The operational window of carbon nanotube electrical wires treated with strong acids and oxidants

Abstract Conventional metal wires suffer from a significant degradation or complete failure in their electrical performance, when subjected to harsh oxidizing environments, however wires constructed from Carbon Nanotubes (CNTs) have been found to actually improve in their electrical performance when...

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Autores principales: S. Lepak-Kuc, S. Boncel, M. Szybowicz, A. B. Nowicka, I. Jozwik, K. Orlinski, T. Gizewski, K. Koziol, M. Jakubowska, A. Lekawa-Raus
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Publicado: Nature Portfolio 2018
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spelling oai:doaj.org-article:08091924a7d64f1e9ead971914c6ba7c2021-12-02T15:07:48ZThe operational window of carbon nanotube electrical wires treated with strong acids and oxidants10.1038/s41598-018-32663-02045-2322https://doaj.org/article/08091924a7d64f1e9ead971914c6ba7c2018-09-01T00:00:00Zhttps://doi.org/10.1038/s41598-018-32663-0https://doaj.org/toc/2045-2322Abstract Conventional metal wires suffer from a significant degradation or complete failure in their electrical performance, when subjected to harsh oxidizing environments, however wires constructed from Carbon Nanotubes (CNTs) have been found to actually improve in their electrical performance when subjected to these environments. These opposing reactions may provide new and interesting applications for CNT wires. Yet, before attempting to move to any real-world harsh environment applications, for the CNT wires, it is essential that this area of their operation be thoroughly examined. To investigate this, CNT wires were treated with multiple combinations of the strongest acids and halogens. The wires were then subjected to conductivity measurements, current carrying capacity tests, as well as Raman, microscopy and thermogravimetric analysis to enable the identification of both the limits of oxidative conductivity boosting and the onset of physical damage to the wires. These experiments have led to two main conclusions. Firstly, that CNT wires may operate effectively in harsh oxidizing environments where metal wires would easily fail and secondly, that the highest conductivity increase of the CNT wires can be achieved through a process of annealing, acetone and HCl purification followed by either H2O2 and HClO4 or Br2 treatment.S. Lepak-KucS. BoncelM. SzybowiczA. B. NowickaI. JozwikK. OrlinskiT. GizewskiK. KoziolM. JakubowskaA. Lekawa-RausNature PortfolioarticleCurrent Carrying Capacity (CCC)Doping ProcedureFloating Catalyst Chemical Vapor DepositionSimultaneous Thermogravimetric AnalysisAbsolute ConductivityMedicineRScienceQENScientific Reports, Vol 8, Iss 1, Pp 1-12 (2018)
institution DOAJ
collection DOAJ
language EN
topic Current Carrying Capacity (CCC)
Doping Procedure
Floating Catalyst Chemical Vapor Deposition
Simultaneous Thermogravimetric Analysis
Absolute Conductivity
Medicine
R
Science
Q
spellingShingle Current Carrying Capacity (CCC)
Doping Procedure
Floating Catalyst Chemical Vapor Deposition
Simultaneous Thermogravimetric Analysis
Absolute Conductivity
Medicine
R
Science
Q
S. Lepak-Kuc
S. Boncel
M. Szybowicz
A. B. Nowicka
I. Jozwik
K. Orlinski
T. Gizewski
K. Koziol
M. Jakubowska
A. Lekawa-Raus
The operational window of carbon nanotube electrical wires treated with strong acids and oxidants
description Abstract Conventional metal wires suffer from a significant degradation or complete failure in their electrical performance, when subjected to harsh oxidizing environments, however wires constructed from Carbon Nanotubes (CNTs) have been found to actually improve in their electrical performance when subjected to these environments. These opposing reactions may provide new and interesting applications for CNT wires. Yet, before attempting to move to any real-world harsh environment applications, for the CNT wires, it is essential that this area of their operation be thoroughly examined. To investigate this, CNT wires were treated with multiple combinations of the strongest acids and halogens. The wires were then subjected to conductivity measurements, current carrying capacity tests, as well as Raman, microscopy and thermogravimetric analysis to enable the identification of both the limits of oxidative conductivity boosting and the onset of physical damage to the wires. These experiments have led to two main conclusions. Firstly, that CNT wires may operate effectively in harsh oxidizing environments where metal wires would easily fail and secondly, that the highest conductivity increase of the CNT wires can be achieved through a process of annealing, acetone and HCl purification followed by either H2O2 and HClO4 or Br2 treatment.
format article
author S. Lepak-Kuc
S. Boncel
M. Szybowicz
A. B. Nowicka
I. Jozwik
K. Orlinski
T. Gizewski
K. Koziol
M. Jakubowska
A. Lekawa-Raus
author_facet S. Lepak-Kuc
S. Boncel
M. Szybowicz
A. B. Nowicka
I. Jozwik
K. Orlinski
T. Gizewski
K. Koziol
M. Jakubowska
A. Lekawa-Raus
author_sort S. Lepak-Kuc
title The operational window of carbon nanotube electrical wires treated with strong acids and oxidants
title_short The operational window of carbon nanotube electrical wires treated with strong acids and oxidants
title_full The operational window of carbon nanotube electrical wires treated with strong acids and oxidants
title_fullStr The operational window of carbon nanotube electrical wires treated with strong acids and oxidants
title_full_unstemmed The operational window of carbon nanotube electrical wires treated with strong acids and oxidants
title_sort operational window of carbon nanotube electrical wires treated with strong acids and oxidants
publisher Nature Portfolio
publishDate 2018
url https://doaj.org/article/08091924a7d64f1e9ead971914c6ba7c
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