Mechanism of copper-free Sonogashira reaction operates through palladium-palladium transmetallation

Mechanism of copper-free Sonogashira reaction operates through palladium-palladium transmetallation

Although the Sonogashira coupling of acetylenes and vinyl/aryl halides has been applied for decades, many mechanistic questions have remained unanswered. Here, the authors provide experimental and theoretical support for two interlinked palladium cycles operating in the debated Sonogashira coupling...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: Martin Gazvoda, Miha Virant, Balazs Pinter, Janez Košmrlj
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2018
Materias:
Science
Q
Acceso en línea:https://doaj.org/article/08ce460536eb49aca9fe455ff76b57bf
Etiquetas: Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
id oai:doaj.org-article:08ce460536eb49aca9fe455ff76b57bf
record_format dspace
spelling oai:doaj.org-article:08ce460536eb49aca9fe455ff76b57bf2021-12-02T17:33:17ZMechanism of copper-free Sonogashira reaction operates through palladium-palladium transmetallation10.1038/s41467-018-07081-52041-1723https://doaj.org/article/08ce460536eb49aca9fe455ff76b57bf2018-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-07081-5https://doaj.org/toc/2041-1723Although the Sonogashira coupling of acetylenes and vinyl/aryl halides has been applied for decades, many mechanistic questions have remained unanswered. Here, the authors provide experimental and theoretical support for two interlinked palladium cycles operating in the debated Sonogashira coupling mechanism.Martin GazvodaMiha VirantBalazs PinterJanez KošmrljNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-9 (2018)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Martin Gazvoda
Miha Virant
Balazs Pinter
Janez Košmrlj
Mechanism of copper-free Sonogashira reaction operates through palladium-palladium transmetallation
description Although the Sonogashira coupling of acetylenes and vinyl/aryl halides has been applied for decades, many mechanistic questions have remained unanswered. Here, the authors provide experimental and theoretical support for two interlinked palladium cycles operating in the debated Sonogashira coupling mechanism.
format article
author Martin Gazvoda
Miha Virant
Balazs Pinter
Janez Košmrlj
author_facet Martin Gazvoda
Miha Virant
Balazs Pinter
Janez Košmrlj
author_sort Martin Gazvoda
title Mechanism of copper-free Sonogashira reaction operates through palladium-palladium transmetallation
title_short Mechanism of copper-free Sonogashira reaction operates through palladium-palladium transmetallation
title_full Mechanism of copper-free Sonogashira reaction operates through palladium-palladium transmetallation
title_fullStr Mechanism of copper-free Sonogashira reaction operates through palladium-palladium transmetallation
title_full_unstemmed Mechanism of copper-free Sonogashira reaction operates through palladium-palladium transmetallation
title_sort mechanism of copper-free sonogashira reaction operates through palladium-palladium transmetallation
publisher Nature Portfolio
publishDate 2018
url https://doaj.org/article/08ce460536eb49aca9fe455ff76b57bf
work_keys_str_mv AT martingazvoda mechanismofcopperfreesonogashirareactionoperatesthroughpalladiumpalladiumtransmetallation
AT mihavirant mechanismofcopperfreesonogashirareactionoperatesthroughpalladiumpalladiumtransmetallation
AT balazspinter mechanismofcopperfreesonogashirareactionoperatesthroughpalladiumpalladiumtransmetallation
AT janezkosmrlj mechanismofcopperfreesonogashirareactionoperatesthroughpalladiumpalladiumtransmetallation
_version_ 1718379981021642752

Ejemplares similares