Untwisted restacking of two-dimensional metal-organic framework nanosheets for highly selective isomer separations

Metal-organic framework nanosheets are promising for separations, but interactions among them, affecting the performance, are largely unexplored. The authors reveal the favored stacking modes in a model system, and that untwisted restacking by thermal treatment improves isomer separation performance...

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Autores principales: Ze-Rong Tao, Jian-Xiang Wu, Ying-Jie Zhao, Ming Xu, Wen-Qi Tang, Qing-Hua Zhang, Lin Gu, Da-Huan Liu, Zhi-Yuan Gu
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/0aef11b69fad4832bb063352a88d9a59
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Sumario:Metal-organic framework nanosheets are promising for separations, but interactions among them, affecting the performance, are largely unexplored. The authors reveal the favored stacking modes in a model system, and that untwisted restacking by thermal treatment improves isomer separation performance in gas chromatography capillary columns.