Ti(Oi-Pr)4-promoted photoenolization Diels–Alder reaction to construct polycyclic rings and its synthetic applications

Anthracenols with multiple chiral centres are common motifs in natural products. Here, the authors show a highly stereoselective photoenolization/Diels–Alder methodology involving a key Lewis acid reagent enabling the efficient construction of a family of anthracenol derivatives with quaternary cent...

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Autores principales: Baochao Yang, Kuaikuai Lin, Yingbo Shi, Shuanhu Gao
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/0af9120aeae34641b0bef29b9a8df013
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spelling oai:doaj.org-article:0af9120aeae34641b0bef29b9a8df0132021-12-02T14:40:58ZTi(Oi-Pr)4-promoted photoenolization Diels–Alder reaction to construct polycyclic rings and its synthetic applications10.1038/s41467-017-00440-82041-1723https://doaj.org/article/0af9120aeae34641b0bef29b9a8df0132017-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-00440-8https://doaj.org/toc/2041-1723Anthracenols with multiple chiral centres are common motifs in natural products. Here, the authors show a highly stereoselective photoenolization/Diels–Alder methodology involving a key Lewis acid reagent enabling the efficient construction of a family of anthracenol derivatives with quaternary centers.Baochao YangKuaikuai LinYingbo ShiShuanhu GaoNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-10 (2017)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Baochao Yang
Kuaikuai Lin
Yingbo Shi
Shuanhu Gao
Ti(Oi-Pr)4-promoted photoenolization Diels–Alder reaction to construct polycyclic rings and its synthetic applications
description Anthracenols with multiple chiral centres are common motifs in natural products. Here, the authors show a highly stereoselective photoenolization/Diels–Alder methodology involving a key Lewis acid reagent enabling the efficient construction of a family of anthracenol derivatives with quaternary centers.
format article
author Baochao Yang
Kuaikuai Lin
Yingbo Shi
Shuanhu Gao
author_facet Baochao Yang
Kuaikuai Lin
Yingbo Shi
Shuanhu Gao
author_sort Baochao Yang
title Ti(Oi-Pr)4-promoted photoenolization Diels–Alder reaction to construct polycyclic rings and its synthetic applications
title_short Ti(Oi-Pr)4-promoted photoenolization Diels–Alder reaction to construct polycyclic rings and its synthetic applications
title_full Ti(Oi-Pr)4-promoted photoenolization Diels–Alder reaction to construct polycyclic rings and its synthetic applications
title_fullStr Ti(Oi-Pr)4-promoted photoenolization Diels–Alder reaction to construct polycyclic rings and its synthetic applications
title_full_unstemmed Ti(Oi-Pr)4-promoted photoenolization Diels–Alder reaction to construct polycyclic rings and its synthetic applications
title_sort ti(oi-pr)4-promoted photoenolization diels–alder reaction to construct polycyclic rings and its synthetic applications
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/0af9120aeae34641b0bef29b9a8df013
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AT yingboshi tioipr4promotedphotoenolizationdielsalderreactiontoconstructpolycyclicringsanditssyntheticapplications
AT shuanhugao tioipr4promotedphotoenolizationdielsalderreactiontoconstructpolycyclicringsanditssyntheticapplications
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