiral o-naphthoquinones by chiral phosphoric acid catalysis and central-to-axial chirality conversion.

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Autores principales: Shuai Zhu, Ye-Hui Chen, Yong-Bin Wang, Peiyuan Yu, Shao-Yu Li, Shao-Hua Xiang, Jun-Qi Wang, Jian Xiao, Bin Tan
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/03c6732f031d4be7b207e6e3dc60046e
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spelling oai:doaj.org-article:03c6732f031d4be7b207e6e3dc60046e2021-12-02T17:02:16ZOrganocatalytic atroposelective construction of axially chiral arylquinones10.1038/s41467-019-12269-42041-1723https://doaj.org/article/03c6732f031d4be7b207e6e3dc60046e2019-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-12269-4https://doaj.org/toc/2041-1723Axially chiral compounds have widespread use in asymmetric catalysis. Here, the authors disclose a highly enantioselective synthesis of axially chiral o-naphthoquinones by chiral phosphoric acid catalysis and central-to-axial chirality conversion.Shuai ZhuYe-Hui ChenYong-Bin WangPeiyuan YuShao-Yu LiShao-Hua XiangJun-Qi WangJian XiaoBin TanNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-10 (2019)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Shuai Zhu
Ye-Hui Chen
Yong-Bin Wang
Peiyuan Yu
Shao-Yu Li
Shao-Hua Xiang
Jun-Qi Wang
Jian Xiao
Bin Tan
Organocatalytic atroposelective construction of axially chiral arylquinones
description Axially chiral compounds have widespread use in asymmetric catalysis. Here, the authors disclose a highly enantioselective synthesis of axially chiral o-naphthoquinones by chiral phosphoric acid catalysis and central-to-axial chirality conversion.
format article
author Shuai Zhu
Ye-Hui Chen
Yong-Bin Wang
Peiyuan Yu
Shao-Yu Li
Shao-Hua Xiang
Jun-Qi Wang
Jian Xiao
Bin Tan
author_facet Shuai Zhu
Ye-Hui Chen
Yong-Bin Wang
Peiyuan Yu
Shao-Yu Li
Shao-Hua Xiang
Jun-Qi Wang
Jian Xiao
Bin Tan
author_sort Shuai Zhu
title Organocatalytic atroposelective construction of axially chiral arylquinones
title_short Organocatalytic atroposelective construction of axially chiral arylquinones
title_full Organocatalytic atroposelective construction of axially chiral arylquinones
title_fullStr Organocatalytic atroposelective construction of axially chiral arylquinones
title_full_unstemmed Organocatalytic atroposelective construction of axially chiral arylquinones
title_sort organocatalytic atroposelective construction of axially chiral arylquinones
publisher Nature Portfolio
publishDate 2019
url https://doaj.org/article/03c6732f031d4be7b207e6e3dc60046e
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AT yongbinwang organocatalyticatroposelectiveconstructionofaxiallychiralarylquinones
AT peiyuanyu organocatalyticatroposelectiveconstructionofaxiallychiralarylquinones
AT shaoyuli organocatalyticatroposelectiveconstructionofaxiallychiralarylquinones
AT shaohuaxiang organocatalyticatroposelectiveconstructionofaxiallychiralarylquinones
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