Synthesis and reactivity of a mononuclear non-haem cobalt(IV)-oxo complex

Terminal CoIV-oxo species are key intermediates in various cobalt-mediated oxidation reactions, but little is known about their chemical properties. Here the authors generate and isolate a mononuclear non-haem CoIV-O complex and analyse its structure and reactivity towards a range of catalytic trans...

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Autores principales: Bin Wang, Yong-Min Lee, Woon-Young Tcho, Samat Tussupbayev, Seoung-Tae Kim, Yujeong Kim, Mi Sook Seo, Kyung-Bin Cho, Yavuz Dede, Brenna C. Keegan, Takashi Ogura, Sun Hee Kim, Takehiro Ohta, Mu-Hyun Baik, Kallol Ray, Jason Shearer, Wonwoo Nam
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Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/0480483a6b9947aabc3c1dc9cca048dd
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spelling oai:doaj.org-article:0480483a6b9947aabc3c1dc9cca048dd2021-12-02T17:06:11ZSynthesis and reactivity of a mononuclear non-haem cobalt(IV)-oxo complex10.1038/ncomms148392041-1723https://doaj.org/article/0480483a6b9947aabc3c1dc9cca048dd2017-03-01T00:00:00Zhttps://doi.org/10.1038/ncomms14839https://doaj.org/toc/2041-1723Terminal CoIV-oxo species are key intermediates in various cobalt-mediated oxidation reactions, but little is known about their chemical properties. Here the authors generate and isolate a mononuclear non-haem CoIV-O complex and analyse its structure and reactivity towards a range of catalytic transformations.Bin WangYong-Min LeeWoon-Young TchoSamat TussupbayevSeoung-Tae KimYujeong KimMi Sook SeoKyung-Bin ChoYavuz DedeBrenna C. KeeganTakashi OguraSun Hee KimTakehiro OhtaMu-Hyun BaikKallol RayJason ShearerWonwoo NamNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-10 (2017)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Bin Wang
Yong-Min Lee
Woon-Young Tcho
Samat Tussupbayev
Seoung-Tae Kim
Yujeong Kim
Mi Sook Seo
Kyung-Bin Cho
Yavuz Dede
Brenna C. Keegan
Takashi Ogura
Sun Hee Kim
Takehiro Ohta
Mu-Hyun Baik
Kallol Ray
Jason Shearer
Wonwoo Nam
Synthesis and reactivity of a mononuclear non-haem cobalt(IV)-oxo complex
description Terminal CoIV-oxo species are key intermediates in various cobalt-mediated oxidation reactions, but little is known about their chemical properties. Here the authors generate and isolate a mononuclear non-haem CoIV-O complex and analyse its structure and reactivity towards a range of catalytic transformations.
format article
author Bin Wang
Yong-Min Lee
Woon-Young Tcho
Samat Tussupbayev
Seoung-Tae Kim
Yujeong Kim
Mi Sook Seo
Kyung-Bin Cho
Yavuz Dede
Brenna C. Keegan
Takashi Ogura
Sun Hee Kim
Takehiro Ohta
Mu-Hyun Baik
Kallol Ray
Jason Shearer
Wonwoo Nam
author_facet Bin Wang
Yong-Min Lee
Woon-Young Tcho
Samat Tussupbayev
Seoung-Tae Kim
Yujeong Kim
Mi Sook Seo
Kyung-Bin Cho
Yavuz Dede
Brenna C. Keegan
Takashi Ogura
Sun Hee Kim
Takehiro Ohta
Mu-Hyun Baik
Kallol Ray
Jason Shearer
Wonwoo Nam
author_sort Bin Wang
title Synthesis and reactivity of a mononuclear non-haem cobalt(IV)-oxo complex
title_short Synthesis and reactivity of a mononuclear non-haem cobalt(IV)-oxo complex
title_full Synthesis and reactivity of a mononuclear non-haem cobalt(IV)-oxo complex
title_fullStr Synthesis and reactivity of a mononuclear non-haem cobalt(IV)-oxo complex
title_full_unstemmed Synthesis and reactivity of a mononuclear non-haem cobalt(IV)-oxo complex
title_sort synthesis and reactivity of a mononuclear non-haem cobalt(iv)-oxo complex
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/0480483a6b9947aabc3c1dc9cca048dd
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