Ti(Oi-Pr)4-promoted photoenolization Diels–Alder reaction to construct polycyclic rings and its synthetic applications
Anthracenols with multiple chiral centres are common motifs in natural products. Here, the authors show a highly stereoselective photoenolization/Diels–Alder methodology involving a key Lewis acid reagent enabling the efficient construction of a family of anthracenol derivatives with quaternary cent...
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Nature Portfolio
2017
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oai:doaj.org-article:0af9120aeae34641b0bef29b9a8df0132021-12-02T14:40:58ZTi(Oi-Pr)4-promoted photoenolization Diels–Alder reaction to construct polycyclic rings and its synthetic applications10.1038/s41467-017-00440-82041-1723https://doaj.org/article/0af9120aeae34641b0bef29b9a8df0132017-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-00440-8https://doaj.org/toc/2041-1723Anthracenols with multiple chiral centres are common motifs in natural products. Here, the authors show a highly stereoselective photoenolization/Diels–Alder methodology involving a key Lewis acid reagent enabling the efficient construction of a family of anthracenol derivatives with quaternary centers.Baochao YangKuaikuai LinYingbo ShiShuanhu GaoNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-10 (2017) |
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Science Q Baochao Yang Kuaikuai Lin Yingbo Shi Shuanhu Gao Ti(Oi-Pr)4-promoted photoenolization Diels–Alder reaction to construct polycyclic rings and its synthetic applications |
description |
Anthracenols with multiple chiral centres are common motifs in natural products. Here, the authors show a highly stereoselective photoenolization/Diels–Alder methodology involving a key Lewis acid reagent enabling the efficient construction of a family of anthracenol derivatives with quaternary centers. |
format |
article |
author |
Baochao Yang Kuaikuai Lin Yingbo Shi Shuanhu Gao |
author_facet |
Baochao Yang Kuaikuai Lin Yingbo Shi Shuanhu Gao |
author_sort |
Baochao Yang |
title |
Ti(Oi-Pr)4-promoted photoenolization Diels–Alder reaction to construct polycyclic rings and its synthetic applications |
title_short |
Ti(Oi-Pr)4-promoted photoenolization Diels–Alder reaction to construct polycyclic rings and its synthetic applications |
title_full |
Ti(Oi-Pr)4-promoted photoenolization Diels–Alder reaction to construct polycyclic rings and its synthetic applications |
title_fullStr |
Ti(Oi-Pr)4-promoted photoenolization Diels–Alder reaction to construct polycyclic rings and its synthetic applications |
title_full_unstemmed |
Ti(Oi-Pr)4-promoted photoenolization Diels–Alder reaction to construct polycyclic rings and its synthetic applications |
title_sort |
ti(oi-pr)4-promoted photoenolization diels–alder reaction to construct polycyclic rings and its synthetic applications |
publisher |
Nature Portfolio |
publishDate |
2017 |
url |
https://doaj.org/article/0af9120aeae34641b0bef29b9a8df013 |
work_keys_str_mv |
AT baochaoyang tioipr4promotedphotoenolizationdielsalderreactiontoconstructpolycyclicringsanditssyntheticapplications AT kuaikuailin tioipr4promotedphotoenolizationdielsalderreactiontoconstructpolycyclicringsanditssyntheticapplications AT yingboshi tioipr4promotedphotoenolizationdielsalderreactiontoconstructpolycyclicringsanditssyntheticapplications AT shuanhugao tioipr4promotedphotoenolizationdielsalderreactiontoconstructpolycyclicringsanditssyntheticapplications |
_version_ |
1718390034234605568 |