Substrate strain tunes operando geometric distortion and oxygen reduction activity of CuN2C2 single-atom sites

The rational design of single-atom catalysts is challenging. This work reveals a substrate-strain tuned geometry distortion of CuN2C2 single-atom site, which greatly boosts oxygen reduction activity by facilitating electron transfer to adsorbed O.

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Detalles Bibliográficos
Autores principales: Guokang Han, Xue Zhang, Wei Liu, Qinghua Zhang, Zhiqiang Wang, Jun Cheng, Tao Yao, Lin Gu, Chunyu Du, Yunzhi Gao, Geping Yin
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/072f4256cea5454b872c552186885e60
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Sumario:The rational design of single-atom catalysts is challenging. This work reveals a substrate-strain tuned geometry distortion of CuN2C2 single-atom site, which greatly boosts oxygen reduction activity by facilitating electron transfer to adsorbed O.