Ruthenium(II)-catalysed remote C–H alkylations as a versatile platform to meta-decorated arenes

Whileortho-selective C-H activation is well explored, general meta-selective methods are rare and often require directing groups that are retained in the final products. Here the authors show that transient imine groups can be used to direct the meta-functionalization of a range of arenes.

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Autores principales: Jie Li, Korkit Korvorapun, Suman De Sarkar, Torben Rogge, David J. Burns, Svenja Warratz, Lutz Ackermann
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/07468563c5ad43cb8d7d234c58afb3c4
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spelling oai:doaj.org-article:07468563c5ad43cb8d7d234c58afb3c42021-12-02T14:42:36ZRuthenium(II)-catalysed remote C–H alkylations as a versatile platform to meta-decorated arenes10.1038/ncomms154302041-1723https://doaj.org/article/07468563c5ad43cb8d7d234c58afb3c42017-06-01T00:00:00Zhttps://doi.org/10.1038/ncomms15430https://doaj.org/toc/2041-1723Whileortho-selective C-H activation is well explored, general meta-selective methods are rare and often require directing groups that are retained in the final products. Here the authors show that transient imine groups can be used to direct the meta-functionalization of a range of arenes.Jie LiKorkit KorvorapunSuman De SarkarTorben RoggeDavid J. BurnsSvenja WarratzLutz AckermannNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-8 (2017)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Jie Li
Korkit Korvorapun
Suman De Sarkar
Torben Rogge
David J. Burns
Svenja Warratz
Lutz Ackermann
Ruthenium(II)-catalysed remote C–H alkylations as a versatile platform to meta-decorated arenes
description Whileortho-selective C-H activation is well explored, general meta-selective methods are rare and often require directing groups that are retained in the final products. Here the authors show that transient imine groups can be used to direct the meta-functionalization of a range of arenes.
format article
author Jie Li
Korkit Korvorapun
Suman De Sarkar
Torben Rogge
David J. Burns
Svenja Warratz
Lutz Ackermann
author_facet Jie Li
Korkit Korvorapun
Suman De Sarkar
Torben Rogge
David J. Burns
Svenja Warratz
Lutz Ackermann
author_sort Jie Li
title Ruthenium(II)-catalysed remote C–H alkylations as a versatile platform to meta-decorated arenes
title_short Ruthenium(II)-catalysed remote C–H alkylations as a versatile platform to meta-decorated arenes
title_full Ruthenium(II)-catalysed remote C–H alkylations as a versatile platform to meta-decorated arenes
title_fullStr Ruthenium(II)-catalysed remote C–H alkylations as a versatile platform to meta-decorated arenes
title_full_unstemmed Ruthenium(II)-catalysed remote C–H alkylations as a versatile platform to meta-decorated arenes
title_sort ruthenium(ii)-catalysed remote c–h alkylations as a versatile platform to meta-decorated arenes
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/07468563c5ad43cb8d7d234c58afb3c4
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