Divergent synthesis of N-heterocycles via controllable cyclization of azido-diynes catalyzed by copper and gold

Divergent synthesis of N-heterocycles via controllable cyclization of azido-diynes catalyzed by copper and gold

Fused N-heterocycles are structural motifs observed in natural products and bioactive compounds. Here, the authors developed divergent copper- and gold-catalyzed oxidative cyclizations of diynes to two types of tricyclic N-heterocycles and rationalized the product selectivity by theoretical calculat...

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Autores principales: Wen-Bo Shen, Qing Sun, Long Li, Xin Liu, Bo Zhou, Juan-Zhu Yan, Xin Lu, Long-Wu Ye
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/086bb13dab3848118b4404dea44a007b
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spelling oai:doaj.org-article:086bb13dab3848118b4404dea44a007b2021-12-02T17:01:18ZDivergent synthesis of N-heterocycles via controllable cyclization of azido-diynes catalyzed by copper and gold10.1038/s41467-017-01853-12041-1723https://doaj.org/article/086bb13dab3848118b4404dea44a007b2017-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-01853-1https://doaj.org/toc/2041-1723Fused N-heterocycles are structural motifs observed in natural products and bioactive compounds. Here, the authors developed divergent copper- and gold-catalyzed oxidative cyclizations of diynes to two types of tricyclic N-heterocycles and rationalized the product selectivity by theoretical calculations.Wen-Bo ShenQing SunLong LiXin LiuBo ZhouJuan-Zhu YanXin LuLong-Wu YeNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-9 (2017)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Wen-Bo Shen
Qing Sun
Long Li
Xin Liu
Bo Zhou
Juan-Zhu Yan
Xin Lu
Long-Wu Ye
Divergent synthesis of N-heterocycles via controllable cyclization of azido-diynes catalyzed by copper and gold
description Fused N-heterocycles are structural motifs observed in natural products and bioactive compounds. Here, the authors developed divergent copper- and gold-catalyzed oxidative cyclizations of diynes to two types of tricyclic N-heterocycles and rationalized the product selectivity by theoretical calculations.
format article
author Wen-Bo Shen
Qing Sun
Long Li
Xin Liu
Bo Zhou
Juan-Zhu Yan
Xin Lu
Long-Wu Ye
author_facet Wen-Bo Shen
Qing Sun
Long Li
Xin Liu
Bo Zhou
Juan-Zhu Yan
Xin Lu
Long-Wu Ye
author_sort Wen-Bo Shen
title Divergent synthesis of N-heterocycles via controllable cyclization of azido-diynes catalyzed by copper and gold
title_short Divergent synthesis of N-heterocycles via controllable cyclization of azido-diynes catalyzed by copper and gold
title_full Divergent synthesis of N-heterocycles via controllable cyclization of azido-diynes catalyzed by copper and gold
title_fullStr Divergent synthesis of N-heterocycles via controllable cyclization of azido-diynes catalyzed by copper and gold
title_full_unstemmed Divergent synthesis of N-heterocycles via controllable cyclization of azido-diynes catalyzed by copper and gold
title_sort divergent synthesis of n-heterocycles via controllable cyclization of azido-diynes catalyzed by copper and gold
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/086bb13dab3848118b4404dea44a007b
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