Progress and perspective of the cathode/electrolyte interface construction in all‐solid‐state lithium batteries

Abstract Security risks of flammability and explosion represent major problems with the use of conventional lithium rechargeable batteries using a liquid electrolyte. The application of solid‐state electrolytes could effectively help to avoid these safety concerns. However, integrating the solid‐sta...

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Autores principales: Shiming Su, Jiabin Ma, Liang Zhao, Kui Lin, Qidong Li, Shasha Lv, Feiyu Kang, Yan‐Bing He
Formato: article
Lenguaje:EN
Publicado: Wiley 2021
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Acceso en línea:https://doaj.org/article/04997cf474014176a1615c299d8125b0
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spelling oai:doaj.org-article:04997cf474014176a1615c299d8125b02021-11-24T14:45:30ZProgress and perspective of the cathode/electrolyte interface construction in all‐solid‐state lithium batteries2637-936810.1002/cey2.129https://doaj.org/article/04997cf474014176a1615c299d8125b02021-11-01T00:00:00Zhttps://doi.org/10.1002/cey2.129https://doaj.org/toc/2637-9368Abstract Security risks of flammability and explosion represent major problems with the use of conventional lithium rechargeable batteries using a liquid electrolyte. The application of solid‐state electrolytes could effectively help to avoid these safety concerns. However, integrating the solid‐state electrolytes into the all‐solid‐state lithium batteries is still a huge challenge mainly due to the high interfacial resistance present in the entire battery, especially at the interface between the cathode and the solid‐state electrolyte pellet and the interfaces inside the cathode. Herein, recent progress made from investigations of cathode/solid‐state electrolyte interfacial behaviors including the contact problem, the interlayer diffusion issue, the space‐charge layer effect, and electrochemical compatibility is presented according to the classification of oxide‐, sulfide‐, and polymer‐based solid‐state electrolytes. We also propose strategies for the construction of ideal next‐generation cathode/solid‐state electrolyte interfaces with high room‐temperature ionic conductivity, stable interfacial contact during long cycling, free formation of the space‐charge region, and good compatibility with high‐voltage cathodes.Shiming SuJiabin MaLiang ZhaoKui LinQidong LiShasha LvFeiyu KangYan‐Bing HeWileyarticlecathode configuration designinterfacelithium batterysolid‐state electrolyteProduction of electric energy or power. Powerplants. Central stationsTK1001-1841ENCarbon Energy, Vol 3, Iss 6, Pp 866-894 (2021)
institution DOAJ
collection DOAJ
language EN
topic cathode configuration design
interface
lithium battery
solid‐state electrolyte
Production of electric energy or power. Powerplants. Central stations
TK1001-1841
spellingShingle cathode configuration design
interface
lithium battery
solid‐state electrolyte
Production of electric energy or power. Powerplants. Central stations
TK1001-1841
Shiming Su
Jiabin Ma
Liang Zhao
Kui Lin
Qidong Li
Shasha Lv
Feiyu Kang
Yan‐Bing He
Progress and perspective of the cathode/electrolyte interface construction in all‐solid‐state lithium batteries
description Abstract Security risks of flammability and explosion represent major problems with the use of conventional lithium rechargeable batteries using a liquid electrolyte. The application of solid‐state electrolytes could effectively help to avoid these safety concerns. However, integrating the solid‐state electrolytes into the all‐solid‐state lithium batteries is still a huge challenge mainly due to the high interfacial resistance present in the entire battery, especially at the interface between the cathode and the solid‐state electrolyte pellet and the interfaces inside the cathode. Herein, recent progress made from investigations of cathode/solid‐state electrolyte interfacial behaviors including the contact problem, the interlayer diffusion issue, the space‐charge layer effect, and electrochemical compatibility is presented according to the classification of oxide‐, sulfide‐, and polymer‐based solid‐state electrolytes. We also propose strategies for the construction of ideal next‐generation cathode/solid‐state electrolyte interfaces with high room‐temperature ionic conductivity, stable interfacial contact during long cycling, free formation of the space‐charge region, and good compatibility with high‐voltage cathodes.
format article
author Shiming Su
Jiabin Ma
Liang Zhao
Kui Lin
Qidong Li
Shasha Lv
Feiyu Kang
Yan‐Bing He
author_facet Shiming Su
Jiabin Ma
Liang Zhao
Kui Lin
Qidong Li
Shasha Lv
Feiyu Kang
Yan‐Bing He
author_sort Shiming Su
title Progress and perspective of the cathode/electrolyte interface construction in all‐solid‐state lithium batteries
title_short Progress and perspective of the cathode/electrolyte interface construction in all‐solid‐state lithium batteries
title_full Progress and perspective of the cathode/electrolyte interface construction in all‐solid‐state lithium batteries
title_fullStr Progress and perspective of the cathode/electrolyte interface construction in all‐solid‐state lithium batteries
title_full_unstemmed Progress and perspective of the cathode/electrolyte interface construction in all‐solid‐state lithium batteries
title_sort progress and perspective of the cathode/electrolyte interface construction in all‐solid‐state lithium batteries
publisher Wiley
publishDate 2021
url https://doaj.org/article/04997cf474014176a1615c299d8125b0
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