Rhodium-catalysed direct hydroarylation of alkenes and alkynes with phosphines through phosphorous-assisted C−H activation

Dialkyl biaryl phosphines find wide application in catalysis as ligands. Here, the authors report a rhodium-catalysed hydroarylation of alkenes and alkynes with tertiary phosphines through P(III)-chelation assisted C-H activation affording a library of functionalized phosphines which hold potential...

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Autores principales:	Dingyi Wang, Ben Dong, Yandong Wang, Jiasheng Qian, Jinjun Zhu, Yue Zhao, Zhuangzhi Shi
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/066787e680b54ce080cd8c4069219e2f
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spelling	oai:doaj.org-article:066787e680b54ce080cd8c4069219e2f2021-12-02T15:36:22ZRhodium-catalysed direct hydroarylation of alkenes and alkynes with phosphines through phosphorous-assisted C−H activation10.1038/s41467-019-11420-52041-1723https://doaj.org/article/066787e680b54ce080cd8c4069219e2f2019-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-11420-5https://doaj.org/toc/2041-1723Dialkyl biaryl phosphines find wide application in catalysis as ligands. Here, the authors report a rhodium-catalysed hydroarylation of alkenes and alkynes with tertiary phosphines through P(III)-chelation assisted C-H activation affording a library of functionalized phosphines which hold potential in catalytic applications.Dingyi WangBen DongYandong WangJiasheng QianJinjun ZhuYue ZhaoZhuangzhi ShiNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-10 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Dingyi Wang Ben Dong Yandong Wang Jiasheng Qian Jinjun Zhu Yue Zhao Zhuangzhi Shi Rhodium-catalysed direct hydroarylation of alkenes and alkynes with phosphines through phosphorous-assisted C−H activation
description	Dialkyl biaryl phosphines find wide application in catalysis as ligands. Here, the authors report a rhodium-catalysed hydroarylation of alkenes and alkynes with tertiary phosphines through P(III)-chelation assisted C-H activation affording a library of functionalized phosphines which hold potential in catalytic applications.
format	article
author	Dingyi Wang Ben Dong Yandong Wang Jiasheng Qian Jinjun Zhu Yue Zhao Zhuangzhi Shi
author_facet	Dingyi Wang Ben Dong Yandong Wang Jiasheng Qian Jinjun Zhu Yue Zhao Zhuangzhi Shi
author_sort	Dingyi Wang
title	Rhodium-catalysed direct hydroarylation of alkenes and alkynes with phosphines through phosphorous-assisted C−H activation
title_short	Rhodium-catalysed direct hydroarylation of alkenes and alkynes with phosphines through phosphorous-assisted C−H activation
title_full	Rhodium-catalysed direct hydroarylation of alkenes and alkynes with phosphines through phosphorous-assisted C−H activation
title_fullStr	Rhodium-catalysed direct hydroarylation of alkenes and alkynes with phosphines through phosphorous-assisted C−H activation
title_full_unstemmed	Rhodium-catalysed direct hydroarylation of alkenes and alkynes with phosphines through phosphorous-assisted C−H activation
title_sort	rhodium-catalysed direct hydroarylation of alkenes and alkynes with phosphines through phosphorous-assisted c−h activation
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/066787e680b54ce080cd8c4069219e2f
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Rhodium-catalysed direct hydroarylation of alkenes and alkynes with phosphines through phosphorous-assisted C−H activation

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