Bio-inspired creation of heterogeneous reaction vessels via polymerization of supramolecular ion pair

Tuning the environment of catalytic active sites may improve the selectivity of heterogeneous catalysts. Here, the authors modify the outer-sphere environment of active sites in hydroformylation catalysts by encapsulating the active sites in nanovessels formed by ion pair-directed supramolecular ass...

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Bibliographic Details
Main Authors: Ke Dong, Qi Sun, Yongquan Tang, Chuan Shan, Briana Aguila, Sai Wang, Xiangju Meng, Shengqian Ma, Feng-Shou Xiao
Format: article
Language:EN
Published: Nature Portfolio 2019
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Online Access:https://doaj.org/article/0877363f7322426c8d3d9ba7e9a49da2
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Summary:Tuning the environment of catalytic active sites may improve the selectivity of heterogeneous catalysts. Here, the authors modify the outer-sphere environment of active sites in hydroformylation catalysts by encapsulating the active sites in nanovessels formed by ion pair-directed supramolecular assembly.