Asymmetric catalysis mediated by a mirror symmetry-broken helical nanoribbon

If asymmetric catalysts were available by mirror symmetry breaking, an important insight may be given to how the biomolecular homochirality emerged in nature. Here, the authors report the first example of asymmetric catalysis by employing mirror symmetry-broken helical nanoribbons as the ligand.

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Detalles Bibliográficos
Autores principales: Zhaocun Shen, Yutao Sang, Tianyu Wang, Jian Jiang, Yan Meng, Yuqian Jiang, Kou Okuro, Takuzo Aida, Minghua Liu
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/0b32dbc306104271bdbb74c94c97f77f
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Sumario:If asymmetric catalysts were available by mirror symmetry breaking, an important insight may be given to how the biomolecular homochirality emerged in nature. Here, the authors report the first example of asymmetric catalysis by employing mirror symmetry-broken helical nanoribbons as the ligand.