Ruthenium(II)-catalysed remote C–H alkylations as a versatile platform to meta-decorated arenes
Whileortho-selective C-H activation is well explored, general meta-selective methods are rare and often require directing groups that are retained in the final products. Here the authors show that transient imine groups can be used to direct the meta-functionalization of a range of arenes.
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Nature Portfolio
2017
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oai:doaj.org-article:07468563c5ad43cb8d7d234c58afb3c42021-12-02T14:42:36ZRuthenium(II)-catalysed remote C–H alkylations as a versatile platform to meta-decorated arenes10.1038/ncomms154302041-1723https://doaj.org/article/07468563c5ad43cb8d7d234c58afb3c42017-06-01T00:00:00Zhttps://doi.org/10.1038/ncomms15430https://doaj.org/toc/2041-1723Whileortho-selective C-H activation is well explored, general meta-selective methods are rare and often require directing groups that are retained in the final products. Here the authors show that transient imine groups can be used to direct the meta-functionalization of a range of arenes.Jie LiKorkit KorvorapunSuman De SarkarTorben RoggeDavid J. BurnsSvenja WarratzLutz AckermannNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-8 (2017) |
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Science Q Jie Li Korkit Korvorapun Suman De Sarkar Torben Rogge David J. Burns Svenja Warratz Lutz Ackermann Ruthenium(II)-catalysed remote C–H alkylations as a versatile platform to meta-decorated arenes |
description |
Whileortho-selective C-H activation is well explored, general meta-selective methods are rare and often require directing groups that are retained in the final products. Here the authors show that transient imine groups can be used to direct the meta-functionalization of a range of arenes. |
format |
article |
author |
Jie Li Korkit Korvorapun Suman De Sarkar Torben Rogge David J. Burns Svenja Warratz Lutz Ackermann |
author_facet |
Jie Li Korkit Korvorapun Suman De Sarkar Torben Rogge David J. Burns Svenja Warratz Lutz Ackermann |
author_sort |
Jie Li |
title |
Ruthenium(II)-catalysed remote C–H alkylations as a versatile platform to meta-decorated arenes |
title_short |
Ruthenium(II)-catalysed remote C–H alkylations as a versatile platform to meta-decorated arenes |
title_full |
Ruthenium(II)-catalysed remote C–H alkylations as a versatile platform to meta-decorated arenes |
title_fullStr |
Ruthenium(II)-catalysed remote C–H alkylations as a versatile platform to meta-decorated arenes |
title_full_unstemmed |
Ruthenium(II)-catalysed remote C–H alkylations as a versatile platform to meta-decorated arenes |
title_sort |
ruthenium(ii)-catalysed remote c–h alkylations as a versatile platform to meta-decorated arenes |
publisher |
Nature Portfolio |
publishDate |
2017 |
url |
https://doaj.org/article/07468563c5ad43cb8d7d234c58afb3c4 |
work_keys_str_mv |
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