Asymmetric one-pot transformation of isoflavones to pterocarpans and its application in phytoalexin synthesis

Concise total syntheses of 6a-hydroxypterocarpans are sought after due to their broad spectrum of bioactivities. Here, the authors report the asymmetric syntheses of several natural isoflavonoids, including (−)-glyceollin I and (−)-glyceollin II, by means of an asymmetric transfer hydrogenation (ATH...

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Auteurs principaux:	Philipp Ciesielski, Peter Metz
Format:	article
Langue:	EN
Publié:	Nature Portfolio 2020
Sujets:	Science Q
Accès en ligne:	https://doaj.org/article/094b56a46bb64a858a89636719aa66bc
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spelling	oai:doaj.org-article:094b56a46bb64a858a89636719aa66bc2021-12-02T17:23:49ZAsymmetric one-pot transformation of isoflavones to pterocarpans and its application in phytoalexin synthesis10.1038/s41467-020-16933-y2041-1723https://doaj.org/article/094b56a46bb64a858a89636719aa66bc2020-06-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-16933-yhttps://doaj.org/toc/2041-1723Concise total syntheses of 6a-hydroxypterocarpans are sought after due to their broad spectrum of bioactivities. Here, the authors report the asymmetric syntheses of several natural isoflavonoids, including (−)-glyceollin I and (−)-glyceollin II, by means of an asymmetric transfer hydrogenation (ATH) reaction.Philipp CiesielskiPeter MetzNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-8 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Philipp Ciesielski Peter Metz Asymmetric one-pot transformation of isoflavones to pterocarpans and its application in phytoalexin synthesis
description	Concise total syntheses of 6a-hydroxypterocarpans are sought after due to their broad spectrum of bioactivities. Here, the authors report the asymmetric syntheses of several natural isoflavonoids, including (−)-glyceollin I and (−)-glyceollin II, by means of an asymmetric transfer hydrogenation (ATH) reaction.
format	article
author	Philipp Ciesielski Peter Metz
author_facet	Philipp Ciesielski Peter Metz
author_sort	Philipp Ciesielski
title	Asymmetric one-pot transformation of isoflavones to pterocarpans and its application in phytoalexin synthesis
title_short	Asymmetric one-pot transformation of isoflavones to pterocarpans and its application in phytoalexin synthesis
title_full	Asymmetric one-pot transformation of isoflavones to pterocarpans and its application in phytoalexin synthesis
title_fullStr	Asymmetric one-pot transformation of isoflavones to pterocarpans and its application in phytoalexin synthesis
title_full_unstemmed	Asymmetric one-pot transformation of isoflavones to pterocarpans and its application in phytoalexin synthesis
title_sort	asymmetric one-pot transformation of isoflavones to pterocarpans and its application in phytoalexin synthesis
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/094b56a46bb64a858a89636719aa66bc
work_keys_str_mv	AT philippciesielski asymmetriconepottransformationofisoflavonestopterocarpansanditsapplicationinphytoalexinsynthesis AT petermetz asymmetriconepottransformationofisoflavonestopterocarpansanditsapplicationinphytoalexinsynthesis
_version_	1718380949200175104

Asymmetric one-pot transformation of isoflavones to pterocarpans and its application in phytoalexin synthesis

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