Environmental Analysis of Hydrothermal Decomposition of Melamine Etherified Resin Fibre

Plastic waste presents a significant problem for the environment as significant amounts of plastics are produced, of which the majority are still landfilled contaminating soils, waterways and aquifers. A particular challenge present thermoset plastic material, which are more difficult to recycle com...

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Autores principales: Timotej Vidovic, Maja Colnik, Mojca Škerget, Lidija Cucek, Damjan Krajnc, Jan Puhar, Annamaria Vujanovic
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Publicado: AIDIC Servizi S.r.l. 2021
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spelling oai:doaj.org-article:047c7922487a49228536bee9bf86ce9b2021-11-15T21:47:08ZEnvironmental Analysis of Hydrothermal Decomposition of Melamine Etherified Resin Fibre10.3303/CET21881832283-9216https://doaj.org/article/047c7922487a49228536bee9bf86ce9b2021-11-01T00:00:00Zhttps://www.cetjournal.it/index.php/cet/article/view/11976https://doaj.org/toc/2283-9216Plastic waste presents a significant problem for the environment as significant amounts of plastics are produced, of which the majority are still landfilled contaminating soils, waterways and aquifers. A particular challenge present thermoset plastic material, which are more difficult to recycle compared to thermoplastic materials. One of these thermoset materials are melamine resins, noted for their heat resistance and stable structure, but usually disposed in landfills after the end of their life cycle. Hydrothermal processes present a promising method to tackle the issue of reprocessing thermoset materials, as they utilize water at high temperature and pressure to convert plastic waste into useful materials. Hydrothermal decomposition of melamine etherified resin (MER) fibres is studied in this work. The reaction occurs in a hydrothermal reactor with water at subcritical conditions. The aqueous phase extracted from the post reaction mixture was analysed using tube tests for the contents of formaldehyde, organic acid, total nitrogen, and ammonium. Environmental footprints are further analyzed based on the data obtained from experimental work, and compared regarding three different decomposition temperatures: 200, 300 and 350 °C. Footprint assessment is performed mainly using OpenLCA software and various databases. Environmental comparison of the processes is evaluated regarding to greenhouse gas (GHG), nitrogen, phosphorus, energy, and ecological footprints, and human toxicity potential. Results show that decomposition at 200 °C yielded the lowest environmental impacts. However, the highest amounts of secondary compounds were obtained when conducting the process at 300 °C.Timotej VidovicMaja ColnikMojca ŠkergetLidija CucekDamjan KrajncJan PuharAnnamaria VujanovicAIDIC Servizi S.r.l.articleChemical engineeringTP155-156Computer engineering. Computer hardwareTK7885-7895ENChemical Engineering Transactions, Vol 88 (2021)
institution DOAJ
collection DOAJ
language EN
topic Chemical engineering
TP155-156
Computer engineering. Computer hardware
TK7885-7895
spellingShingle Chemical engineering
TP155-156
Computer engineering. Computer hardware
TK7885-7895
Timotej Vidovic
Maja Colnik
Mojca Škerget
Lidija Cucek
Damjan Krajnc
Jan Puhar
Annamaria Vujanovic
Environmental Analysis of Hydrothermal Decomposition of Melamine Etherified Resin Fibre
description Plastic waste presents a significant problem for the environment as significant amounts of plastics are produced, of which the majority are still landfilled contaminating soils, waterways and aquifers. A particular challenge present thermoset plastic material, which are more difficult to recycle compared to thermoplastic materials. One of these thermoset materials are melamine resins, noted for their heat resistance and stable structure, but usually disposed in landfills after the end of their life cycle. Hydrothermal processes present a promising method to tackle the issue of reprocessing thermoset materials, as they utilize water at high temperature and pressure to convert plastic waste into useful materials. Hydrothermal decomposition of melamine etherified resin (MER) fibres is studied in this work. The reaction occurs in a hydrothermal reactor with water at subcritical conditions. The aqueous phase extracted from the post reaction mixture was analysed using tube tests for the contents of formaldehyde, organic acid, total nitrogen, and ammonium. Environmental footprints are further analyzed based on the data obtained from experimental work, and compared regarding three different decomposition temperatures: 200, 300 and 350 °C. Footprint assessment is performed mainly using OpenLCA software and various databases. Environmental comparison of the processes is evaluated regarding to greenhouse gas (GHG), nitrogen, phosphorus, energy, and ecological footprints, and human toxicity potential. Results show that decomposition at 200 °C yielded the lowest environmental impacts. However, the highest amounts of secondary compounds were obtained when conducting the process at 300 °C.
format article
author Timotej Vidovic
Maja Colnik
Mojca Škerget
Lidija Cucek
Damjan Krajnc
Jan Puhar
Annamaria Vujanovic
author_facet Timotej Vidovic
Maja Colnik
Mojca Škerget
Lidija Cucek
Damjan Krajnc
Jan Puhar
Annamaria Vujanovic
author_sort Timotej Vidovic
title Environmental Analysis of Hydrothermal Decomposition of Melamine Etherified Resin Fibre
title_short Environmental Analysis of Hydrothermal Decomposition of Melamine Etherified Resin Fibre
title_full Environmental Analysis of Hydrothermal Decomposition of Melamine Etherified Resin Fibre
title_fullStr Environmental Analysis of Hydrothermal Decomposition of Melamine Etherified Resin Fibre
title_full_unstemmed Environmental Analysis of Hydrothermal Decomposition of Melamine Etherified Resin Fibre
title_sort environmental analysis of hydrothermal decomposition of melamine etherified resin fibre
publisher AIDIC Servizi S.r.l.
publishDate 2021
url https://doaj.org/article/047c7922487a49228536bee9bf86ce9b
work_keys_str_mv AT timotejvidovic environmentalanalysisofhydrothermaldecompositionofmelamineetherifiedresinfibre
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AT lidijacucek environmentalanalysisofhydrothermaldecompositionofmelamineetherifiedresinfibre
AT damjankrajnc environmentalanalysisofhydrothermaldecompositionofmelamineetherifiedresinfibre
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