Amide-Assisted Rearrangement of Hydroxyarylformimidoyl Chloride to Diarylurea

A novel amide-assisted rearrangement reaction of hydroxybenzimidoyl chloride has been established for the efficient synthesis of 1,3-diphenylurea derivatives. A variety of electronically and sterically different 1,3-diphenylurea derivatives can be obtained in good to excellent yields, and a proposed...

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Autores principales:	Xizhong Song, Xiaoyu Liu, Wei Yu, Yi Jin
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	rearrangement Diarylurea benzamide hydroxyarylformimidoyl chloride Organic chemistry QD241-441
Acceso en línea:	https://doaj.org/article/09eceae1ae1f410eaf84954024afa21b
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spelling	oai:doaj.org-article:09eceae1ae1f410eaf84954024afa21b2021-11-11T18:27:06ZAmide-Assisted Rearrangement of Hydroxyarylformimidoyl Chloride to Diarylurea10.3390/molecules262164371420-3049https://doaj.org/article/09eceae1ae1f410eaf84954024afa21b2021-10-01T00:00:00Zhttps://www.mdpi.com/1420-3049/26/21/6437https://doaj.org/toc/1420-3049A novel amide-assisted rearrangement reaction of hydroxybenzimidoyl chloride has been established for the efficient synthesis of 1,3-diphenylurea derivatives. A variety of electronically and sterically different 1,3-diphenylurea derivatives can be obtained in good to excellent yields, and a proposed reaction mechanism is also presented.Xizhong SongXiaoyu LiuWei YuYi JinMDPI AGarticlerearrangementDiarylureabenzamidehydroxyarylformimidoyl chlorideOrganic chemistryQD241-441ENMolecules, Vol 26, Iss 6437, p 6437 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	rearrangement Diarylurea benzamide hydroxyarylformimidoyl chloride Organic chemistry QD241-441
spellingShingle	rearrangement Diarylurea benzamide hydroxyarylformimidoyl chloride Organic chemistry QD241-441 Xizhong Song Xiaoyu Liu Wei Yu Yi Jin Amide-Assisted Rearrangement of Hydroxyarylformimidoyl Chloride to Diarylurea
description	A novel amide-assisted rearrangement reaction of hydroxybenzimidoyl chloride has been established for the efficient synthesis of 1,3-diphenylurea derivatives. A variety of electronically and sterically different 1,3-diphenylurea derivatives can be obtained in good to excellent yields, and a proposed reaction mechanism is also presented.
format	article
author	Xizhong Song Xiaoyu Liu Wei Yu Yi Jin
author_facet	Xizhong Song Xiaoyu Liu Wei Yu Yi Jin
author_sort	Xizhong Song
title	Amide-Assisted Rearrangement of Hydroxyarylformimidoyl Chloride to Diarylurea
title_short	Amide-Assisted Rearrangement of Hydroxyarylformimidoyl Chloride to Diarylurea
title_full	Amide-Assisted Rearrangement of Hydroxyarylformimidoyl Chloride to Diarylurea
title_fullStr	Amide-Assisted Rearrangement of Hydroxyarylformimidoyl Chloride to Diarylurea
title_full_unstemmed	Amide-Assisted Rearrangement of Hydroxyarylformimidoyl Chloride to Diarylurea
title_sort	amide-assisted rearrangement of hydroxyarylformimidoyl chloride to diarylurea
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/09eceae1ae1f410eaf84954024afa21b
work_keys_str_mv	AT xizhongsong amideassistedrearrangementofhydroxyarylformimidoylchloridetodiarylurea AT xiaoyuliu amideassistedrearrangementofhydroxyarylformimidoylchloridetodiarylurea AT weiyu amideassistedrearrangementofhydroxyarylformimidoylchloridetodiarylurea AT yijin amideassistedrearrangementofhydroxyarylformimidoylchloridetodiarylurea
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Amide-Assisted Rearrangement of Hydroxyarylformimidoyl Chloride to Diarylurea

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