Cement Substitution in High-Temperature Concrete
An alternative binder to calcium aluminate cement (CAC) was prepared by the sol-gel method. Chemically pure systems such as tetraethylorthosilicate (SiC<sub>8</sub>H<sub>20</sub>O<sub>4</sub>) and nonahydrate of alumina nitrate (Al(NO<sub>3</sub>)<s...
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MDPI AG
2021
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oai:doaj.org-article:0a4fe956be5746b893fd11d870d8e6ef2021-11-25T18:25:53ZCement Substitution in High-Temperature Concrete10.3390/min111111612075-163Xhttps://doaj.org/article/0a4fe956be5746b893fd11d870d8e6ef2021-10-01T00:00:00Zhttps://www.mdpi.com/2075-163X/11/11/1161https://doaj.org/toc/2075-163XAn alternative binder to calcium aluminate cement (CAC) was prepared by the sol-gel method. Chemically pure systems such as tetraethylorthosilicate (SiC<sub>8</sub>H<sub>20</sub>O<sub>4</sub>) and nonahydrate of alumina nitrate (Al(NO<sub>3</sub>)<sub>3</sub>·9H<sub>2</sub>O) were used as major raw materials. The manufacturing process of binder via solution is mentioned, and transitions in binder structure as a function of thermal treatment in the range between 85 and 1400 °C are described. Finally, binder efficiency was verified by its application in high-temperature concrete instead of calcium aluminate cement (CAC). Newly developed sol-gel binder was characterized by XRFS quantitative analyses, XRD diffraction, STA-DTA and TG analyses and the BET method. Samples of concrete which were based on natural bauxite raw material showed cold compressive strength of 42 MPa compared to the same material where a conventional CAC was applied, and samples reached cold compressive strength of 44 MPa.Miroslava KlárováJozef VlčekMichaela TopinkováJiří BurdaAlexandr MartausIvan PriesolJacek SzczerbaMDPI AGarticlenon-cement bindercorundumsol-gelMineralogyQE351-399.2ENMinerals, Vol 11, Iss 1161, p 1161 (2021) |
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non-cement binder corundum sol-gel Mineralogy QE351-399.2 |
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non-cement binder corundum sol-gel Mineralogy QE351-399.2 Miroslava Klárová Jozef Vlček Michaela Topinková Jiří Burda Alexandr Martaus Ivan Priesol Jacek Szczerba Cement Substitution in High-Temperature Concrete |
description |
An alternative binder to calcium aluminate cement (CAC) was prepared by the sol-gel method. Chemically pure systems such as tetraethylorthosilicate (SiC<sub>8</sub>H<sub>20</sub>O<sub>4</sub>) and nonahydrate of alumina nitrate (Al(NO<sub>3</sub>)<sub>3</sub>·9H<sub>2</sub>O) were used as major raw materials. The manufacturing process of binder via solution is mentioned, and transitions in binder structure as a function of thermal treatment in the range between 85 and 1400 °C are described. Finally, binder efficiency was verified by its application in high-temperature concrete instead of calcium aluminate cement (CAC). Newly developed sol-gel binder was characterized by XRFS quantitative analyses, XRD diffraction, STA-DTA and TG analyses and the BET method. Samples of concrete which were based on natural bauxite raw material showed cold compressive strength of 42 MPa compared to the same material where a conventional CAC was applied, and samples reached cold compressive strength of 44 MPa. |
format |
article |
author |
Miroslava Klárová Jozef Vlček Michaela Topinková Jiří Burda Alexandr Martaus Ivan Priesol Jacek Szczerba |
author_facet |
Miroslava Klárová Jozef Vlček Michaela Topinková Jiří Burda Alexandr Martaus Ivan Priesol Jacek Szczerba |
author_sort |
Miroslava Klárová |
title |
Cement Substitution in High-Temperature Concrete |
title_short |
Cement Substitution in High-Temperature Concrete |
title_full |
Cement Substitution in High-Temperature Concrete |
title_fullStr |
Cement Substitution in High-Temperature Concrete |
title_full_unstemmed |
Cement Substitution in High-Temperature Concrete |
title_sort |
cement substitution in high-temperature concrete |
publisher |
MDPI AG |
publishDate |
2021 |
url |
https://doaj.org/article/0a4fe956be5746b893fd11d870d8e6ef |
work_keys_str_mv |
AT miroslavaklarova cementsubstitutioninhightemperatureconcrete AT jozefvlcek cementsubstitutioninhightemperatureconcrete AT michaelatopinkova cementsubstitutioninhightemperatureconcrete AT jiriburda cementsubstitutioninhightemperatureconcrete AT alexandrmartaus cementsubstitutioninhightemperatureconcrete AT ivanpriesol cementsubstitutioninhightemperatureconcrete AT jacekszczerba cementsubstitutioninhightemperatureconcrete |
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1718411116129812480 |