Cement Substitution in High-Temperature Concrete

An alternative binder to calcium aluminate cement (CAC) was prepared by the sol-gel method. Chemically pure systems such as tetraethylorthosilicate (SiC<sub>8</sub>H<sub>20</sub>O<sub>4</sub>) and nonahydrate of alumina nitrate (Al(NO<sub>3</sub>)<s...

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Autores principales: Miroslava Klárová, Jozef Vlček, Michaela Topinková, Jiří Burda, Alexandr Martaus, Ivan Priesol, Jacek Szczerba
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Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:0a4fe956be5746b893fd11d870d8e6ef2021-11-25T18:25:53ZCement Substitution in High-Temperature Concrete10.3390/min111111612075-163Xhttps://doaj.org/article/0a4fe956be5746b893fd11d870d8e6ef2021-10-01T00:00:00Zhttps://www.mdpi.com/2075-163X/11/11/1161https://doaj.org/toc/2075-163XAn alternative binder to calcium aluminate cement (CAC) was prepared by the sol-gel method. Chemically pure systems such as tetraethylorthosilicate (SiC<sub>8</sub>H<sub>20</sub>O<sub>4</sub>) and nonahydrate of alumina nitrate (Al(NO<sub>3</sub>)<sub>3</sub>·9H<sub>2</sub>O) were used as major raw materials. The manufacturing process of binder via solution is mentioned, and transitions in binder structure as a function of thermal treatment in the range between 85 and 1400 °C are described. Finally, binder efficiency was verified by its application in high-temperature concrete instead of calcium aluminate cement (CAC). Newly developed sol-gel binder was characterized by XRFS quantitative analyses, XRD diffraction, STA-DTA and TG analyses and the BET method. Samples of concrete which were based on natural bauxite raw material showed cold compressive strength of 42 MPa compared to the same material where a conventional CAC was applied, and samples reached cold compressive strength of 44 MPa.Miroslava KlárováJozef VlčekMichaela TopinkováJiří BurdaAlexandr MartausIvan PriesolJacek SzczerbaMDPI AGarticlenon-cement bindercorundumsol-gelMineralogyQE351-399.2ENMinerals, Vol 11, Iss 1161, p 1161 (2021)
institution DOAJ
collection DOAJ
language EN
topic non-cement binder
corundum
sol-gel
Mineralogy
QE351-399.2
spellingShingle non-cement binder
corundum
sol-gel
Mineralogy
QE351-399.2
Miroslava Klárová
Jozef Vlček
Michaela Topinková
Jiří Burda
Alexandr Martaus
Ivan Priesol
Jacek Szczerba
Cement Substitution in High-Temperature Concrete
description An alternative binder to calcium aluminate cement (CAC) was prepared by the sol-gel method. Chemically pure systems such as tetraethylorthosilicate (SiC<sub>8</sub>H<sub>20</sub>O<sub>4</sub>) and nonahydrate of alumina nitrate (Al(NO<sub>3</sub>)<sub>3</sub>·9H<sub>2</sub>O) were used as major raw materials. The manufacturing process of binder via solution is mentioned, and transitions in binder structure as a function of thermal treatment in the range between 85 and 1400 °C are described. Finally, binder efficiency was verified by its application in high-temperature concrete instead of calcium aluminate cement (CAC). Newly developed sol-gel binder was characterized by XRFS quantitative analyses, XRD diffraction, STA-DTA and TG analyses and the BET method. Samples of concrete which were based on natural bauxite raw material showed cold compressive strength of 42 MPa compared to the same material where a conventional CAC was applied, and samples reached cold compressive strength of 44 MPa.
format article
author Miroslava Klárová
Jozef Vlček
Michaela Topinková
Jiří Burda
Alexandr Martaus
Ivan Priesol
Jacek Szczerba
author_facet Miroslava Klárová
Jozef Vlček
Michaela Topinková
Jiří Burda
Alexandr Martaus
Ivan Priesol
Jacek Szczerba
author_sort Miroslava Klárová
title Cement Substitution in High-Temperature Concrete
title_short Cement Substitution in High-Temperature Concrete
title_full Cement Substitution in High-Temperature Concrete
title_fullStr Cement Substitution in High-Temperature Concrete
title_full_unstemmed Cement Substitution in High-Temperature Concrete
title_sort cement substitution in high-temperature concrete
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/0a4fe956be5746b893fd11d870d8e6ef
work_keys_str_mv AT miroslavaklarova cementsubstitutioninhightemperatureconcrete
AT jozefvlcek cementsubstitutioninhightemperatureconcrete
AT michaelatopinkova cementsubstitutioninhightemperatureconcrete
AT jiriburda cementsubstitutioninhightemperatureconcrete
AT alexandrmartaus cementsubstitutioninhightemperatureconcrete
AT ivanpriesol cementsubstitutioninhightemperatureconcrete
AT jacekszczerba cementsubstitutioninhightemperatureconcrete
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