Preparation, characterization and dyeing wastewater treatment of a new PVDF/PMMA five-bore UF membrane with β-cyclodextrin and additive combinations

A new type of polyvinylidene fluoride (PVDF)/polymethyl methacrylate (PMMA) hollow fiber membrane (HFM) with five bores was prepared. The effects of polyvinylpyrrolidone (PVP), β-cyclodextrine (β-CD), polyethylene glycol (PEG) and polysorbate 80 (Tween 80) and their combinations on the PVDF/PMMA fiv...

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Autores principales: Xiaozheng Bian, Jianping Huang, Lin Qiu, Chunyan Ma, Danli Xi
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Publicado: IWA Publishing 2021
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spelling oai:doaj.org-article:063ec67c579b470bbcecca0fc12646142021-11-06T10:56:04ZPreparation, characterization and dyeing wastewater treatment of a new PVDF/PMMA five-bore UF membrane with β-cyclodextrin and additive combinations0273-12231996-973210.2166/wst.2021.104https://doaj.org/article/063ec67c579b470bbcecca0fc12646142021-04-01T00:00:00Zhttp://wst.iwaponline.com/content/83/8/1847https://doaj.org/toc/0273-1223https://doaj.org/toc/1996-9732A new type of polyvinylidene fluoride (PVDF)/polymethyl methacrylate (PMMA) hollow fiber membrane (HFM) with five bores was prepared. The effects of polyvinylpyrrolidone (PVP), β-cyclodextrine (β-CD), polyethylene glycol (PEG) and polysorbate 80 (Tween 80) and their combinations on the PVDF/PMMA five-bore HFMs were investigated. The performance and fouling characteristics of five-bore HFMs for dyeing wastewater treatment were evaluated. Results indicated that adding 5 wt.% PVP increased the porosity and water flux of the membrane but decreased the bovine serum albumin (BSA) rejection rate. Adding 5 wt.% β-CD significantly improved the tensile strength and rejection of the HFMs with no effect on the increase of water flux. The characteristic of the HFMs with different additive combinations proved that the mixture of 5 wt.% PVP and 1 wt.% β-CD gave the best membrane performance, with a pure water flux of 427.9 L/ m2·h, a contact angle of 25°, and a rejection of BSA of 89.7%. The CODcr and UV254 removal rates of dyeing wastewater treatment were 61.10% and 50.41%, respectively. No breakage or leakage points were found after 120 days of operation, showing their reliable mechanical properties. We set the operating flux to 55 L/m2·h and cross-flow rate to 10%, which can effectively control membrane fouling. HIGHLIGHTS PVDF/PMMA five-bore HFMs were prepared by dry-wet spinning.; The addition of PVP and β-CD had significant effects on HFM hydrophilicity and rejection respectively.; The best film properties were obtained by mixing 5 wt% PVP and 1 wt% β-CD.; The laboratory-made membrane module could effectively remove chemical oxygen demand and the turbidity of the dyeing wastewater.; No breakage or leakage points were found after 120 days of operation, showing their reliable mechanical properties.;Xiaozheng BianJianping HuangLin QiuChunyan MaDanli XiIWA Publishingarticleadditiveβ-cyclodextrine (β-cd)dyeing wastewaterfive-borehollow fiber membranepolyvinylpyrrolidone (pvp)Environmental technology. Sanitary engineeringTD1-1066ENWater Science and Technology, Vol 83, Iss 8, Pp 1847-1862 (2021)
institution DOAJ
collection DOAJ
language EN
topic additive
β-cyclodextrine (β-cd)
dyeing wastewater
five-bore
hollow fiber membrane
polyvinylpyrrolidone (pvp)
Environmental technology. Sanitary engineering
TD1-1066
spellingShingle additive
β-cyclodextrine (β-cd)
dyeing wastewater
five-bore
hollow fiber membrane
polyvinylpyrrolidone (pvp)
Environmental technology. Sanitary engineering
TD1-1066
Xiaozheng Bian
Jianping Huang
Lin Qiu
Chunyan Ma
Danli Xi
Preparation, characterization and dyeing wastewater treatment of a new PVDF/PMMA five-bore UF membrane with β-cyclodextrin and additive combinations
description A new type of polyvinylidene fluoride (PVDF)/polymethyl methacrylate (PMMA) hollow fiber membrane (HFM) with five bores was prepared. The effects of polyvinylpyrrolidone (PVP), β-cyclodextrine (β-CD), polyethylene glycol (PEG) and polysorbate 80 (Tween 80) and their combinations on the PVDF/PMMA five-bore HFMs were investigated. The performance and fouling characteristics of five-bore HFMs for dyeing wastewater treatment were evaluated. Results indicated that adding 5 wt.% PVP increased the porosity and water flux of the membrane but decreased the bovine serum albumin (BSA) rejection rate. Adding 5 wt.% β-CD significantly improved the tensile strength and rejection of the HFMs with no effect on the increase of water flux. The characteristic of the HFMs with different additive combinations proved that the mixture of 5 wt.% PVP and 1 wt.% β-CD gave the best membrane performance, with a pure water flux of 427.9 L/ m2·h, a contact angle of 25°, and a rejection of BSA of 89.7%. The CODcr and UV254 removal rates of dyeing wastewater treatment were 61.10% and 50.41%, respectively. No breakage or leakage points were found after 120 days of operation, showing their reliable mechanical properties. We set the operating flux to 55 L/m2·h and cross-flow rate to 10%, which can effectively control membrane fouling. HIGHLIGHTS PVDF/PMMA five-bore HFMs were prepared by dry-wet spinning.; The addition of PVP and β-CD had significant effects on HFM hydrophilicity and rejection respectively.; The best film properties were obtained by mixing 5 wt% PVP and 1 wt% β-CD.; The laboratory-made membrane module could effectively remove chemical oxygen demand and the turbidity of the dyeing wastewater.; No breakage or leakage points were found after 120 days of operation, showing their reliable mechanical properties.;
format article
author Xiaozheng Bian
Jianping Huang
Lin Qiu
Chunyan Ma
Danli Xi
author_facet Xiaozheng Bian
Jianping Huang
Lin Qiu
Chunyan Ma
Danli Xi
author_sort Xiaozheng Bian
title Preparation, characterization and dyeing wastewater treatment of a new PVDF/PMMA five-bore UF membrane with β-cyclodextrin and additive combinations
title_short Preparation, characterization and dyeing wastewater treatment of a new PVDF/PMMA five-bore UF membrane with β-cyclodextrin and additive combinations
title_full Preparation, characterization and dyeing wastewater treatment of a new PVDF/PMMA five-bore UF membrane with β-cyclodextrin and additive combinations
title_fullStr Preparation, characterization and dyeing wastewater treatment of a new PVDF/PMMA five-bore UF membrane with β-cyclodextrin and additive combinations
title_full_unstemmed Preparation, characterization and dyeing wastewater treatment of a new PVDF/PMMA five-bore UF membrane with β-cyclodextrin and additive combinations
title_sort preparation, characterization and dyeing wastewater treatment of a new pvdf/pmma five-bore uf membrane with β-cyclodextrin and additive combinations
publisher IWA Publishing
publishDate 2021
url https://doaj.org/article/063ec67c579b470bbcecca0fc1264614
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