Influence of different aluminum salts on the photocatalytic properties of Al doped TiO2 nanoparticles towards the degradation of AO7 dye
Abstract Three kinds of Al-TiO2 samples and pure TiO2 samples were synthesized via a modified polyacrylamide gel route using different aluminum salts, including Al2(SO4)3∙18H2O, AlCl3, and Al(NO3)3∙9H2O under identical conditions. The influence of different aluminum salts on the phase purity, morpho...
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oai:doaj.org-article:071e9ed3a5d843f7ab8d38afd9d3e2d82021-12-02T12:32:05ZInfluence of different aluminum salts on the photocatalytic properties of Al doped TiO2 nanoparticles towards the degradation of AO7 dye10.1038/s41598-017-08216-22045-2322https://doaj.org/article/071e9ed3a5d843f7ab8d38afd9d3e2d82017-08-01T00:00:00Zhttps://doi.org/10.1038/s41598-017-08216-2https://doaj.org/toc/2045-2322Abstract Three kinds of Al-TiO2 samples and pure TiO2 samples were synthesized via a modified polyacrylamide gel route using different aluminum salts, including Al2(SO4)3∙18H2O, AlCl3, and Al(NO3)3∙9H2O under identical conditions. The influence of different aluminum salts on the phase purity, morphologies, thermal stability of anatase and photocatalytic properties of the as-prepared Al-TiO2 nanoparticles were studied. The energy gap (Eg) of Al-TiO2 nanoparticles decreases due to Al ion doping into TiO2. The photocatalytic activities of the Al-TiO2 samples were investigated by the degradation of acid orange 7 dye in aqueous solution under simulated solar irradiation. The Al-TiO2 nanoparticles prepared from Al(NO3)3∙9H2O exhibit the best photocatalytic activity among the four kinds of samples, followed in turn by the Al-TiO2 nanoparticles prepared with AlCl3, Al2(SO4)3∙18H2O and pure TiO2. The different performances are attributed to complex effects of Eg, particle size, surface morphology, phase purity and the defect sites of the Al-TiO2 nanoparticles.Jin-ling LuoShi-fa WangWei LiuCheng-xiang TianJu-wei WuXiao-tao ZuWei-lie ZhouXiao-dong YuanXia XiangNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 7, Iss 1, Pp 1-16 (2017) |
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Medicine R Science Q Jin-ling Luo Shi-fa Wang Wei Liu Cheng-xiang Tian Ju-wei Wu Xiao-tao Zu Wei-lie Zhou Xiao-dong Yuan Xia Xiang Influence of different aluminum salts on the photocatalytic properties of Al doped TiO2 nanoparticles towards the degradation of AO7 dye |
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Abstract Three kinds of Al-TiO2 samples and pure TiO2 samples were synthesized via a modified polyacrylamide gel route using different aluminum salts, including Al2(SO4)3∙18H2O, AlCl3, and Al(NO3)3∙9H2O under identical conditions. The influence of different aluminum salts on the phase purity, morphologies, thermal stability of anatase and photocatalytic properties of the as-prepared Al-TiO2 nanoparticles were studied. The energy gap (Eg) of Al-TiO2 nanoparticles decreases due to Al ion doping into TiO2. The photocatalytic activities of the Al-TiO2 samples were investigated by the degradation of acid orange 7 dye in aqueous solution under simulated solar irradiation. The Al-TiO2 nanoparticles prepared from Al(NO3)3∙9H2O exhibit the best photocatalytic activity among the four kinds of samples, followed in turn by the Al-TiO2 nanoparticles prepared with AlCl3, Al2(SO4)3∙18H2O and pure TiO2. The different performances are attributed to complex effects of Eg, particle size, surface morphology, phase purity and the defect sites of the Al-TiO2 nanoparticles. |
format |
article |
author |
Jin-ling Luo Shi-fa Wang Wei Liu Cheng-xiang Tian Ju-wei Wu Xiao-tao Zu Wei-lie Zhou Xiao-dong Yuan Xia Xiang |
author_facet |
Jin-ling Luo Shi-fa Wang Wei Liu Cheng-xiang Tian Ju-wei Wu Xiao-tao Zu Wei-lie Zhou Xiao-dong Yuan Xia Xiang |
author_sort |
Jin-ling Luo |
title |
Influence of different aluminum salts on the photocatalytic properties of Al doped TiO2 nanoparticles towards the degradation of AO7 dye |
title_short |
Influence of different aluminum salts on the photocatalytic properties of Al doped TiO2 nanoparticles towards the degradation of AO7 dye |
title_full |
Influence of different aluminum salts on the photocatalytic properties of Al doped TiO2 nanoparticles towards the degradation of AO7 dye |
title_fullStr |
Influence of different aluminum salts on the photocatalytic properties of Al doped TiO2 nanoparticles towards the degradation of AO7 dye |
title_full_unstemmed |
Influence of different aluminum salts on the photocatalytic properties of Al doped TiO2 nanoparticles towards the degradation of AO7 dye |
title_sort |
influence of different aluminum salts on the photocatalytic properties of al doped tio2 nanoparticles towards the degradation of ao7 dye |
publisher |
Nature Portfolio |
publishDate |
2017 |
url |
https://doaj.org/article/071e9ed3a5d843f7ab8d38afd9d3e2d8 |
work_keys_str_mv |
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1718394138375749632 |