Renewable Butanol Production via Catalytic Routes

Fluctuating crude oil price and global environmental problems such as global warming and climate change lead to growing demand for the production of renewable chemicals as petrochemical substitutes. Butanol is a nonpolar alcohol that is used in a large variety of consumer products and as an importan...

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Autores principales: Heeyoung Choi, Jeehoon Han, Jechan Lee
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Lenguaje:EN
Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:08494fab8f8046119419949fd7c611f72021-11-25T17:47:57ZRenewable Butanol Production via Catalytic Routes10.3390/ijerph1822117491660-46011661-7827https://doaj.org/article/08494fab8f8046119419949fd7c611f72021-11-01T00:00:00Zhttps://www.mdpi.com/1660-4601/18/22/11749https://doaj.org/toc/1661-7827https://doaj.org/toc/1660-4601Fluctuating crude oil price and global environmental problems such as global warming and climate change lead to growing demand for the production of renewable chemicals as petrochemical substitutes. Butanol is a nonpolar alcohol that is used in a large variety of consumer products and as an important industrial intermediate. Thus, the production of butanol from renewable resources (e.g., biomass and organic waste) has gained a great deal of attention from researchers. Although typical renewable butanol is produced via a fermentative route (i.e., acetone-butanol-ethanol (ABE) fermentation of biomass-derived sugars), the fermentative butanol production has disadvantages such as a low yield of butanol and the formation of byproducts, such as acetone and ethanol. To avoid the drawbacks, the production of renewable butanol via non-fermentative catalytic routes has been recently proposed. This review is aimed at providing an overview on three different emerging and promising catalytic routes from biomass/organic waste-derived chemicals to butanol. The first route involves the conversion of ethanol into butanol over metal and oxide catalysts. Volatile fatty acid can be a raw chemical for the production of butanol using porous materials and metal catalysts. In addition, biomass-derived syngas can be transformed to butanol on non-noble metal catalysts promoted by alkali metals. The prospect of catalytic renewable butanol production is also discussed.Heeyoung ChoiJeehoon HanJechan LeeMDPI AGarticlebiomassbutanolcatalysisorganic wasterenewable chemicalsustainable chemistryMedicineRENInternational Journal of Environmental Research and Public Health, Vol 18, Iss 11749, p 11749 (2021)
institution DOAJ
collection DOAJ
language EN
topic biomass
butanol
catalysis
organic waste
renewable chemical
sustainable chemistry
Medicine
R
spellingShingle biomass
butanol
catalysis
organic waste
renewable chemical
sustainable chemistry
Medicine
R
Heeyoung Choi
Jeehoon Han
Jechan Lee
Renewable Butanol Production via Catalytic Routes
description Fluctuating crude oil price and global environmental problems such as global warming and climate change lead to growing demand for the production of renewable chemicals as petrochemical substitutes. Butanol is a nonpolar alcohol that is used in a large variety of consumer products and as an important industrial intermediate. Thus, the production of butanol from renewable resources (e.g., biomass and organic waste) has gained a great deal of attention from researchers. Although typical renewable butanol is produced via a fermentative route (i.e., acetone-butanol-ethanol (ABE) fermentation of biomass-derived sugars), the fermentative butanol production has disadvantages such as a low yield of butanol and the formation of byproducts, such as acetone and ethanol. To avoid the drawbacks, the production of renewable butanol via non-fermentative catalytic routes has been recently proposed. This review is aimed at providing an overview on three different emerging and promising catalytic routes from biomass/organic waste-derived chemicals to butanol. The first route involves the conversion of ethanol into butanol over metal and oxide catalysts. Volatile fatty acid can be a raw chemical for the production of butanol using porous materials and metal catalysts. In addition, biomass-derived syngas can be transformed to butanol on non-noble metal catalysts promoted by alkali metals. The prospect of catalytic renewable butanol production is also discussed.
format article
author Heeyoung Choi
Jeehoon Han
Jechan Lee
author_facet Heeyoung Choi
Jeehoon Han
Jechan Lee
author_sort Heeyoung Choi
title Renewable Butanol Production via Catalytic Routes
title_short Renewable Butanol Production via Catalytic Routes
title_full Renewable Butanol Production via Catalytic Routes
title_fullStr Renewable Butanol Production via Catalytic Routes
title_full_unstemmed Renewable Butanol Production via Catalytic Routes
title_sort renewable butanol production via catalytic routes
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/08494fab8f8046119419949fd7c611f7
work_keys_str_mv AT heeyoungchoi renewablebutanolproductionviacatalyticroutes
AT jeehoonhan renewablebutanolproductionviacatalyticroutes
AT jechanlee renewablebutanolproductionviacatalyticroutes
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