Synthesis and characterization of furfural-functionalized poly(vinyl alcohol) cross-linked with maleimide bearing tributyltin groups
In the present work, new cross-linked networks based on furfural-functionalized poly(vinyl alcohol) (PVF) and maleimide compounds containing tributyltin groups were synthesized. The networks were obtained both as films and porous membranes. The structure of the compounds was confirmed by ATR-FTIR sp...
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Budapest University of Technology
2022
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oai:doaj.org-article:0826044f15c24ceeb671365bc23637cd2021-12-01T09:25:39ZSynthesis and characterization of furfural-functionalized poly(vinyl alcohol) cross-linked with maleimide bearing tributyltin groups1788-618X10.3144/expresspolymlett.2022.15https://doaj.org/article/0826044f15c24ceeb671365bc23637cd2022-02-01T00:00:00Zhttp://www.expresspolymlett.com/letolt.php?file=EPL-0011561&mi=cdhttps://doaj.org/toc/1788-618XIn the present work, new cross-linked networks based on furfural-functionalized poly(vinyl alcohol) (PVF) and maleimide compounds containing tributyltin groups were synthesized. The networks were obtained both as films and porous membranes. The structure of the compounds was confirmed by ATR-FTIR spectroscopy, and the morphology of the films/microporous membranes was investigated using scanning electron microscopy measurements (SEM), the differences between the films and membranes being evidenced. The mechanical performance and thermal stability of the membranes were examined by dynamic mechanical analysis (DMA) and thermogravimetry analysis (TGA), respectively. In addition, their water absorption and antimicrobial properties were thoroughly discussed. The antimicrobial activity of furfural-functionalized poly(vinyl alcohol) was significantly improved by its reaction with compounds containing tributyltin groups.Viorica GainaOana UrsacheConstantin GainaIrina RoscaAna-Lavinia VasiliuBudapest University of Technology articlepolymer membranespolyvinyl furfuralmaleimidestributhyltin compoundsantibacterial activityMaterials of engineering and construction. Mechanics of materialsTA401-492Chemical technologyTP1-1185ENeXPRESS Polymer Letters, Vol 16, Iss 2, Pp 184-196 (2022) |
institution |
DOAJ |
collection |
DOAJ |
language |
EN |
topic |
polymer membranes polyvinyl furfural maleimides tributhyltin compounds antibacterial activity Materials of engineering and construction. Mechanics of materials TA401-492 Chemical technology TP1-1185 |
spellingShingle |
polymer membranes polyvinyl furfural maleimides tributhyltin compounds antibacterial activity Materials of engineering and construction. Mechanics of materials TA401-492 Chemical technology TP1-1185 Viorica Gaina Oana Ursache Constantin Gaina Irina Rosca Ana-Lavinia Vasiliu Synthesis and characterization of furfural-functionalized poly(vinyl alcohol) cross-linked with maleimide bearing tributyltin groups |
description |
In the present work, new cross-linked networks based on furfural-functionalized poly(vinyl alcohol) (PVF) and maleimide compounds containing tributyltin groups were synthesized. The networks were obtained both as films and porous membranes. The structure of the compounds was confirmed by ATR-FTIR spectroscopy, and the morphology of the films/microporous membranes was investigated using scanning electron microscopy measurements (SEM), the differences between the films and membranes being evidenced. The mechanical performance and thermal stability of the membranes were examined by dynamic mechanical analysis (DMA) and thermogravimetry analysis (TGA), respectively. In addition, their water absorption and antimicrobial properties were thoroughly discussed. The antimicrobial activity of furfural-functionalized poly(vinyl alcohol) was significantly improved by its reaction with compounds containing tributyltin groups. |
format |
article |
author |
Viorica Gaina Oana Ursache Constantin Gaina Irina Rosca Ana-Lavinia Vasiliu |
author_facet |
Viorica Gaina Oana Ursache Constantin Gaina Irina Rosca Ana-Lavinia Vasiliu |
author_sort |
Viorica Gaina |
title |
Synthesis and characterization of furfural-functionalized poly(vinyl alcohol) cross-linked with maleimide bearing tributyltin groups |
title_short |
Synthesis and characterization of furfural-functionalized poly(vinyl alcohol) cross-linked with maleimide bearing tributyltin groups |
title_full |
Synthesis and characterization of furfural-functionalized poly(vinyl alcohol) cross-linked with maleimide bearing tributyltin groups |
title_fullStr |
Synthesis and characterization of furfural-functionalized poly(vinyl alcohol) cross-linked with maleimide bearing tributyltin groups |
title_full_unstemmed |
Synthesis and characterization of furfural-functionalized poly(vinyl alcohol) cross-linked with maleimide bearing tributyltin groups |
title_sort |
synthesis and characterization of furfural-functionalized poly(vinyl alcohol) cross-linked with maleimide bearing tributyltin groups |
publisher |
Budapest University of Technology |
publishDate |
2022 |
url |
https://doaj.org/article/0826044f15c24ceeb671365bc23637cd |
work_keys_str_mv |
AT vioricagaina synthesisandcharacterizationoffurfuralfunctionalizedpolyvinylalcoholcrosslinkedwithmaleimidebearingtributyltingroups AT oanaursache synthesisandcharacterizationoffurfuralfunctionalizedpolyvinylalcoholcrosslinkedwithmaleimidebearingtributyltingroups AT constantingaina synthesisandcharacterizationoffurfuralfunctionalizedpolyvinylalcoholcrosslinkedwithmaleimidebearingtributyltingroups AT irinarosca synthesisandcharacterizationoffurfuralfunctionalizedpolyvinylalcoholcrosslinkedwithmaleimidebearingtributyltingroups AT analaviniavasiliu synthesisandcharacterizationoffurfuralfunctionalizedpolyvinylalcoholcrosslinkedwithmaleimidebearingtributyltingroups |
_version_ |
1718405334631972864 |