A unified approach for divergent synthesis of contiguous stereodiads employing a small boronyl group

Predictable and unified approaches to all possible stereoisomers of acyclic compounds with contiguous stereocentres are rare. Here, the authors disclose a divergent α-functionalization of enolates with either syn or anti selectivity employing a β-boronyl group as a small, directing handle.

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Autores principales:	Miao Zhan, Zhengwei Ding, Shaozhi Du, Haohua Chen, Chao Feng, Ming Xu, Zhi Liu, Mengxi Zhang, Chao Wu, Yu Lan, Pengfei Li
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/074fe3b89ac84034ad62c58a17d7a07c
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spelling	oai:doaj.org-article:074fe3b89ac84034ad62c58a17d7a07c2021-12-02T16:49:29ZA unified approach for divergent synthesis of contiguous stereodiads employing a small boronyl group10.1038/s41467-020-14592-72041-1723https://doaj.org/article/074fe3b89ac84034ad62c58a17d7a07c2020-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-14592-7https://doaj.org/toc/2041-1723Predictable and unified approaches to all possible stereoisomers of acyclic compounds with contiguous stereocentres are rare. Here, the authors disclose a divergent α-functionalization of enolates with either syn or anti selectivity employing a β-boronyl group as a small, directing handle.Miao ZhanZhengwei DingShaozhi DuHaohua ChenChao FengMing XuZhi LiuMengxi ZhangChao WuYu LanPengfei LiNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-9 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Miao Zhan Zhengwei Ding Shaozhi Du Haohua Chen Chao Feng Ming Xu Zhi Liu Mengxi Zhang Chao Wu Yu Lan Pengfei Li A unified approach for divergent synthesis of contiguous stereodiads employing a small boronyl group
description	Predictable and unified approaches to all possible stereoisomers of acyclic compounds with contiguous stereocentres are rare. Here, the authors disclose a divergent α-functionalization of enolates with either syn or anti selectivity employing a β-boronyl group as a small, directing handle.
format	article
author	Miao Zhan Zhengwei Ding Shaozhi Du Haohua Chen Chao Feng Ming Xu Zhi Liu Mengxi Zhang Chao Wu Yu Lan Pengfei Li
author_facet	Miao Zhan Zhengwei Ding Shaozhi Du Haohua Chen Chao Feng Ming Xu Zhi Liu Mengxi Zhang Chao Wu Yu Lan Pengfei Li
author_sort	Miao Zhan
title	A unified approach for divergent synthesis of contiguous stereodiads employing a small boronyl group
title_short	A unified approach for divergent synthesis of contiguous stereodiads employing a small boronyl group
title_full	A unified approach for divergent synthesis of contiguous stereodiads employing a small boronyl group
title_fullStr	A unified approach for divergent synthesis of contiguous stereodiads employing a small boronyl group
title_full_unstemmed	A unified approach for divergent synthesis of contiguous stereodiads employing a small boronyl group
title_sort	unified approach for divergent synthesis of contiguous stereodiads employing a small boronyl group
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/074fe3b89ac84034ad62c58a17d7a07c
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A unified approach for divergent synthesis of contiguous stereodiads employing a small boronyl group

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