Controlling pairing of π-conjugated electrons in 2D covalent organic radical frameworks via in-plane strain

Controlling the electronic states of molecules is a fundamental challenge for future sub-nanoscale device technologies but the external dynamical control of these states still awaits experimental realization. Here, via quantum chemical calculations, the authors demonstrate that in-plane uniaxial str...

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Autores principales:	Isaac Alcón, Raúl Santiago, Jordi Ribas-Arino, Mercè Deumal, Ibério de P. R. Moreira, Stefan T. Bromley
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/0acfa094221c4409a3bc7d09cf9401f7
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spelling	oai:doaj.org-article:0acfa094221c4409a3bc7d09cf9401f72021-12-02T11:39:31ZControlling pairing of π-conjugated electrons in 2D covalent organic radical frameworks via in-plane strain10.1038/s41467-021-21885-y2041-1723https://doaj.org/article/0acfa094221c4409a3bc7d09cf9401f72021-03-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-21885-yhttps://doaj.org/toc/2041-1723Controlling the electronic states of molecules is a fundamental challenge for future sub-nanoscale device technologies but the external dynamical control of these states still awaits experimental realization. Here, via quantum chemical calculations, the authors demonstrate that in-plane uniaxial strain of 2D covalently linked arrays of radical units induces controlled pairing of π-conjugated electrons in a reversible way.Isaac AlcónRaúl SantiagoJordi Ribas-ArinoMercè DeumalIbério de P. R. MoreiraStefan T. BromleyNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Isaac Alcón Raúl Santiago Jordi Ribas-Arino Mercè Deumal Ibério de P. R. Moreira Stefan T. Bromley Controlling pairing of π-conjugated electrons in 2D covalent organic radical frameworks via in-plane strain
description	Controlling the electronic states of molecules is a fundamental challenge for future sub-nanoscale device technologies but the external dynamical control of these states still awaits experimental realization. Here, via quantum chemical calculations, the authors demonstrate that in-plane uniaxial strain of 2D covalently linked arrays of radical units induces controlled pairing of π-conjugated electrons in a reversible way.
format	article
author	Isaac Alcón Raúl Santiago Jordi Ribas-Arino Mercè Deumal Ibério de P. R. Moreira Stefan T. Bromley
author_facet	Isaac Alcón Raúl Santiago Jordi Ribas-Arino Mercè Deumal Ibério de P. R. Moreira Stefan T. Bromley
author_sort	Isaac Alcón
title	Controlling pairing of π-conjugated electrons in 2D covalent organic radical frameworks via in-plane strain
title_short	Controlling pairing of π-conjugated electrons in 2D covalent organic radical frameworks via in-plane strain
title_full	Controlling pairing of π-conjugated electrons in 2D covalent organic radical frameworks via in-plane strain
title_fullStr	Controlling pairing of π-conjugated electrons in 2D covalent organic radical frameworks via in-plane strain
title_full_unstemmed	Controlling pairing of π-conjugated electrons in 2D covalent organic radical frameworks via in-plane strain
title_sort	controlling pairing of π-conjugated electrons in 2d covalent organic radical frameworks via in-plane strain
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/0acfa094221c4409a3bc7d09cf9401f7
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Controlling pairing of π-conjugated electrons in 2D covalent organic radical frameworks via in-plane strain

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