Olefin oligomerization by main group Ga3+ and Zn2+ single site catalysts on SiO2

Olefin oligomerization by main group Ga3+ and Zn2+ single site catalysts on SiO2

Silica-supported, single site, main group Zn(II) and Ga(III) ions catalyze ethylene and propylene oligomerization. Here, experimental and theoretical evidence suggests a Cossee-Arlman reaction mechanism similar to that for transition metal catalysts.

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Autores principales: Nicole J. LiBretto, Yinan Xu, Aubrey Quigley, Ethan Edwards, Rhea Nargund, Juan Carlos Vega-Vila, Richard Caulkins, Arunima Saxena, Rajamani Gounder, Jeffrey Greeley, Guanghui Zhang, Jeffrey T. Miller
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Science
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Acceso en línea:https://doaj.org/article/0883a7441fb2463d8acac813c97935cd
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