Electrochemical performance of hierarchical hollow CoMn<sub>2</sub>O<sub>4</sub> hanospheres <i>in-situ</i> grown on nickel foam as supercapacitor electrode materials
Hierarchical hollow nanospheres of cobalt manganese oxide(CoMn<sub>2</sub>O<sub>4</sub>) on nickel foam(NF) are facilely synthesized by a hydrothermal method and post heat treatment in air, and further characterized by diffraction of X-rays(XRD), field emission scanning elect...
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Academic Journals Center of Shanghai Normal University
2021
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oai:doaj.org-article:088f3a824d3e4a26b89bb547b78c30052021-11-12T03:34:00ZElectrochemical performance of hierarchical hollow CoMn<sub>2</sub>O<sub>4</sub> hanospheres <i>in-situ</i> grown on nickel foam as supercapacitor electrode materials1000-513710.3969/J.ISSN.1000-5137.2021.05.009https://doaj.org/article/088f3a824d3e4a26b89bb547b78c30052021-10-01T00:00:00Zhttp://qktg.shnu.edu.cn/zrb/shsfqkszrb/ch/reader/view_abstract.aspx?file_no=20210509https://doaj.org/toc/1000-5137Hierarchical hollow nanospheres of cobalt manganese oxide(CoMn<sub>2</sub>O<sub>4</sub>) on nickel foam(NF) are facilely synthesized by a hydrothermal method and post heat treatment in air, and further characterized by diffraction of X-rays(XRD), field emission scanning electron microscope (FE-SEM) and X-ray photoelectron spectroscopy(XPS). In a three-electrode system of electrochemical measurement, the areal capacitance of 0.1 Co<sup>2+</sup>-250 electrode material is as high as 6 184 mF·cm<sup>-2</sup> at 5 mA·cm<sup>-2</sup>. The hybrid supercapacitor assembled by 0.1 Co<sup>2+</sup>-250 as the positive electrode and commercial activated carbon (AC) as negative electrode presents a maximum energy density of 0.112 mWh·cm<sup>-2</sup> at 1.6 mW·cm<sup>-2</sup>. Even at the power density of 16 mW cm<sup>-2</sup>, the energy density still reaches 0.064 mWh·cm<sup>-2</sup>. After 10 000 charge/discharge cycles under the current density of 2 mA·cm<sup>-2</sup>, the capacitance retains 93% of the initial value. With excellent electrochemical performance and facilely cost-effective synthesis, such hierarchical CoMn<sub>2</sub>O<sub>4</sub> electrode material may hold great promise for high-performance supercapacitor applications.GE ZongyunZHOU QingyaGUO AipingWANG ZhenhuaHUANG JinpingAcademic Journals Center of Shanghai Normal Universityarticlecobalt manganese oxide(comn<sub>2</sub>o<sub>4</sub>)hierarchical hollow nanosphereshybrid supercapacitorelectrochemical performanceareal capacitanceenergy densitypower densityScience (General)Q1-390ENZHJournal of Shanghai Normal University (Natural Sciences), Vol 50, Iss 5, Pp 586-596 (2021) |
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EN ZH |
topic |
cobalt manganese oxide(comn<sub>2</sub>o<sub>4</sub>) hierarchical hollow nanospheres hybrid supercapacitor electrochemical performance areal capacitance energy density power density Science (General) Q1-390 |
spellingShingle |
cobalt manganese oxide(comn<sub>2</sub>o<sub>4</sub>) hierarchical hollow nanospheres hybrid supercapacitor electrochemical performance areal capacitance energy density power density Science (General) Q1-390 GE Zongyun ZHOU Qingya GUO Aiping WANG Zhenhua HUANG Jinping Electrochemical performance of hierarchical hollow CoMn<sub>2</sub>O<sub>4</sub> hanospheres <i>in-situ</i> grown on nickel foam as supercapacitor electrode materials |
description |
Hierarchical hollow nanospheres of cobalt manganese oxide(CoMn<sub>2</sub>O<sub>4</sub>) on nickel foam(NF) are facilely synthesized by a hydrothermal method and post heat treatment in air, and further characterized by diffraction of X-rays(XRD), field emission scanning electron microscope (FE-SEM) and X-ray photoelectron spectroscopy(XPS). In a three-electrode system of electrochemical measurement, the areal capacitance of 0.1 Co<sup>2+</sup>-250 electrode material is as high as 6 184 mF·cm<sup>-2</sup> at 5 mA·cm<sup>-2</sup>. The hybrid supercapacitor assembled by 0.1 Co<sup>2+</sup>-250 as the positive electrode and commercial activated carbon (AC) as negative electrode presents a maximum energy density of 0.112 mWh·cm<sup>-2</sup> at 1.6 mW·cm<sup>-2</sup>. Even at the power density of 16 mW cm<sup>-2</sup>, the energy density still reaches 0.064 mWh·cm<sup>-2</sup>. After 10 000 charge/discharge cycles under the current density of 2 mA·cm<sup>-2</sup>, the capacitance retains 93% of the initial value. With excellent electrochemical performance and facilely cost-effective synthesis, such hierarchical CoMn<sub>2</sub>O<sub>4</sub> electrode material may hold great promise for high-performance supercapacitor applications. |
format |
article |
author |
GE Zongyun ZHOU Qingya GUO Aiping WANG Zhenhua HUANG Jinping |
author_facet |
GE Zongyun ZHOU Qingya GUO Aiping WANG Zhenhua HUANG Jinping |
author_sort |
GE Zongyun |
title |
Electrochemical performance of hierarchical hollow CoMn<sub>2</sub>O<sub>4</sub> hanospheres <i>in-situ</i> grown on nickel foam as supercapacitor electrode materials |
title_short |
Electrochemical performance of hierarchical hollow CoMn<sub>2</sub>O<sub>4</sub> hanospheres <i>in-situ</i> grown on nickel foam as supercapacitor electrode materials |
title_full |
Electrochemical performance of hierarchical hollow CoMn<sub>2</sub>O<sub>4</sub> hanospheres <i>in-situ</i> grown on nickel foam as supercapacitor electrode materials |
title_fullStr |
Electrochemical performance of hierarchical hollow CoMn<sub>2</sub>O<sub>4</sub> hanospheres <i>in-situ</i> grown on nickel foam as supercapacitor electrode materials |
title_full_unstemmed |
Electrochemical performance of hierarchical hollow CoMn<sub>2</sub>O<sub>4</sub> hanospheres <i>in-situ</i> grown on nickel foam as supercapacitor electrode materials |
title_sort |
electrochemical performance of hierarchical hollow comn<sub>2</sub>o<sub>4</sub> hanospheres <i>in-situ</i> grown on nickel foam as supercapacitor electrode materials |
publisher |
Academic Journals Center of Shanghai Normal University |
publishDate |
2021 |
url |
https://doaj.org/article/088f3a824d3e4a26b89bb547b78c3005 |
work_keys_str_mv |
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