Synthesis and characterization of furfural-functionalized poly(vinyl alcohol) cross-linked with maleimide bearing tributyltin groups

In the present work, new cross-linked networks based on furfural-functionalized poly(vinyl alcohol) (PVF) and maleimide compounds containing tributyltin groups were synthesized. The networks were obtained both as films and porous membranes. The structure of the compounds was confirmed by ATR-FTIR sp...

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Autores principales: Viorica Gaina, Oana Ursache, Constantin Gaina, Irina Rosca, Ana-Lavinia Vasiliu
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Lenguaje:EN
Publicado: Budapest University of Technology 2022
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spelling oai:doaj.org-article:0826044f15c24ceeb671365bc23637cd2021-12-01T09:25:39ZSynthesis and characterization of furfural-functionalized poly(vinyl alcohol) cross-linked with maleimide bearing tributyltin groups1788-618X10.3144/expresspolymlett.2022.15https://doaj.org/article/0826044f15c24ceeb671365bc23637cd2022-02-01T00:00:00Zhttp://www.expresspolymlett.com/letolt.php?file=EPL-0011561&mi=cdhttps://doaj.org/toc/1788-618XIn the present work, new cross-linked networks based on furfural-functionalized poly(vinyl alcohol) (PVF) and maleimide compounds containing tributyltin groups were synthesized. The networks were obtained both as films and porous membranes. The structure of the compounds was confirmed by ATR-FTIR spectroscopy, and the morphology of the films/microporous membranes was investigated using scanning electron microscopy measurements (SEM), the differences between the films and membranes being evidenced. The mechanical performance and thermal stability of the membranes were examined by dynamic mechanical analysis (DMA) and thermogravimetry analysis (TGA), respectively. In addition, their water absorption and antimicrobial properties were thoroughly discussed. The antimicrobial activity of furfural-functionalized poly(vinyl alcohol) was significantly improved by its reaction with compounds containing tributyltin groups.Viorica GainaOana UrsacheConstantin GainaIrina RoscaAna-Lavinia VasiliuBudapest University of Technology articlepolymer membranespolyvinyl furfuralmaleimidestributhyltin compoundsantibacterial activityMaterials of engineering and construction. Mechanics of materialsTA401-492Chemical technologyTP1-1185ENeXPRESS Polymer Letters, Vol 16, Iss 2, Pp 184-196 (2022)
institution DOAJ
collection DOAJ
language EN
topic polymer membranes
polyvinyl furfural
maleimides
tributhyltin compounds
antibacterial activity
Materials of engineering and construction. Mechanics of materials
TA401-492
Chemical technology
TP1-1185
spellingShingle polymer membranes
polyvinyl furfural
maleimides
tributhyltin compounds
antibacterial activity
Materials of engineering and construction. Mechanics of materials
TA401-492
Chemical technology
TP1-1185
Viorica Gaina
Oana Ursache
Constantin Gaina
Irina Rosca
Ana-Lavinia Vasiliu
Synthesis and characterization of furfural-functionalized poly(vinyl alcohol) cross-linked with maleimide bearing tributyltin groups
description In the present work, new cross-linked networks based on furfural-functionalized poly(vinyl alcohol) (PVF) and maleimide compounds containing tributyltin groups were synthesized. The networks were obtained both as films and porous membranes. The structure of the compounds was confirmed by ATR-FTIR spectroscopy, and the morphology of the films/microporous membranes was investigated using scanning electron microscopy measurements (SEM), the differences between the films and membranes being evidenced. The mechanical performance and thermal stability of the membranes were examined by dynamic mechanical analysis (DMA) and thermogravimetry analysis (TGA), respectively. In addition, their water absorption and antimicrobial properties were thoroughly discussed. The antimicrobial activity of furfural-functionalized poly(vinyl alcohol) was significantly improved by its reaction with compounds containing tributyltin groups.
format article
author Viorica Gaina
Oana Ursache
Constantin Gaina
Irina Rosca
Ana-Lavinia Vasiliu
author_facet Viorica Gaina
Oana Ursache
Constantin Gaina
Irina Rosca
Ana-Lavinia Vasiliu
author_sort Viorica Gaina
title Synthesis and characterization of furfural-functionalized poly(vinyl alcohol) cross-linked with maleimide bearing tributyltin groups
title_short Synthesis and characterization of furfural-functionalized poly(vinyl alcohol) cross-linked with maleimide bearing tributyltin groups
title_full Synthesis and characterization of furfural-functionalized poly(vinyl alcohol) cross-linked with maleimide bearing tributyltin groups
title_fullStr Synthesis and characterization of furfural-functionalized poly(vinyl alcohol) cross-linked with maleimide bearing tributyltin groups
title_full_unstemmed Synthesis and characterization of furfural-functionalized poly(vinyl alcohol) cross-linked with maleimide bearing tributyltin groups
title_sort synthesis and characterization of furfural-functionalized poly(vinyl alcohol) cross-linked with maleimide bearing tributyltin groups
publisher Budapest University of Technology
publishDate 2022
url https://doaj.org/article/0826044f15c24ceeb671365bc23637cd
work_keys_str_mv AT vioricagaina synthesisandcharacterizationoffurfuralfunctionalizedpolyvinylalcoholcrosslinkedwithmaleimidebearingtributyltingroups
AT oanaursache synthesisandcharacterizationoffurfuralfunctionalizedpolyvinylalcoholcrosslinkedwithmaleimidebearingtributyltingroups
AT constantingaina synthesisandcharacterizationoffurfuralfunctionalizedpolyvinylalcoholcrosslinkedwithmaleimidebearingtributyltingroups
AT irinarosca synthesisandcharacterizationoffurfuralfunctionalizedpolyvinylalcoholcrosslinkedwithmaleimidebearingtributyltingroups
AT analaviniavasiliu synthesisandcharacterizationoffurfuralfunctionalizedpolyvinylalcoholcrosslinkedwithmaleimidebearingtributyltingroups
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