Sequence-selective dynamic covalent assembly of information-bearing oligomers

Dynamic covalent interactions have been employed to mediate molecular self-assembly reactions but often do not converge to a thermodynamic equilibrium and yield a mixture of kinetically trapped species. Here, the authors show a sequence-selective, dynamic covalent self-assembly process that mitigate...

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Autores principales: Samuel C. Leguizamon, Timothy F. Scott
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/09df118c738a420c9464aa05784992ac
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spelling oai:doaj.org-article:09df118c738a420c9464aa05784992ac2021-12-02T14:41:26ZSequence-selective dynamic covalent assembly of information-bearing oligomers10.1038/s41467-020-14607-32041-1723https://doaj.org/article/09df118c738a420c9464aa05784992ac2020-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-14607-3https://doaj.org/toc/2041-1723Dynamic covalent interactions have been employed to mediate molecular self-assembly reactions but often do not converge to a thermodynamic equilibrium and yield a mixture of kinetically trapped species. Here, the authors show a sequence-selective, dynamic covalent self-assembly process that mitigates kinetic trapping to afford biomimetic molecular ladders with covalent rungs.Samuel C. LeguizamonTimothy F. ScottNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-10 (2020)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Samuel C. Leguizamon
Timothy F. Scott
Sequence-selective dynamic covalent assembly of information-bearing oligomers
description Dynamic covalent interactions have been employed to mediate molecular self-assembly reactions but often do not converge to a thermodynamic equilibrium and yield a mixture of kinetically trapped species. Here, the authors show a sequence-selective, dynamic covalent self-assembly process that mitigates kinetic trapping to afford biomimetic molecular ladders with covalent rungs.
format article
author Samuel C. Leguizamon
Timothy F. Scott
author_facet Samuel C. Leguizamon
Timothy F. Scott
author_sort Samuel C. Leguizamon
title Sequence-selective dynamic covalent assembly of information-bearing oligomers
title_short Sequence-selective dynamic covalent assembly of information-bearing oligomers
title_full Sequence-selective dynamic covalent assembly of information-bearing oligomers
title_fullStr Sequence-selective dynamic covalent assembly of information-bearing oligomers
title_full_unstemmed Sequence-selective dynamic covalent assembly of information-bearing oligomers
title_sort sequence-selective dynamic covalent assembly of information-bearing oligomers
publisher Nature Portfolio
publishDate 2020
url https://doaj.org/article/09df118c738a420c9464aa05784992ac
work_keys_str_mv AT samuelcleguizamon sequenceselectivedynamiccovalentassemblyofinformationbearingoligomers
AT timothyfscott sequenceselectivedynamiccovalentassemblyofinformationbearingoligomers
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