Asymmetric one-pot transformation of isoflavones to pterocarpans and its application in phytoalexin synthesis

Concise total syntheses of 6a-hydroxypterocarpans are sought after due to their broad spectrum of bioactivities. Here, the authors report the asymmetric syntheses of several natural isoflavonoids, including (−)-glyceollin I and (−)-glyceollin II, by means of an asymmetric transfer hydrogenation (ATH...

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Autores principales: Philipp Ciesielski, Peter Metz
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Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/094b56a46bb64a858a89636719aa66bc
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spelling oai:doaj.org-article:094b56a46bb64a858a89636719aa66bc2021-12-02T17:23:49ZAsymmetric one-pot transformation of isoflavones to pterocarpans and its application in phytoalexin synthesis10.1038/s41467-020-16933-y2041-1723https://doaj.org/article/094b56a46bb64a858a89636719aa66bc2020-06-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-16933-yhttps://doaj.org/toc/2041-1723Concise total syntheses of 6a-hydroxypterocarpans are sought after due to their broad spectrum of bioactivities. Here, the authors report the asymmetric syntheses of several natural isoflavonoids, including (−)-glyceollin I and (−)-glyceollin II, by means of an asymmetric transfer hydrogenation (ATH) reaction.Philipp CiesielskiPeter MetzNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-8 (2020)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Philipp Ciesielski
Peter Metz
Asymmetric one-pot transformation of isoflavones to pterocarpans and its application in phytoalexin synthesis
description Concise total syntheses of 6a-hydroxypterocarpans are sought after due to their broad spectrum of bioactivities. Here, the authors report the asymmetric syntheses of several natural isoflavonoids, including (−)-glyceollin I and (−)-glyceollin II, by means of an asymmetric transfer hydrogenation (ATH) reaction.
format article
author Philipp Ciesielski
Peter Metz
author_facet Philipp Ciesielski
Peter Metz
author_sort Philipp Ciesielski
title Asymmetric one-pot transformation of isoflavones to pterocarpans and its application in phytoalexin synthesis
title_short Asymmetric one-pot transformation of isoflavones to pterocarpans and its application in phytoalexin synthesis
title_full Asymmetric one-pot transformation of isoflavones to pterocarpans and its application in phytoalexin synthesis
title_fullStr Asymmetric one-pot transformation of isoflavones to pterocarpans and its application in phytoalexin synthesis
title_full_unstemmed Asymmetric one-pot transformation of isoflavones to pterocarpans and its application in phytoalexin synthesis
title_sort asymmetric one-pot transformation of isoflavones to pterocarpans and its application in phytoalexin synthesis
publisher Nature Portfolio
publishDate 2020
url https://doaj.org/article/094b56a46bb64a858a89636719aa66bc
work_keys_str_mv AT philippciesielski asymmetriconepottransformationofisoflavonestopterocarpansanditsapplicationinphytoalexinsynthesis
AT petermetz asymmetriconepottransformationofisoflavonestopterocarpansanditsapplicationinphytoalexinsynthesis
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