Olefin oligomerization by main group Ga3+ and Zn2+ single site catalysts on SiO2

Olefin oligomerization by main group Ga3+ and Zn2+ single site catalysts on SiO2

Silica-supported, single site, main group Zn(II) and Ga(III) ions catalyze ethylene and propylene oligomerization. Here, experimental and theoretical evidence suggests a Cossee-Arlman reaction mechanism similar to that for transition metal catalysts.

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Autores principales: Nicole J. LiBretto, Yinan Xu, Aubrey Quigley, Ethan Edwards, Rhea Nargund, Juan Carlos Vega-Vila, Richard Caulkins, Arunima Saxena, Rajamani Gounder, Jeffrey Greeley, Guanghui Zhang, Jeffrey T. Miller
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/0883a7441fb2463d8acac813c97935cd
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spelling oai:doaj.org-article:0883a7441fb2463d8acac813c97935cd2021-12-02T16:45:10ZOlefin oligomerization by main group Ga3+ and Zn2+ single site catalysts on SiO210.1038/s41467-021-22512-62041-1723https://doaj.org/article/0883a7441fb2463d8acac813c97935cd2021-04-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-22512-6https://doaj.org/toc/2041-1723Silica-supported, single site, main group Zn(II) and Ga(III) ions catalyze ethylene and propylene oligomerization. Here, experimental and theoretical evidence suggests a Cossee-Arlman reaction mechanism similar to that for transition metal catalysts.Nicole J. LiBrettoYinan XuAubrey QuigleyEthan EdwardsRhea NargundJuan Carlos Vega-VilaRichard CaulkinsArunima SaxenaRajamani GounderJeffrey GreeleyGuanghui ZhangJeffrey T. MillerNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Nicole J. LiBretto
Yinan Xu
Aubrey Quigley
Ethan Edwards
Rhea Nargund
Juan Carlos Vega-Vila
Richard Caulkins
Arunima Saxena
Rajamani Gounder
Jeffrey Greeley
Guanghui Zhang
Jeffrey T. Miller
Olefin oligomerization by main group Ga3+ and Zn2+ single site catalysts on SiO2
description Silica-supported, single site, main group Zn(II) and Ga(III) ions catalyze ethylene and propylene oligomerization. Here, experimental and theoretical evidence suggests a Cossee-Arlman reaction mechanism similar to that for transition metal catalysts.
format article
author Nicole J. LiBretto
Yinan Xu
Aubrey Quigley
Ethan Edwards
Rhea Nargund
Juan Carlos Vega-Vila
Richard Caulkins
Arunima Saxena
Rajamani Gounder
Jeffrey Greeley
Guanghui Zhang
Jeffrey T. Miller
author_facet Nicole J. LiBretto
Yinan Xu
Aubrey Quigley
Ethan Edwards
Rhea Nargund
Juan Carlos Vega-Vila
Richard Caulkins
Arunima Saxena
Rajamani Gounder
Jeffrey Greeley
Guanghui Zhang
Jeffrey T. Miller
author_sort Nicole J. LiBretto
title Olefin oligomerization by main group Ga3+ and Zn2+ single site catalysts on SiO2
title_short Olefin oligomerization by main group Ga3+ and Zn2+ single site catalysts on SiO2
title_full Olefin oligomerization by main group Ga3+ and Zn2+ single site catalysts on SiO2
title_fullStr Olefin oligomerization by main group Ga3+ and Zn2+ single site catalysts on SiO2
title_full_unstemmed Olefin oligomerization by main group Ga3+ and Zn2+ single site catalysts on SiO2
title_sort olefin oligomerization by main group ga3+ and zn2+ single site catalysts on sio2
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/0883a7441fb2463d8acac813c97935cd
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