Sequence-selective dynamic covalent assembly of information-bearing oligomers

Dynamic covalent interactions have been employed to mediate molecular self-assembly reactions but often do not converge to a thermodynamic equilibrium and yield a mixture of kinetically trapped species. Here, the authors show a sequence-selective, dynamic covalent self-assembly process that mitigate...

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Main Authors:	Samuel C. Leguizamon, Timothy F. Scott
Format:	article
Language:	EN
Published:	Nature Portfolio 2020
Subjects:	Science Q
Online Access:	https://doaj.org/article/09df118c738a420c9464aa05784992ac
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spelling	oai:doaj.org-article:09df118c738a420c9464aa05784992ac2021-12-02T14:41:26ZSequence-selective dynamic covalent assembly of information-bearing oligomers10.1038/s41467-020-14607-32041-1723https://doaj.org/article/09df118c738a420c9464aa05784992ac2020-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-14607-3https://doaj.org/toc/2041-1723Dynamic covalent interactions have been employed to mediate molecular self-assembly reactions but often do not converge to a thermodynamic equilibrium and yield a mixture of kinetically trapped species. Here, the authors show a sequence-selective, dynamic covalent self-assembly process that mitigates kinetic trapping to afford biomimetic molecular ladders with covalent rungs.Samuel C. LeguizamonTimothy F. ScottNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-10 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Samuel C. Leguizamon Timothy F. Scott Sequence-selective dynamic covalent assembly of information-bearing oligomers
description	Dynamic covalent interactions have been employed to mediate molecular self-assembly reactions but often do not converge to a thermodynamic equilibrium and yield a mixture of kinetically trapped species. Here, the authors show a sequence-selective, dynamic covalent self-assembly process that mitigates kinetic trapping to afford biomimetic molecular ladders with covalent rungs.
format	article
author	Samuel C. Leguizamon Timothy F. Scott
author_facet	Samuel C. Leguizamon Timothy F. Scott
author_sort	Samuel C. Leguizamon
title	Sequence-selective dynamic covalent assembly of information-bearing oligomers
title_short	Sequence-selective dynamic covalent assembly of information-bearing oligomers
title_full	Sequence-selective dynamic covalent assembly of information-bearing oligomers
title_fullStr	Sequence-selective dynamic covalent assembly of information-bearing oligomers
title_full_unstemmed	Sequence-selective dynamic covalent assembly of information-bearing oligomers
title_sort	sequence-selective dynamic covalent assembly of information-bearing oligomers
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/09df118c738a420c9464aa05784992ac
work_keys_str_mv	AT samuelcleguizamon sequenceselectivedynamiccovalentassemblyofinformationbearingoligomers AT timothyfscott sequenceselectivedynamiccovalentassemblyofinformationbearingoligomers
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Sequence-selective dynamic covalent assembly of information-bearing oligomers

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