A unified approach for divergent synthesis of contiguous stereodiads employing a small boronyl group

Predictable and unified approaches to all possible stereoisomers of acyclic compounds with contiguous stereocentres are rare. Here, the authors disclose a divergent α-functionalization of enolates with either syn or anti selectivity employing a β-boronyl group as a small, directing handle.

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Auteurs principaux: Miao Zhan, Zhengwei Ding, Shaozhi Du, Haohua Chen, Chao Feng, Ming Xu, Zhi Liu, Mengxi Zhang, Chao Wu, Yu Lan, Pengfei Li
Format: article
Langue:EN
Publié: Nature Portfolio 2020
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Accès en ligne:https://doaj.org/article/074fe3b89ac84034ad62c58a17d7a07c
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