Electrochemical performance of hierarchical hollow CoMn<sub>2</sub>O<sub>4</sub> hanospheres <i>in-situ</i> grown on nickel foam as supercapacitor electrode materials

Hierarchical hollow nanospheres of cobalt manganese oxide(CoMn<sub>2</sub>O<sub>4</sub>) on nickel foam(NF) are facilely synthesized by a hydrothermal method and post heat treatment in air, and further characterized by diffraction of X-rays(XRD), field emission scanning elect...

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Autores principales: GE Zongyun, ZHOU Qingya, GUO Aiping, WANG Zhenhua, HUANG Jinping
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Publicado: Academic Journals Center of Shanghai Normal University 2021
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spelling oai:doaj.org-article:088f3a824d3e4a26b89bb547b78c30052021-11-12T03:34:00ZElectrochemical performance of hierarchical hollow CoMn<sub>2</sub>O<sub>4</sub> hanospheres <i>in-situ</i> grown on nickel foam as supercapacitor electrode materials1000-513710.3969/J.ISSN.1000-5137.2021.05.009https://doaj.org/article/088f3a824d3e4a26b89bb547b78c30052021-10-01T00:00:00Zhttp://qktg.shnu.edu.cn/zrb/shsfqkszrb/ch/reader/view_abstract.aspx?file_no=20210509https://doaj.org/toc/1000-5137Hierarchical hollow nanospheres of cobalt manganese oxide(CoMn<sub>2</sub>O<sub>4</sub>) on nickel foam(NF) are facilely synthesized by a hydrothermal method and post heat treatment in air, and further characterized by diffraction of X-rays(XRD), field emission scanning electron microscope (FE-SEM) and X-ray photoelectron spectroscopy(XPS). In a three-electrode system of electrochemical measurement, the areal capacitance of 0.1 Co<sup>2+</sup>-250 electrode material is as high as 6 184 mF·cm<sup>-2</sup> at 5 mA·cm<sup>-2</sup>. The hybrid supercapacitor assembled by 0.1 Co<sup>2+</sup>-250 as the positive electrode and commercial activated carbon (AC) as negative electrode presents a maximum energy density of 0.112 mWh·cm<sup>-2</sup> at 1.6 mW·cm<sup>-2</sup>. Even at the power density of 16 mW cm<sup>-2</sup>, the energy density still reaches 0.064 mWh·cm<sup>-2</sup>. After 10 000 charge/discharge cycles under the current density of 2 mA·cm<sup>-2</sup>, the capacitance retains 93% of the initial value. With excellent electrochemical performance and facilely cost-effective synthesis, such hierarchical CoMn<sub>2</sub>O<sub>4</sub> electrode material may hold great promise for high-performance supercapacitor applications.GE ZongyunZHOU QingyaGUO AipingWANG ZhenhuaHUANG JinpingAcademic Journals Center of Shanghai Normal Universityarticlecobalt manganese oxide(comn<sub>2</sub>o<sub>4</sub>)hierarchical hollow nanosphereshybrid supercapacitorelectrochemical performanceareal capacitanceenergy densitypower densityScience (General)Q1-390ENZHJournal of Shanghai Normal University (Natural Sciences), Vol 50, Iss 5, Pp 586-596 (2021)
institution DOAJ
collection DOAJ
language EN
ZH
topic cobalt manganese oxide(comn<sub>2</sub>o<sub>4</sub>)
hierarchical hollow nanospheres
hybrid supercapacitor
electrochemical performance
areal capacitance
energy density
power density
Science (General)
Q1-390
spellingShingle cobalt manganese oxide(comn<sub>2</sub>o<sub>4</sub>)
hierarchical hollow nanospheres
hybrid supercapacitor
electrochemical performance
areal capacitance
energy density
power density
Science (General)
Q1-390
GE Zongyun
ZHOU Qingya
GUO Aiping
WANG Zhenhua
HUANG Jinping
Electrochemical performance of hierarchical hollow CoMn<sub>2</sub>O<sub>4</sub> hanospheres <i>in-situ</i> grown on nickel foam as supercapacitor electrode materials
description Hierarchical hollow nanospheres of cobalt manganese oxide(CoMn<sub>2</sub>O<sub>4</sub>) on nickel foam(NF) are facilely synthesized by a hydrothermal method and post heat treatment in air, and further characterized by diffraction of X-rays(XRD), field emission scanning electron microscope (FE-SEM) and X-ray photoelectron spectroscopy(XPS). In a three-electrode system of electrochemical measurement, the areal capacitance of 0.1 Co<sup>2+</sup>-250 electrode material is as high as 6 184 mF·cm<sup>-2</sup> at 5 mA·cm<sup>-2</sup>. The hybrid supercapacitor assembled by 0.1 Co<sup>2+</sup>-250 as the positive electrode and commercial activated carbon (AC) as negative electrode presents a maximum energy density of 0.112 mWh·cm<sup>-2</sup> at 1.6 mW·cm<sup>-2</sup>. Even at the power density of 16 mW cm<sup>-2</sup>, the energy density still reaches 0.064 mWh·cm<sup>-2</sup>. After 10 000 charge/discharge cycles under the current density of 2 mA·cm<sup>-2</sup>, the capacitance retains 93% of the initial value. With excellent electrochemical performance and facilely cost-effective synthesis, such hierarchical CoMn<sub>2</sub>O<sub>4</sub> electrode material may hold great promise for high-performance supercapacitor applications.
format article
author GE Zongyun
ZHOU Qingya
GUO Aiping
WANG Zhenhua
HUANG Jinping
author_facet GE Zongyun
ZHOU Qingya
GUO Aiping
WANG Zhenhua
HUANG Jinping
author_sort GE Zongyun
title Electrochemical performance of hierarchical hollow CoMn<sub>2</sub>O<sub>4</sub> hanospheres <i>in-situ</i> grown on nickel foam as supercapacitor electrode materials
title_short Electrochemical performance of hierarchical hollow CoMn<sub>2</sub>O<sub>4</sub> hanospheres <i>in-situ</i> grown on nickel foam as supercapacitor electrode materials
title_full Electrochemical performance of hierarchical hollow CoMn<sub>2</sub>O<sub>4</sub> hanospheres <i>in-situ</i> grown on nickel foam as supercapacitor electrode materials
title_fullStr Electrochemical performance of hierarchical hollow CoMn<sub>2</sub>O<sub>4</sub> hanospheres <i>in-situ</i> grown on nickel foam as supercapacitor electrode materials
title_full_unstemmed Electrochemical performance of hierarchical hollow CoMn<sub>2</sub>O<sub>4</sub> hanospheres <i>in-situ</i> grown on nickel foam as supercapacitor electrode materials
title_sort electrochemical performance of hierarchical hollow comn<sub>2</sub>o<sub>4</sub> hanospheres <i>in-situ</i> grown on nickel foam as supercapacitor electrode materials
publisher Academic Journals Center of Shanghai Normal University
publishDate 2021
url https://doaj.org/article/088f3a824d3e4a26b89bb547b78c3005
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