Surface Modification of a Nickel-Free Austenitic Stainless Steel by Low-Temperature Nitriding

Low-temperature nitriding allows to improve surface hardening of austenitic stainless steels, maintaining or even increasing their corrosion resistance. The treatment conditions to be used in order to avoid the precipitation of large amounts of nitrides are strictly related to alloy composition. Whe...

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Autores principales: Francesca Borgioli, Emanuele Galvanetto, Tiberio Bacci
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Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:03ef088c9baa456fb1debabb51e96a142021-11-25T18:22:21ZSurface Modification of a Nickel-Free Austenitic Stainless Steel by Low-Temperature Nitriding10.3390/met111118452075-4701https://doaj.org/article/03ef088c9baa456fb1debabb51e96a142021-11-01T00:00:00Zhttps://www.mdpi.com/2075-4701/11/11/1845https://doaj.org/toc/2075-4701Low-temperature nitriding allows to improve surface hardening of austenitic stainless steels, maintaining or even increasing their corrosion resistance. The treatment conditions to be used in order to avoid the precipitation of large amounts of nitrides are strictly related to alloy composition. When nickel is substituted by manganese as an austenite forming element, the production of nitride-free modified surface layers becomes a challenge, since manganese is a nitride forming element while nickel is not. In this study, the effects of nitriding conditions on the characteristics of the modified surface layers obtained on an austenitic stainless steel having a high manganese content and a negligible nickel one, a so-called nickel-free austenitic stainless steel, were investigated. Microstructure, phase composition, surface microhardness, and corrosion behavior in 5% NaCl were evaluated. The obtained results suggest that the precipitation of a large volume fraction of nitrides can be avoided using treatment temperatures lower than those usually employed for nickel-containing austenitic stainless steels. Nitriding at 360 and 380 °C for duration up to 5 h allows to produce modified surface layers, consisting mainly of the so-called expanded austenite or γ<sub>N</sub>, which increase surface hardness in comparison with the untreated steel. Using selected conditions, corrosion resistance can also be significantly improved.Francesca BorgioliEmanuele GalvanettoTiberio BacciMDPI AGarticleaustenitic stainless steelsNi-free austenitic stainless steelslow-temperature nitridingexpanded austeniteS-phasehardeningMining engineering. MetallurgyTN1-997ENMetals, Vol 11, Iss 1845, p 1845 (2021)
institution DOAJ
collection DOAJ
language EN
topic austenitic stainless steels
Ni-free austenitic stainless steels
low-temperature nitriding
expanded austenite
S-phase
hardening
Mining engineering. Metallurgy
TN1-997
spellingShingle austenitic stainless steels
Ni-free austenitic stainless steels
low-temperature nitriding
expanded austenite
S-phase
hardening
Mining engineering. Metallurgy
TN1-997
Francesca Borgioli
Emanuele Galvanetto
Tiberio Bacci
Surface Modification of a Nickel-Free Austenitic Stainless Steel by Low-Temperature Nitriding
description Low-temperature nitriding allows to improve surface hardening of austenitic stainless steels, maintaining or even increasing their corrosion resistance. The treatment conditions to be used in order to avoid the precipitation of large amounts of nitrides are strictly related to alloy composition. When nickel is substituted by manganese as an austenite forming element, the production of nitride-free modified surface layers becomes a challenge, since manganese is a nitride forming element while nickel is not. In this study, the effects of nitriding conditions on the characteristics of the modified surface layers obtained on an austenitic stainless steel having a high manganese content and a negligible nickel one, a so-called nickel-free austenitic stainless steel, were investigated. Microstructure, phase composition, surface microhardness, and corrosion behavior in 5% NaCl were evaluated. The obtained results suggest that the precipitation of a large volume fraction of nitrides can be avoided using treatment temperatures lower than those usually employed for nickel-containing austenitic stainless steels. Nitriding at 360 and 380 °C for duration up to 5 h allows to produce modified surface layers, consisting mainly of the so-called expanded austenite or γ<sub>N</sub>, which increase surface hardness in comparison with the untreated steel. Using selected conditions, corrosion resistance can also be significantly improved.
format article
author Francesca Borgioli
Emanuele Galvanetto
Tiberio Bacci
author_facet Francesca Borgioli
Emanuele Galvanetto
Tiberio Bacci
author_sort Francesca Borgioli
title Surface Modification of a Nickel-Free Austenitic Stainless Steel by Low-Temperature Nitriding
title_short Surface Modification of a Nickel-Free Austenitic Stainless Steel by Low-Temperature Nitriding
title_full Surface Modification of a Nickel-Free Austenitic Stainless Steel by Low-Temperature Nitriding
title_fullStr Surface Modification of a Nickel-Free Austenitic Stainless Steel by Low-Temperature Nitriding
title_full_unstemmed Surface Modification of a Nickel-Free Austenitic Stainless Steel by Low-Temperature Nitriding
title_sort surface modification of a nickel-free austenitic stainless steel by low-temperature nitriding
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/03ef088c9baa456fb1debabb51e96a14
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AT tiberiobacci surfacemodificationofanickelfreeausteniticstainlesssteelbylowtemperaturenitriding
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