Asymmetric one-pot transformation of isoflavones to pterocarpans and its application in phytoalexin synthesis
Concise total syntheses of 6a-hydroxypterocarpans are sought after due to their broad spectrum of bioactivities. Here, the authors report the asymmetric syntheses of several natural isoflavonoids, including (−)-glyceollin I and (−)-glyceollin II, by means of an asymmetric transfer hydrogenation (ATH...
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2020
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oai:doaj.org-article:094b56a46bb64a858a89636719aa66bc2021-12-02T17:23:49ZAsymmetric one-pot transformation of isoflavones to pterocarpans and its application in phytoalexin synthesis10.1038/s41467-020-16933-y2041-1723https://doaj.org/article/094b56a46bb64a858a89636719aa66bc2020-06-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-16933-yhttps://doaj.org/toc/2041-1723Concise total syntheses of 6a-hydroxypterocarpans are sought after due to their broad spectrum of bioactivities. Here, the authors report the asymmetric syntheses of several natural isoflavonoids, including (−)-glyceollin I and (−)-glyceollin II, by means of an asymmetric transfer hydrogenation (ATH) reaction.Philipp CiesielskiPeter MetzNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-8 (2020) |
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Science Q Philipp Ciesielski Peter Metz Asymmetric one-pot transformation of isoflavones to pterocarpans and its application in phytoalexin synthesis |
description |
Concise total syntheses of 6a-hydroxypterocarpans are sought after due to their broad spectrum of bioactivities. Here, the authors report the asymmetric syntheses of several natural isoflavonoids, including (−)-glyceollin I and (−)-glyceollin II, by means of an asymmetric transfer hydrogenation (ATH) reaction. |
format |
article |
author |
Philipp Ciesielski Peter Metz |
author_facet |
Philipp Ciesielski Peter Metz |
author_sort |
Philipp Ciesielski |
title |
Asymmetric one-pot transformation of isoflavones to pterocarpans and its application in phytoalexin synthesis |
title_short |
Asymmetric one-pot transformation of isoflavones to pterocarpans and its application in phytoalexin synthesis |
title_full |
Asymmetric one-pot transformation of isoflavones to pterocarpans and its application in phytoalexin synthesis |
title_fullStr |
Asymmetric one-pot transformation of isoflavones to pterocarpans and its application in phytoalexin synthesis |
title_full_unstemmed |
Asymmetric one-pot transformation of isoflavones to pterocarpans and its application in phytoalexin synthesis |
title_sort |
asymmetric one-pot transformation of isoflavones to pterocarpans and its application in phytoalexin synthesis |
publisher |
Nature Portfolio |
publishDate |
2020 |
url |
https://doaj.org/article/094b56a46bb64a858a89636719aa66bc |
work_keys_str_mv |
AT philippciesielski asymmetriconepottransformationofisoflavonestopterocarpansanditsapplicationinphytoalexinsynthesis AT petermetz asymmetriconepottransformationofisoflavonestopterocarpansanditsapplicationinphytoalexinsynthesis |
_version_ |
1718380949200175104 |