Reductive cyanation of organic chlorides using CO2 and NH3 via Triphos–Ni(I) species

Nitriles are key intermediates in production of pharmaceuticals, agrochemicals and organic materials. Here, the authors report a nickel-catalyzed reductive cyanation of organic chlorides with CO2/NH3 and urea as cyanation reagents to afford a broad range of organic nitriles.

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Autores principales:	Yanan Dong, Peiju Yang, Shizhen Zhao, Yuehui Li
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/05d18c221ec64e6f9d77dfcb44eda4b1
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spelling	oai:doaj.org-article:05d18c221ec64e6f9d77dfcb44eda4b12021-12-02T16:28:07ZReductive cyanation of organic chlorides using CO2 and NH3 via Triphos–Ni(I) species10.1038/s41467-020-17939-22041-1723https://doaj.org/article/05d18c221ec64e6f9d77dfcb44eda4b12020-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-17939-2https://doaj.org/toc/2041-1723Nitriles are key intermediates in production of pharmaceuticals, agrochemicals and organic materials. Here, the authors report a nickel-catalyzed reductive cyanation of organic chlorides with CO2/NH3 and urea as cyanation reagents to afford a broad range of organic nitriles.Yanan DongPeiju YangShizhen ZhaoYuehui LiNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-9 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Yanan Dong Peiju Yang Shizhen Zhao Yuehui Li Reductive cyanation of organic chlorides using CO2 and NH3 via Triphos–Ni(I) species
description	Nitriles are key intermediates in production of pharmaceuticals, agrochemicals and organic materials. Here, the authors report a nickel-catalyzed reductive cyanation of organic chlorides with CO2/NH3 and urea as cyanation reagents to afford a broad range of organic nitriles.
format	article
author	Yanan Dong Peiju Yang Shizhen Zhao Yuehui Li
author_facet	Yanan Dong Peiju Yang Shizhen Zhao Yuehui Li
author_sort	Yanan Dong
title	Reductive cyanation of organic chlorides using CO2 and NH3 via Triphos–Ni(I) species
title_short	Reductive cyanation of organic chlorides using CO2 and NH3 via Triphos–Ni(I) species
title_full	Reductive cyanation of organic chlorides using CO2 and NH3 via Triphos–Ni(I) species
title_fullStr	Reductive cyanation of organic chlorides using CO2 and NH3 via Triphos–Ni(I) species
title_full_unstemmed	Reductive cyanation of organic chlorides using CO2 and NH3 via Triphos–Ni(I) species
title_sort	reductive cyanation of organic chlorides using co2 and nh3 via triphos–ni(i) species
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/05d18c221ec64e6f9d77dfcb44eda4b1
work_keys_str_mv	AT yanandong reductivecyanationoforganicchloridesusingco2andnh3viatriphosniispecies AT peijuyang reductivecyanationoforganicchloridesusingco2andnh3viatriphosniispecies AT shizhenzhao reductivecyanationoforganicchloridesusingco2andnh3viatriphosniispecies AT yuehuili reductivecyanationoforganicchloridesusingco2andnh3viatriphosniispecies
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Reductive cyanation of organic chlorides using CO2 and NH3 via Triphos–Ni(I) species

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