Generation of non-stabilized alkyl radicals from thianthrenium salts for C–B and C–C bond formation

The generation of non-stabilized alkyl radicals from sulfonium salts has been a challenge for several decades. Here, the authors show the treatment of S-(alkyl) thianthrenium salts, which can generate non-stabilized alkyl radicals as key intermediates that enable controlled and selective reactions u...

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Autores principales:	Cheng Chen, Zheng-Jun Wang, Hongjian Lu, Yue Zhao, Zhuangzhi Shi
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/0b571ffe6c464e238b5fc31904d37738
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spelling	oai:doaj.org-article:0b571ffe6c464e238b5fc31904d377382021-12-02T18:46:58ZGeneration of non-stabilized alkyl radicals from thianthrenium salts for C–B and C–C bond formation10.1038/s41467-021-24716-22041-1723https://doaj.org/article/0b571ffe6c464e238b5fc31904d377382021-07-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-24716-2https://doaj.org/toc/2041-1723The generation of non-stabilized alkyl radicals from sulfonium salts has been a challenge for several decades. Here, the authors show the treatment of S-(alkyl) thianthrenium salts, which can generate non-stabilized alkyl radicals as key intermediates that enable controlled and selective reactions under mild photoredox conditions.Cheng ChenZheng-Jun WangHongjian LuYue ZhaoZhuangzhi ShiNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Cheng Chen Zheng-Jun Wang Hongjian Lu Yue Zhao Zhuangzhi Shi Generation of non-stabilized alkyl radicals from thianthrenium salts for C–B and C–C bond formation
description	The generation of non-stabilized alkyl radicals from sulfonium salts has been a challenge for several decades. Here, the authors show the treatment of S-(alkyl) thianthrenium salts, which can generate non-stabilized alkyl radicals as key intermediates that enable controlled and selective reactions under mild photoredox conditions.
format	article
author	Cheng Chen Zheng-Jun Wang Hongjian Lu Yue Zhao Zhuangzhi Shi
author_facet	Cheng Chen Zheng-Jun Wang Hongjian Lu Yue Zhao Zhuangzhi Shi
author_sort	Cheng Chen
title	Generation of non-stabilized alkyl radicals from thianthrenium salts for C–B and C–C bond formation
title_short	Generation of non-stabilized alkyl radicals from thianthrenium salts for C–B and C–C bond formation
title_full	Generation of non-stabilized alkyl radicals from thianthrenium salts for C–B and C–C bond formation
title_fullStr	Generation of non-stabilized alkyl radicals from thianthrenium salts for C–B and C–C bond formation
title_full_unstemmed	Generation of non-stabilized alkyl radicals from thianthrenium salts for C–B and C–C bond formation
title_sort	generation of non-stabilized alkyl radicals from thianthrenium salts for c–b and c–c bond formation
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/0b571ffe6c464e238b5fc31904d37738
work_keys_str_mv	AT chengchen generationofnonstabilizedalkylradicalsfromthianthreniumsaltsforcbandccbondformation AT zhengjunwang generationofnonstabilizedalkylradicalsfromthianthreniumsaltsforcbandccbondformation AT hongjianlu generationofnonstabilizedalkylradicalsfromthianthreniumsaltsforcbandccbondformation AT yuezhao generationofnonstabilizedalkylradicalsfromthianthreniumsaltsforcbandccbondformation AT zhuangzhishi generationofnonstabilizedalkylradicalsfromthianthreniumsaltsforcbandccbondformation
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Generation of non-stabilized alkyl radicals from thianthrenium salts for C–B and C–C bond formation

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